Method for preparing super-amphiphobic aluminum surface

An aluminum surface, super-amphiphobic technology, applied in the direction of metal material coating process, can solve the problems of poor product stability, difficult mass production, poor super-amphiphobic surface stability, etc., to achieve good stability, low cost, anti- Good effect of self-cleaning and anti-impedance cream

Inactive Publication Date: 2017-02-08
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the preparation process is relatively complicated, the product stability is poor, and it is difficult to achieve large-scale production
At present, the preparation process of most metal superamphiphobic surfaces is relatively complicated, often requiring the use of strong corrosive chemicals such as hydrochloric acid and sodium hydroxide, and the prepared superamphiphobic surfaces generally have the problem of poor stability.

Method used

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  • Method for preparing super-amphiphobic aluminum surface
  • Method for preparing super-amphiphobic aluminum surface
  • Method for preparing super-amphiphobic aluminum surface

Examples

Experimental program
Comparison scheme
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Embodiment 1

[0022] This embodiment provides a method for preparing a super amphiphobic aluminum surface, which specifically includes the following steps:

[0023] (1) Pre-treatment: use 400#, 800#, 1200# SiC sandpaper to grind the aluminum sheet horizontally and vertically in order to remove the oxide layer and some oil stains on the surface; after polishing, put the aluminum sheet into ethanol for 30 minutes, and then use ethanol , Ultrasonic cleaning with distilled water for 5 minutes;

[0024] (2) Etching: Put the aluminum sheet into NaCl and CuSO with a concentration of 0.6mol / L 4 Etched in the mixed solution for 6 minutes, and ultrasonically cleaned with distilled water for 10 minutes after etching;

[0025] (3) Construct micro / nano structures: put the cleaned aluminum sheet into boiling distilled water for 7 minutes, and dry at 80°C for 15 minutes after the water bath;

[0026] (4) Low surface energy modification: Soak the dried aluminum sheet in an ethanol solution of 1H, 1H, 2H,...

Embodiment 2

[0028] This embodiment provides a method for preparing a super amphiphobic aluminum surface, which specifically includes the following steps:

[0029] (1) Pre-treatment: Use 800#, 1200#, 1500# SiC sandpaper to polish the aluminum sheet horizontally and longitudinally in turn to remove the oxide layer and some oil stains on the surface. After polishing, soak the aluminum sheet in ethanol for 30 minutes, then ultrasonically clean it with ethanol and distilled water for 5 minutes respectively;

[0030] (2) Etching: Put the aluminum sheet into NaCl and CuSO with a concentration of 0.8mol / L 4 Etched in the mixed solution for 3 minutes, and ultrasonically cleaned with distilled water for 10 minutes after etching;

[0031] (3) Construct micro / nano structures: put the cleaned aluminum sheet into boiling distilled water for 15 minutes, and dry at 80°C for 10 minutes after the water bath;

[0032] (4) Low surface energy modification: Soak the dried aluminum sheet in an ethanol solutio...

Embodiment 3

[0034] This embodiment provides a method for preparing a super amphiphobic aluminum surface, which specifically includes the following steps:

[0035] (1) Pre-treatment: use 1200#, 1500#, 2000# SiC sandpaper to polish the aluminum sheet horizontally and vertically in sequence to remove the oxide layer and some oil stains on the surface. After polishing, soak the aluminum sheet in ethanol for 30 minutes, then ultrasonically clean it with ethanol and distilled water for 5 minutes respectively;

[0036] (2) Etching: Put the aluminum sheet into NaCl and CuSO with a concentration of 1mol / L 4 Etched in the mixed solution for 4 minutes, and ultrasonically cleaned with distilled water for 10 minutes after etching;

[0037] (3) Construct micro / nano structures: put the cleaned aluminum sheet into boiling distilled water for 12 minutes, and dry at 80°C for 10 minutes after the water bath;

[0038] (4) Low surface energy modification: Soak the dried aluminum sheet in an ethanol solution...

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Abstract

The invention discloses a method for preparing a super-amphiphobic aluminum surface and belongs to the field of metal surface treatment. The method comprises the following steps: first, performing chemical etching on metal aluminum, so as to form a micron-sized rough structure on the surface of metal aluminum; then, performing water bath treatment on the etched sample, so as to form a petal-shaped nanometer structure on the micron-sized rough structure; and finally, performing low surface energy treatment to obtain the super-amphiphobic aluminum surface of which the water contact angle reaches up to 159.6 degrees, the rolling angle I is as low as 2 degrees, the oil contact angle is 154.8 degrees, and the rolling angle II is 7 degrees. The super-amphiphobic aluminum surface prepared according to the method is high in stability and corrosion resistance. Meanwhile, the method provided by the invention has the advantages that the process is simple; the cost is low; the cleanliness and the environmental protection are achieved; the limitation by the shape and the size of a substrate is avoided; and the industrialized production is easy to implement.

Description

technical field [0001] The invention relates to a method for preparing a superamphiphobic aluminum surface, belonging to the field of metal surface treatment. Background technique [0002] As the non-ferrous metal with the largest output in the world, aluminum is widely used in construction, packaging, aerospace, transportation and other fields. With the development of national economic construction and national defense technology industry, the performance requirements of aluminum metal are becoming more and more stringent. It has good corrosion resistance and drag reduction properties. Constructing aluminum surfaces with superamphiphobic properties is of great significance for further improving the application of metallic aluminum. [0003] A superamphiphobic surface refers to a surface on which water and oil droplets have a contact angle greater than 150° and a rolling angle less than 10°. The method of preparing a metal-based superamphiphobic surface is usually: first p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F1/14C23C22/02C23C22/78
CPCC23F1/14C23C22/02C23C22/78C23C2222/20
Inventor 朱艳黎振华王力胡永茂
Owner KUNMING UNIV OF SCI & TECH
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