Wear-resistant low-floating fiber glass fiber-reinforced polyphenylene sulfide composite material and preparation method thereof

A technology of polyphenylene sulfide and floating fiber glass fiber, which is applied in the field of polymer material modification, can solve the problems of difficult to meet the appearance and use requirements of precision parts, large amount of wear-resistant agent added, and limited application expansion, etc., to achieve production efficiency High, reduce the amount of wear-resistant agent used, the effect of simple production process

Inactive Publication Date: 2017-02-08
上海聚威新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention aims at the prominent floating fiber problem of glass fiber reinforced PPS composite material existing in the prior art, and it is difficult to meet the requirements of the appearance and the use of precision parts; the traditional method in the preparation of PPS-based wear-resistant composite material has a large amount of wear-resistant agent; at the same time, a single Due to the current situation that glass fiber reinforced PPS-based composite materials are limited by application expansion due to insufficient wear resistance, a wear-resistant low-floating fiber glass fiber reinforced polyphenylene sulfide composite material and its preparation method are provided. The method is simple to operate and easy to produce

Method used

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  • Wear-resistant low-floating fiber glass fiber-reinforced polyphenylene sulfide composite material and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] 1 Preparation of wear-resistant and anti-floating fiber masterbatch

[0044] Take 74 parts of PPS1150C, 15 parts of molybdenum disulfide, 10 parts of graphite, 1680.2 parts of antioxidant, 0.2 parts of light stabilizer V703, 0.3 parts of compatibilizer EMA-g-MAH, 0.3 parts of lubricant EBS, The above materials are uniformly mixed in a high-speed mixer, and then the mixture is melted and extruded through a twin-screw extruder, and finally cooled and dried to obtain abrasion-resistant and anti-floating fiber masterbatch. Among them, the processing temperature from zone 1 to zone 9 are 200℃, 260℃, 270℃, 280℃, 280℃, 285℃, 285℃, 290℃, 290℃, the speed is 280r / min, and the feeding speed is 20r / min.

[0045] 2 Preparation of wear-resistant low-floating fiber glass fiber reinforced polyphenylene sulfide composite material

[0046] Take 8 parts by weight of the abrasion and anti-floating fiber masterbatch prepared above, 72 parts of polyphenylene sulfide 1110C, 18 parts of continuous...

Embodiment 2

[0050] 1 Preparation of wear-resistant and anti-floating fiber masterbatch

[0051] Take 65 parts of PPS1170C, 16.5 parts of molybdenum disulfide, 17 parts of graphite, 0.4 parts of antioxidants 412s, 1680.3 parts of antioxidants, 0.5 parts of compatibilizer EMA-g-MAH, and 0.3 parts of lubricant EBS. The above materials are uniformly mixed in a high-speed mixer, and then the mixture is melted and extruded through a twin-screw extruder, and finally cooled and dried to obtain abrasion-resistant and anti-floating fiber masterbatch. Among them, the processing temperature from zone 1 to zone 9 are 200℃, 260℃, 270℃, 280℃, 280℃, 285℃, 285℃, 290℃, 290℃, the speed is 280r / min, and the feeding speed is 20r / min.

[0052] 2 Preparation of wear-resistant low-floating fiber glass fiber reinforced polyphenylene sulfide composite material

[0053] Take 12 parts by weight of the abrasion-resistant and anti-floating fiber masterbatch prepared above, 61 parts of polyphenylene sulfide 1130C, 25 parts...

Embodiment 3

[0055] 1 Preparation of wear-resistant and anti-floating fiber masterbatch

[0056] Take 60 parts of PPS1190C, 20 parts of molybdenum disulfide, 18 parts of graphite, 1680.5 parts of antioxidants, 10100.4 parts of antioxidants, 0.6 parts of compatibilizer EMA-g-MAH, and 0.5 parts of lubricant EBS by weight. The materials are uniformly mixed in a high-speed mixer, and then the mixture is melted and extruded through a twin-screw extruder, and finally cooled and dried to obtain abrasion-resistant and anti-floating fiber masterbatch. Among them, the processing temperature from zone 1 to zone 9 are 200℃, 260℃, 270℃, 280℃, 280℃, 285℃, 285℃, 290℃, 290℃, the speed is 280r / min, and the feeding speed is 20r / min.

[0057] 2 Preparation of wear-resistant low-floating fiber glass fiber reinforced polyphenylene sulfide composite material

[0058] Take 15 parts by weight of the abrasion-resistant and anti-floating fiber masterbatch prepared above, 53 parts of polyphenylene sulfide 1H30C, 30 part...

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Abstract

The invention relates to a wear-resistant low-floating fiber glass fiber-reinforced polyphenylene sulfide composite material and a preparation method thereof. The composite material comprises 45-85wt% of polyphenylene sulfide resin, 5-45wt% of glass fibers, 1-15wt% of wear-resistant anti-floating fiber master batches, 0.1-1.5wt% of an anti-oxidant, 0.1-1wt% of a coupling agent, 0.3-1.5wt% of a compatilizer and 0-2.5wt% of other auxiliary agents. The wear-resistant anti-floating fiber master batch comprises 65-95wt% of polyphenylene sulfide resin, 1-25wt% of molybdenum disulfide, 1-25wt% of graphite, 0.1-1wt% of an anti-oxidant, 0.1-2wt% of a compatilizer and 0-2.5wt% of other auxiliary agents. The composite material can eliminate floating fiber-caused influence on product appearance, reduce a wear-resisting agent use amount and improve wear resistance. The preparation method has simple processes and high production efficiency.

Description

Technical field [0001] The invention belongs to the technical field of polymer material modification, and specifically relates to a wear-resistant low-fiber glass fiber reinforced polyphenylene sulfide composite material and a preparation method thereof. Background technique [0002] Polyphenylene sulfide (PPS) is a special engineering plastic with excellent comprehensive properties. It has the characteristics of high strength, good chemical resistance, flame retardancy, and creep resistance. It is widely used in automobiles, electronic and electrical, aerospace and chemical industries. field. However, polyphenylene sulfide also has shortcomings such as high brittleness and low toughness, which restrict its further application and development. Although PPS is reinforced with glass fiber, its mechanical properties can be significantly improved, but the surface of the product is rough, the gloss is poor, and there are many floating fibers, which can not meet the appearance require...

Claims

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Application Information

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IPC IPC(8): C08L81/02C08L51/06C08L51/04C08L51/00C08K13/04C08K7/14C08K3/30C08K3/04C08K7/24C08K5/20C08K5/10C08K5/544B29C47/92B29C48/92
CPCC08L81/02B29C48/92B29C2948/92514B29C2948/92704C08J3/226C08J2381/02C08J2481/02C08L2205/025C08L2205/035C08L51/06C08L51/04C08L51/003C08K13/04C08K7/14C08K2003/3009C08K3/04C08K7/24C08K5/20C08K5/10C08K5/544
Inventor 王晶张天荣张剑牛永杰刘志林
Owner 上海聚威新材料股份有限公司
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