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A coating process for crystalline silicon solar cells

A solar cell, crystalline silicon technology, applied in metal material coating process, circuit, sputtering and other directions, can solve the problems of uneven film thickness, complex crystal structure, etc., to achieve good product quality, uniform thickness, improve work efficiency The effect of efficiency

Inactive Publication Date: 2018-12-11
福建省宝顿智能装备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But the SiO prepared by this patent 2 Non-uniform film thickness and complex crystal structure

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  • A coating process for crystalline silicon solar cells

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Effect test

Embodiment 1

[0026] A coating process for a crystalline silicon solar cell, using sputtering of a single-layer boron-aluminum compound anti-reflection film on the surface of a crystalline silicon substrate; the sputtering method of a single-layer boron-aluminum compound anti-reflection film comprises the following steps:

[0027] Step S1, pre-cleaning the surface of the crystalline silicon substrate, specifically: cleaning with ultrasonic waves added with RBS25 liquid cleaning agent, the ultrasonic frequency is 50kHz, the temperature is 40°C, and the power density is 0.1W / cm 2 ;

[0028] Step S2, performing an etching operation on the pre-cleaned crystalline silicon surface, specifically: first use HNO with a volume concentration of 10% 3 The aqueous solution oxidizes N-type silicon containing phosphorus impurities, and then uses HF aqueous solution with a volume concentration of 2% to remove silicon oxide.

[0029] In step S3, the etched crystalline silicon is transferred to the magnetro...

Embodiment 2

[0031] A coating process for a crystalline silicon solar cell, using sputtering of a single-layer boron-aluminum compound anti-reflection film on the surface of a crystalline silicon substrate; the sputtering method of a single-layer boron-aluminum compound anti-reflection film comprises the following steps:

[0032] Step S1, pre-cleaning the surface of the crystalline silicon substrate, specifically: cleaning with ultrasonic waves added with RBS35 type liquid detergent medium, the ultrasonic frequency is 200kHz, the temperature is 60°C, and the power density is 0.8W / cm 2 ;

[0033] Step S2, performing an etching operation on the pre-cleaned crystalline silicon surface, specifically: first use HNO with a volume concentration of 30% 3 The aqueous solution oxidizes N-type silicon containing phosphorus impurities, and then uses 5% HF aqueous solution to remove silicon oxide.

[0034] In step S3, the etched crystalline silicon is transferred to the magnetron sputtering chamber as...

Embodiment 3

[0036] A coating process for a crystalline silicon solar cell, using sputtering of a single-layer boron-aluminum compound anti-reflection film on the surface of a crystalline silicon substrate; the sputtering method of a single-layer boron-aluminum compound anti-reflection film comprises the following steps:

[0037] Step S1, pre-cleaning the surface of the crystalline silicon substrate, specifically: cleaning with ultrasonic waves added with RBS IND 940 liquid detergent medium, the ultrasonic frequency is 125kHz, the temperature is 50°C, and the power density is 0.4W / cm 2 ;

[0038] Step S2, performing an etching operation on the pre-cleaned crystalline silicon surface, specifically: first use HNO with a volume concentration of 20% 3 The aqueous solution oxidizes N-type silicon containing phosphorus impurities, and then uses HF aqueous solution with a volume concentration of 3.5% to remove silicon oxide.

[0039] In step S3, the etched crystalline silicon is transferred to t...

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Abstract

The invention discloses a coating process of a crystalline silicon solar battery. A single layer of boron-aluminum compound antireflective film is sputtered on the surface of a crystalline silicon substrate; the sputtering method comprises the steps of performing pre-cleaning on the surface of the crystalline silicon substrate; performing an etching operation on the pre-cleaned surface of the crystalline silicon; and transferring the crystalline silicon after the crystalline silicon is subjected to the etching operation to a magnetron sputtering chamber to be used as a base material, taking elementary aluminum as a target material, pumping mixed gas of alkyl borohydride and an inert gas to apply a negative bias pressure to the mixed gas, and performing sputtering to obtain the boron-aluminum compound antireflective film. The coating material is creative, and the photoelectric conversion efficiency of the crystalline silicon solar battery can be effectively improved.

Description

technical field [0001] The invention relates to the coating field of a sputtering method, in particular to a coating process of a crystalline silicon solar cell. Background technique [0002] Crystalline silicon is one of the important raw materials for the preparation of solar cell materials. Among silicon solar cell materials, monocrystalline silicon undoubtedly has the highest photoelectric conversion efficiency, and the corresponding technological development is relatively comprehensive. However, due to the complex structure and high manufacturing cost of monocrystalline silicon cells, the application of monocrystalline silicon series solar cell materials is limited to a certain extent. The polycrystalline silicon thin-film series solar cells supplement the shortage of monocrystalline silicon cells to a certain extent, occupy a certain market share, and are also one of the application directions that people are striving to develop. Polycrystalline silicon thin-film ser...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/18H01L31/068H01L31/0216C23C14/35C23C14/06C23C14/02
CPCC23C14/0057C23C14/067C23C14/35H01L31/02168H01L31/068H01L31/1804Y02E10/547Y02P70/50
Inventor 洪铮铮
Owner 福建省宝顿智能装备有限公司