Heteroatom-doped flowerene derivatives and synthesis method thereof

A technology for hydrinoflorene and heteroatom, which is applied in the field of heteroatom-doped florene derivatives and the preparation thereof, can solve the problems of low total yield, difficult synthesis of raw materials, inability to synthesize parent structures, etc., and achieves short synthesis steps, Easy bulk preparation, mild effect
CN107325116BActive Publication Date: 2019-08-06SHANGHAI UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANGHAI UNIV
Publication Date
2019-08-06

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Abstract

The invention provides a heteroatom doped sumanene derivative and a synthetic method thereof. The heteroatom doped sumanene derivative has a structural formula as shown in the specification. The raw materials for the method provided by the invention can be prepared easily in a large amount, and the method is short in synthetic step, mild in operation and good in yield. A method of high-temperature pyrolysis is not needed, and the synthetic method has the advantages of being mild in condition and easy for large-amount preparation. According to the invention, an iodine doped sumanene salt compound (I) and selenium doped sumanene (III) are synthesized for the first time, which has originality. The compound (I) has an important value in preparation of other polycyclic aromatic hydrocarbon compounds. A sulfur doped sumanene compound has a special curved surface structure (Buckybowl), is similar to a part of fullerene, and has an important application value in the fields of new material research, supramolecular recognition and the like.
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Description

technical field

[0001] The invention relates to a heteroatom-doped flowerene derivative and a preparation method thereof. In particular, a heteroatom-doped sumanene derivative formed by introducing heteroatoms into the molecular skeleton of the bowl-shaped aromatic compound Sumanene and a preparation method thereof. Background technique

[0002] Buckybowl is a representative class of polycyclic aromatic hydrocarbons with curved surfaces. Its structure is similar to a segment of fullerene or the capping structure of carbon nanotubes. Its biggest feature is its curved surface. , and its shape is similar to a bowl, hence the name. Bucky bowls have novel physical and chemical properties due to their novel and unique structure, and have potential application value in organic optoelectronic materials, such as they can be used to synthesize fullerenes and carbon nanotubes with uniform size and chirality control and curl Graphene and other multi-carbon materials. In addition, as ...

Claims

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