Deoiling phosphating solution and preparation method thereof

A technology of phosphating solution and zinc dihydrogen phosphate, which is applied in the coating process of metal materials, can solve the problems of few breakthroughs in phosphating technology, incomplete clarification, and high energy consumption, and achieve a dense and uniform phosphating film , low cost and simple preparation method

Inactive Publication Date: 2016-09-21
WUXI EPIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although scientists have done a lot of research in this area, it is not yet fully understood
After the end of World War II, there were few breakthroughs in phosphating technology, but steady development and improvement.
However, the degreasing and phosphating agents currently on the market use strong alkaline hot solutions (high energy consumption, heavy pollution, and the floating oil on the surface of the working fluid will cause secondary oil pollution to the treated parts), or use strong acids, or use easy Combustible, explosive and toxic organic solvents, producing toxic, highly corrosive and heavy pollution of gas, liquid and solid waste

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] The degreasing and phosphating solution of this embodiment is prepared from the following components by weight: 3-6 parts of hydroxylamine sulfate, 2 parts of sodium alkylarylsulfonate, 1 part of hexamethylenetetramine, zinc dihydrogen phosphate 12 parts, 12 parts of N-(phosphonomethyl) glycine isopropylamine salt, 6 parts of sodium lauryl sulfate, 2 parts of sodium carboxymethyl starch, 10 parts of linolenic acid, 3 parts of dinitropentamethylenetetramine parts, 40 parts of water, 15 parts of sodium fluoroborate.

[0012] Weigh each component according to the above weight ratio, then mix and stir, and stir evenly to completely dissolve each component, so as to obtain the oil-removing phosphating solution.

[0013] In the present invention, the surface of the metal workpiece can be treated by directly soaking and spraying, and then naturally dried to obtain a phosphating film.

Embodiment 2

[0015] The degreasing and phosphating solution of the present embodiment is prepared from the following components in parts by weight: 3-6 parts of hydroxylamine sulfate, 5 parts of sodium alkylarylsulfonate, 6 parts of hexamethylenetetramine, zinc dihydrogen phosphate 16 parts, N-(phosphonomethyl)glycine isopropylamine salt 15 parts, sodium lauryl sulfate 9 parts, carboxymethyl starch 4 parts, linolenic acid 14 parts, dinitropentamethylenetetramine 6 parts , 60 parts of water, 17 parts of sodium fluoroborate, and 8 parts of sodium fatty acid.

[0016] Weigh each component according to the above weight ratio, then mix and stir, and stir evenly to completely dissolve each component, so as to obtain the oil-removing phosphating solution.

[0017] In the present invention, the surface of the metal workpiece can be treated by directly soaking and spraying, and then naturally dried to obtain a phosphating film.

Embodiment 3

[0019] The degreasing and phosphating solution of this embodiment is prepared from the following components by weight: 3-6 parts of hydroxylamine sulfate, 2 parts of sodium alkylarylsulfonate, 1 part of hexamethylenetetramine, zinc dihydrogen phosphate 12 parts, 12 parts of N-(phosphonomethyl) glycine isopropylamine salt, 6 parts of sodium lauryl sulfate, 2 parts of sodium carboxymethyl starch, 10 parts of linolenic acid, 3 parts of dinitropentamethylenetetramine 40 parts of water, 15 parts of sodium fluoroborate, 5 parts of sodium fatty acid, 3 parts of ethylenediaminetetraacetic acid.

[0020] Weigh each component according to the above weight ratio, then mix and stir, and stir evenly to completely dissolve each component, so as to obtain the oil-removing phosphating solution.

[0021] In the present invention, the surface of the metal workpiece can be treated by directly soaking and spraying, and then naturally dried to obtain a phosphating film.

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PUM

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Abstract

The invention discloses a deoiling phosphating solution and a preparation method thereof. The deoiling phosphating solution is prepared through the following raw materials in parts by weight: 3 to 6 parts of hydroxylamine sulphate, 2 to 5 parts of sodium alkylarysulfonate, 1 to 6 parts of hexamine, 12 to 16 parts of zinc dihydrogen phosphate, 12 to 15 parts of N-(phosphonomethyl) glycine isopropylamine salt, 6 to 9 parts of sodium dodecyl sulfate, 2 to 4 parts of carboxymethyl starch sodium, 10 to 14 parts of linolenic acid, 3 to 6 parts of dinitro pentamethylene tetramine, 40 to 60 parts of water, and 15 to 17 parts of sodium fluoborate. A phosphating membrane prepared through the environmentally-friendly deoiling phosphating solution is dense, uniform, nontoxic and environmentally friendly; the deoiling process in the phosphating process is simplified, so that the phosphating efficiency can be improved; in addition, the preparation method is simple, and the cost is low.

Description

technical field [0001] The invention relates to a degreasing phosphating solution and a preparation method thereof. Background technique [0002] Phosphating is a commonly used pretreatment technology. In principle, it should belong to chemical conversion film treatment. It is mainly used for phosphating on the surface of steel, and non-ferrous metals (such as aluminum and zinc) can also be phosphating. Phosphating is a process in which chemical and electrochemical reactions form a phosphate chemical conversion film, and the formed phosphate conversion film is called a phosphating film. The purpose of phosphating is mainly to provide protection for the base metal and prevent the metal from being corroded to a certain extent; it is used as a primer before painting to improve the adhesion and anti-corrosion ability of the paint film layer; it can reduce friction in the metal cold processing process Lubrication. The phosphating process includes chemical and electrochemical re...

Claims

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Application Information

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IPC IPC(8): C23C22/36C23G1/02
CPCC23C22/362C23G1/02
Inventor 尤为
Owner WUXI EPIC TECH
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