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A kind of method of acrylamide organic solution grafting modified carbon fiber surface sizing agent

A technology of acrylamide and organic solution, applied in the direction of carbon fiber, fiber treatment, fiber type, etc., can solve the problem of low interface bonding strength, and achieve the improvement of mechanical properties, the method is simple and easy to implement, the interface shear strength and various mechanical properties improved effect

Active Publication Date: 2019-05-14
常州融信复合材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims to solve the technical problem of low interfacial bonding strength of current carbon fiber reinforced vinyl ester resin or unsaturated polyester resin composite materials, and provides a method for grafting and modifying carbon fiber surface sizing agent with acrylamide organic solution

Method used

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  • A kind of method of acrylamide organic solution grafting modified carbon fiber surface sizing agent
  • A kind of method of acrylamide organic solution grafting modified carbon fiber surface sizing agent
  • A kind of method of acrylamide organic solution grafting modified carbon fiber surface sizing agent

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specific Embodiment approach 1

[0020] Embodiment 1: This embodiment is a method for grafting a modified carbon fiber surface sizing agent with an acrylamide organic solution, specifically as follows:

[0021] 1. Configure the modifier solution: dissolve the modifier in a volatile organic solvent to obtain a modifier solution; the mass concentration of the modifier solution is 0.1% to 2.0%; the modifier It is an acrylamide organic small molecule containing both amino groups and unsaturated double bonds in its molecular structure;

[0022] 2. Carbon fiber surface modification: heat the modifier solution prepared in step 1 to 20°C to 80°C, and use the modifier solution at 20°C to 80°C to modify the surface of the carbon fiber at a temperature of 50°C to 80°C Dry under the condition of 0.5h~1h, obtain the carbon fiber after the surface sizing agent is chemically grafted and modified; The carbon fiber is unidirectional carbon fiber with epoxy type sizing agent, carbon fiber woven fabric with epoxy type sizing ag...

specific Embodiment approach 2

[0024] Embodiment 2: The difference between this embodiment and Embodiment 1 is that the acrylamide-type organic small molecules containing both amino groups and unsaturated double bonds in the molecular structure described in step 1 are acrylamide, methacrylamide, A mixture of one or more of phenylacrylamide and N-methylolacrylamide. Others are the same as in the first embodiment.

specific Embodiment approach 3

[0025] Embodiment 3: This embodiment is different from Embodiment 1 in that the volatile organic solvent described in Step 1 is one or a mixture of alcohols, ethers and ketones. Others are the same as in the first embodiment.

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Abstract

The invention discloses a graft modification method of a sizing agent on a carbon fiber surface from an acrylamide organic solution, and relates to a modification method of the sizing agent on the carbon fiber surface. The method aims to solve the technical problem that the interface bonding strength of a current carbon fiber strengthened vinyl ester resin or unsaturated polyester resin composite material is low. The method comprises the following steps: firstly preparing the acrylamide modifier organic solution; secondly, carrying out carbon fiber surface modification. The method is simple and practicable, chemical grating is directly carried out on the sizing agent on the carbon fiber surface, the strength of the carbon fiber cannot be damaged, and the modified sizing agent can also play a role of protecting the carbon fiber. The interfacial shear strength and mechanical properties of the composite material prepared from the modified carbon fiber and unsaturated polyester resin are obviously improved.

Description

technical field [0001] The invention relates to a method for modifying a carbon fiber surface sizing agent. Background technique [0002] Vinyl ester resin (VE) is a thermosetting resin obtained by reacting epoxy resin with unsaturated small molecules. Vinyl ester resin not only retains the basic chain segment of epoxy resin, inherits the excellent characteristics of epoxy resin, but also introduces unsaturated double bonds in the molecular chain, which has good process performance of unsaturated polyester resin. Therefore, vinyl ester resin has excellent performance in mechanical properties, high temperature resistance, chemical corrosion resistance, curing performance, molding performance and processing performance, and has been widely used in automobile, sports, medical and health fields. The curing mechanism of vinyl ester resin is the same as that of unsaturated polyester resin. It is the cross-linking molding between the double bonds in the resin molecule and the doub...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M13/41C08L63/10C08K9/04C08K7/06D06M101/40
CPCC08K7/06C08K9/04D06M13/41D06M2101/40D06M2200/40C08L63/10
Inventor 王荣国刘文博焦卫卫
Owner 常州融信复合材料有限公司