Environment-friendly high-strength polypropylene bio-based plastic master batch with high antibacterial properties and method for preparing environment-friendly high-strength polypropylene bio-based plastic master batch
An antibacterial polypropylene and bio-based plastic technology is applied in the field of environmentally friendly high-strength and high-antibacterial polypropylene bio-based plastic masterbatch and its preparation, which can solve the problems of poor processing fluidity, poor mechanical properties, and no antibacterial properties.
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Embodiment 1
[0028] The fineness of 40 parts by weight is the chaff of 20 meshes, the polypropylene of 50 parts by weight, the titanium dioxide of 0.5 parts by weight, the talcum powder of 6 parts by weight, the antioxidant 1010 of 0.5 parts by weight and the carbendazim of 0.5 parts by weight Put it into a high-speed mixer for premixing, control the temperature at 130 ° C, keep it for 30 minutes, and then cool it to obtain a premixed material, put the premixed material into a twin-screw granulator for granulation, and control the temperature in each zone to 170 ℃ to obtain environmentally friendly high-strength and high-antibacterial polypropylene bio-based plastic masterbatch.
Embodiment 2
[0030] The fineness of 40 parts by weight is the chaff of 20 meshes, the polypropylene of 50 parts by weight, the titanium dioxide of 0.5 parts by weight, the talcum powder of 6 parts by weight, the antioxidant 1010 of 0.3 parts by weight, the antioxidant of 0.2 parts by weight 168 and 0.5 parts by weight of carbendazim were put into a high-speed mixer for premixing, the temperature was controlled at 130°C, kept for 30 minutes, and then cooled to obtain a premix, which was then put into a twin-screw granulator for Granulating, controlling the temperature in each zone to be 170°C to obtain environmentally friendly high-strength and high-antibacterial polypropylene bio-based plastic masterbatch.
Embodiment 3
[0032] The fineness of 40 parts by weight is the chaff of 20 meshes, the polypropylene of 50 parts by weight, the titanium dioxide of 0.5 parts by weight, the talcum powder of 6 parts by weight, the antioxidant 1010 of 0.3 parts by weight, the antioxidant of 0.2 parts by weight 168 and 0.5 parts by weight of the polyquaternium / prepared polypyrrole / polyetheramine ternary compound were placed in a high-speed mixer for premixing, the temperature was controlled at 130°C, kept for 30min, and then cooled to obtain a premix, Put the premix into a twin-screw granulator for granulation, and control the temperature in each zone to 170°C to obtain an environmentally friendly high-strength and high-antibacterial polypropylene bio-based plastic masterbatch;
[0033] The polyquaternium / polypyrrolene / polyetheramine ternary compound is prepared through the following steps:
[0034] (1) Preparation of polyquaternium prepolymer
[0035] In a 1000ml dry three-necked flask, add 0.05 mol of 1,3-d...
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