A kind of environment-friendly repeated writing paper and preparation method thereof
A kind of writing paper, an environment-friendly technology, applied in the direction of paper, papermaking, paper coating, etc., to achieve moderate ink absorption uniformity and adhesion, enhance writing performance, and enhance the effect of writing clarity
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Embodiment 1
[0052] A preparation method of environmentally friendly repetitive writing paper includes the following steps:
[0053] 1) The bacterial cellulose with a water content of 98.7% obtained by fermentation is cleaned and crushed into a bacterial cellulose suspension with a particle size of 70nm;
[0054] 2) Add the hydroxyl protecting group 2.5 times the dry weight of bacterial cellulose to the bacterial cellulose suspension, mix evenly, adjust the pH of the mixture to 12, first react at room temperature for 0.8 hours, and then react at 70°C for 4 hours , The stirring speed of the whole reaction process was 150 rpm; after the reaction, the supernatant A1 was separated by centrifugal separation at 10000 rpm for 30 min; the precipitate A2 was added with deionized water of 100 times its dry weight and stirred evenly at 10000 rpm Centrifuge and wash for 30 minutes at the rotating speed, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernat...
Embodiment 2
[0080] A preparation method of environmentally friendly repetitive writing paper includes the following steps:
[0081] 1) Wash the bacterial cellulose with 98% water content obtained by fermentation, and crush it into a bacterial cellulose suspension with a particle size of 40nm;
[0082] 2) Add the hydroxyl protecting group 1.5 times the dry weight of bacterial cellulose to the bacterial cellulose suspension, mix evenly, adjust the pH of the mixture to 11, first react at room temperature for 0.5h, and then react at 60℃ for 3h , The stirring speed of the whole reaction process is 100 rpm; after the reaction, centrifuge at 8000 rpm for 20 min to separate the supernatant A1; add deionized water of 100 times its dry weight to the precipitate A2 and stir evenly at 8000 rpm Centrifuge and wash for 20 minutes at the rotating speed, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernatant B1; add deionized water 60 times its dry weight t...
Embodiment 3
[0111] A preparation method of environmentally friendly repetitive writing paper includes the following steps:
[0112] 1) Wash the bacterial cellulose with a water content of 99.5% obtained by fermentation, and pulverize it into a bacterial cellulose suspension with a particle size of 100 nm;
[0113] 2) Add the hydroxyl protecting group of 3 times the dry weight of bacterial cellulose to the bacterial cellulose suspension, mix evenly, adjust the pH of the mixture to 13, first react at room temperature for 1 hour, and then at 80°C for 5 hours, The stirring speed of the whole reaction process was 200 rpm; after the reaction, the supernatant A1 was separated by centrifugal separation at 12000 rpm for 40 minutes; deionized water 100 times its dry weight was added to the precipitate A2, and stirred evenly at 12000 rpm. Centrifuge and wash for 40 minutes, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernatant B1; add deionized water ...
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