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Phosphorus-free corrosion and scale inhibitor for water treatment and preparation method thereof

A phosphorus-free corrosion inhibition and water treatment technology, applied in the field of water treatment, can solve the problems of complex formula, no phosphorus-free corrosion and scale inhibitor formula, etc. Effect

Inactive Publication Date: 2017-09-15
HEFEI ZHIHUI LONGTUTENG INTPROP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patents 200710052475, 200810039161, 200610127172, and 2009100205068 disclose the formulation of non-phosphorus corrosion and scale inhibitors, which contain molybdate and polyepoxysuccinic acid that play a role in corrosion inhibition, but the above corrosion and scale inhibitors The agent also contains other components such as polymaleic anhydride, acrylic acid copolymer, triethanolamine, benzotriazole (BTA) or tungstate, borate, etc., and the formula is complex
However, for chemical wastewater to be used as circulating cooling water after secondary biochemical treatment, there is no efficient phosphorus-free corrosion and scale inhibitor formula

Method used

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  • Phosphorus-free corrosion and scale inhibitor for water treatment and preparation method thereof

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Effect test

Embodiment 1

[0032] In the embodiment of the present invention, a phosphorus-free corrosion and scale inhibitor for water treatment is composed of the following raw materials in parts by weight:

[0033] Sodium metasilicate 30 parts

[0034] Ammonium acetate 15 parts

[0035] 45 parts of monoglyceride succinate

[0036] 10 parts citric acid

[0037] 100 parts of water.

[0038] The preparation method of the phosphorus-free corrosion and scale inhibitor for water treatment is to dissolve sodium metasilicate in half of the water to obtain an aqueous sodium metasilicate solution; then dissolve ammonium acetate in the remaining half of the water to obtain acetic acid Ammonium aqueous solution; heat sodium metasilicate aqueous solution to 60°C, then add citric acid, stir for 30 minutes, then heat up to 100°C, add succinic acid monoglyceride, stir for 5 minutes, add ammonium acetate aqueous solution, continue stirring for 1 hour, drop to The non-phosphorus corrosion and scale inhibitor for w...

Embodiment 2

[0043] In the embodiment of the present invention, a phosphorus-free corrosion and scale inhibitor for water treatment is composed of the following raw materials in parts by weight:

[0044] Sodium metasilicate 50 parts

[0045] Ammonium acetate 35 parts

[0046] 60 parts of monoglyceride succinate

[0047] 20 parts citric acid

[0048] 150 parts of water.

[0049] The preparation method of the phosphorus-free corrosion and scale inhibitor for water treatment is to dissolve sodium metasilicate in half of the water to obtain an aqueous sodium metasilicate solution; then dissolve ammonium acetate in the remaining half of the water to obtain acetic acid Ammonium aqueous solution; heat sodium metasilicate aqueous solution to 90°C, then add citric acid, stir for 50 minutes, then heat up to 120°C, add monoglyceride succinate, stir for 10 minutes, add ammonium acetate aqueous solution, continue stirring for 1.5h, drop After reaching room temperature, the non-phosphorus corrosion ...

Embodiment 3

[0054] In the embodiment of the present invention, a phosphorus-free corrosion and scale inhibitor for water treatment is composed of the following raw materials in parts by weight:

[0055] Sodium metasilicate 35 parts

[0056] Ammonium acetate 20 parts

[0057] Monoglyceride succinate 50 parts

[0058] 13 parts citric acid

[0059] 120 parts of water.

[0060] The preparation method of the phosphorus-free corrosion and scale inhibitor for water treatment is to dissolve sodium metasilicate in half of the water to obtain an aqueous sodium metasilicate solution; then dissolve ammonium acetate in the remaining half of the water to obtain acetic acid Ammonium aqueous solution; heat sodium metasilicate aqueous solution to 70°C, then add citric acid, stir for 35 minutes, then raise the temperature to 105°C, add monoglyceride succinate, stir for 6 minutes, add ammonium acetate aqueous solution, continue stirring for 1.1h, drop After reaching room temperature, the non-phosphorus ...

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Abstract

The invention discloses a phosphorus-free corrosion and scale inhibitor for water treatment and a preparation method thereof. The phosphorus-free corrosion and scale inhibitor comprises the following raw materials in parts by weight: 30-50 parts of sodium metasilicate, 15-35 parts of ammonium acetate, 45-60 parts of succinylatedmonoglycerides, 10-20 parts of citric acid and 100-150 parts of water. The preparation method comprises the following steps: dissolving sodium metasilicate in half of the water to prepare a sodium metasilicate aqueous solution; dissolving ammonium acetate in the remaining half of the water to prepare an ammonium acetate aqueous solution; heating the sodium metasilicate aqueous solution to 60-90 DEG C, adding the citric acid, stirring for 30-50 minutes, then raising the temperature to 100-120 DEG C, adding succinylatedmonoglycerides, stirring for 5-10 minutes, adding the ammonium acetate aqueous solution, continuously stirring for 1-1.5 hours and reducing to a room temperature to obtain the phosphorus-free corrosion and scale inhibitor for water treatment. The phosphorus-free corrosion and scale inhibitor disclosed by the invention does not contain phosphorus and is non-toxic and pollution-free to an environment, good in corrosion and scale inhibition effect, rich in raw material source, simple in preparation process, low in cost and suitable for an industrial circulating cooling water system.

Description

[0001] This application is a divisional application with application number 2015104635982, application date of August 2, 2015, and title of invention "a non-phosphorus corrosion and scale inhibitor for water treatment and its preparation method". technical field [0002] The invention relates to the field of water treatment, in particular to a phosphorus-free corrosion and scale inhibitor for water treatment and a preparation method thereof. Background technique [0003] During the recycling process of industrial cooling water, there will be different degrees of inorganic salt deposition, corrosion, bacteria and algae growth and other problems, resulting in serious consequences such as reduced efficiency of heat exchange equipment, blockage, corrosion and perforation, and bring great hidden dangers to industrial production. . The use of appropriate corrosion and scale inhibitors and supporting water treatment agents can reduce the adverse effects caused by corrosion, scaling...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/12C02F103/02
CPCC02F5/125C02F2103/023C02F2303/08
Inventor 不公告发明人
Owner HEFEI ZHIHUI LONGTUTENG INTPROP CO LTD