Acrylate adhesive for cementing skirting line ofhigh-speed train

A technology of acrylate glue and methyl methacrylate, applied in adhesives, polymer adhesive additives, non-polymer adhesive additives, etc. Excessive heat release, etc., to achieve short curing time, easy scraping, and reduced thixotropy

Pending Publication Date: 2017-05-31
HUBEI HUITIAN NEW MATERIALS STOCK CO LTD +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the bottom plate of the motor car is close to the ground, it is easily eroded by water vapor, and when the motor car is running, it will pass through areas with large temperature differences, so that the baseboard and viscose are not only in a state of slight vibration for a long time, but also prone to thermal expansion and cold shrink
[0004] Existing adhesives are easy to peel off when used in a humid environment, and the volume changes greatly during curing, and more heat is released, which is easy to cause corrugated burns on the skirting board, resulting in deformation of the board

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Mix 100g of dibutyl phthalate, 10g of silane coupling agent, 100g of calcium carbonate, 150g of benzoyl peroxide and 10g of castor oil to obtain an oxidizing agent.

[0040] Mix 200g methyl methacrylate, 50g impact modifier, 50g chlorosulfonated polyethylene, 10g accelerator, 5g paraffin, 20g maleic acid, 5g stabilizer, 50g calcium carbonate, 10g silane coupling agent, get reducing agent.

[0041] Mix 500ml of oxidizing agent and 4L of reducing agent evenly to obtain the acrylic ester glue for bonding the baseboard of the motor car.

[0042] Among them, the silane coupling agent is vinyl triperoxy tert-butyl silane, the calcium carbonate is nano-calcium carbonate, the impact modifier is acrylonitrile-butadiene-styrene terpolymer, and the accelerator is naphthenic acid Cobalt and paraffin are paraffins with a melting point of 47° C., and hydroquinone is used as a stabilizer.

[0043] Using aluminum alloy as a test piece, the tensile shear strength and peel strength tes...

Embodiment 2

[0046]Mix 45g of dibutyl phthalate, 5g of bisphenol A epoxy resin, 5g of silane coupling agent, 20g of calcium carbonate, 20g of benzoyl peroxide and 5g of castor oil to obtain an oxidizing agent.

[0047] Mix 45g methyl methacrylate, 20g impact modifier, 10g chlorosulfonated polyethylene, 3g accelerator, 1g paraffin, 5g maleic acid, 1g stabilizer, 10g calcium carbonate, 5g silane coupling agent, get reducing agent.

[0048] Mix 50ml of oxidizing agent and 500ml of reducing agent evenly to obtain acrylate glue for bonding motor car skirting.

[0049] Among them, the silane coupling agent is a mixture of γ-aminopropyltriethoxysilane, γ-glycidyloxypropyltrimethoxysilane, γ-(methacryloxy)propyltrimethoxysilane, specifically The matching ratio of is set according to the actual situation and has no substantial influence on the experimental results.

[0050] Calcium carbonate is heavy calcium carbonate, and the impact modifier is a mixture of ABS, MBS and ACR. The specific ratio i...

Embodiment 3

[0056] Mix 75g of dibutyl phthalate, 9g of bisphenol A epoxy resin, 9g of silane coupling agent, 45g of calcium carbonate, 54g of benzoyl peroxide and 12g of castor oil to obtain an oxidizing agent.

[0057] Mix 105g methyl methacrylate, 45g impact modifier, 24g chlorosulfonated polyethylene, 6g accelerator, 2.4g paraffin, 12g maleic acid, 2.1g stabilizer, 24g calcium carbonate, 9g silane coupling agent Evenly, the reducing agent is obtained.

[0058] Mix 500ml of oxidizing agent and 4.5L of reducing agent evenly to obtain the acrylate glue for bonding the baseboard of the motor car.

[0059] Wherein, the silane coupling agent is a mixture of γ-aminopropyltriethoxysilane and γ-glycidyloxypropyltrimethoxysilane, and the calcium carbonate is a mixture of nano calcium carbonate and heavy calcium carbonate.

[0060] The impact modifier is a mixture of ABS and MBS, the accelerator is a mixture of triethylenediamine, triethylamine and N,N dimethyl-p-toluidine; the paraffin wax has ...

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Abstract

The invention discloses an acrylate adhesive for cementing a skirting line of ahigh-speed train, relating to the field of acrylate structural adhesives. The acrylate adhesive contains the following components in parts by volume: 1 part of an oxidizing agent and 8-12 parts of a reducing agent, wherein the oxidizing agent contains the following components in parts by weight: 10-45 parts of dibutyl phthalate, 0-5parts of bisphenol A epoxy resin, 1-5 parts of a silane coupling agent, 10-20 parts of calcium carbonate, 15-20 parts of benzoyl peroxide and 1-5 parts of castor oil; the reducing agent contains the following components in parts by weight: 20-45 parts of methyl methacrylate, 5-20 parts of an impact-resistant modifier, 5-10 parts of chlorosulfonated polyethylene, 1-3 parts of an accelerant, 0.5-1 part of paraffin, 2-5 parts of maleic acid, 0.5-1 part of a stabilizer, 5-10 parts of calcium carbonate and 1-5 parts of the silane coupling agent. The acrylate adhesive has relatively good heat resistance and moisture resistance, the volume change is relatively small during the curing, and a high exothermic peak is avoided.

Description

technical field [0001] The invention relates to the field of acrylic structural adhesives, in particular to an acrylic adhesive used for bonding motor vehicle skirtings. Background technique [0002] In the compartments, cabs and toilets of high-speed trains, in order to increase the impact resistance of the wall area and improve the combination of the wall and the floor, it is necessary to set a skirting line at the connection between the wall and the floor. [0003] Most of the baseboards are made of wooden thin-layer boards. During construction, the baseboards are mainly bonded to the wall by sizing the entire area. Since the bottom plate of the motor car is close to the ground, it is easily eroded by water vapor, and when the motor car is running, it will pass through areas with large temperature differences, so that the baseboard and viscose are not only in a state of slight vibration for a long time, but also prone to thermal expansion and cold shrink. [0004] Exist...

Claims

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Application Information

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IPC IPC(8): C09J4/02C09J4/06C09J11/08C09J11/06C09J11/04
CPCC09J4/06C09J11/04C09J11/06C09J11/08
Inventor 刘苏宇韩胜利张浩军章锋吴正明
Owner HUBEI HUITIAN NEW MATERIALS STOCK CO LTD
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