Method for preparing graphene/rubber composite material

A composite material and graphene technology, which is applied in the field of graphene/rubber composite material preparation, can solve the problems of graphene being difficult to disperse, deteriorated rubber properties, and easy to agglomerate, and achieves environmentally friendly use, high preparation efficiency, and application prospects. expansive effect

Active Publication Date: 2017-11-07
QINGDAO UNIV OF SCI & TECH
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Problems solved by technology

[0005] The purpose of the present invention is to overcome the shortcomings of the prior art, solve the problem that graphene is difficult to disperse and easily agglomerate in the wet mixing process, and at the same time solve the glue caused by adding acid components to flocculate the mixed rubber in the wet mixing process. In order to solve the problems of poor material performance and other problems, a new wet mixing method and process was developed and designed, and the graphene is uniformly dispersed in the

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  • Method for preparing graphene/rubber composite material
  • Method for preparing graphene/rubber composite material
  • Method for preparing graphene/rubber composite material

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Embodiment 1

[0021]The preparation method of the silica / rubber composite material involved in this embodiment is also called the atomization drying method, and its process includes three steps of preparing the masterbatch mixture, preparing the masterbatch and preparing the composite material:

[0022] (1) Preparation of masterbatch mixture: first prepare modified graphene oxide aqueous solution: graphene oxide powder and water are ultrasonicated for 15min-12h at a temperature of 25-100°C and a power of 500-1500W to prepare graphene oxide Aqueous solution, the content of graphene oxide in the graphene oxide aqueous solution is 1-10mg / ml, adding γ-aminopropyltriethoxysilane (KH-550) to the deionized water of set quality and diluting to a mass percentage concentration of 0.5-2% KH-550 aqueous solution, add graphene oxide aqueous solution to KH-550 aqueous solution to form a mixed solution, ultrasonically disperse the mixed solution at room temperature for 10-30min, and then place the mixed so...

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Abstract

The invention belongs to the technical field of rubber wet-method mixing, and in particular relates to a method for preparing a graphene/rubber composite material. The method comprises the following three steps of preparing a rubber master batch mixed solution, preparing a rubber master batch and preparing a composite material, namely firstly, preptreating packing by using stirring and ultrasonic atomization techniques so as to form a packing emulsion, ejecting the packing emulsion to the surface of a high-temperature article through high gas pressure by using a packing pre-dispersion sudden heating crushing technique, performing sudden heating crushing on packing emulsion droplets so as to achieve secondary dispersion on the packing in a rubber substrate, further implementing a high-temperature evaporation drying technique, performing sudden heating crushing dispersion on a packing pre-dispersed material, placing prepared wet-method mixing rubber in a high-temperature environment, performing instantaneous evaporation on moisture of the rubber, performing high-quality dispersion on the cured packing in the rubber substrate, and finally preparing a packing/rubber composite material by using a common sealed mixing machine. The method is scientific and reliable in principle, practical, simple and convenient to prepare, high in preparation efficiency, wide in application prospect and good in environmental-friendliness.

Description

Technical field: [0001] The invention belongs to the technical field of rubber wet mixing, and specifically relates to a graphene / rubber composite material preparation method, which uses a combination of graphene latex predispersion and wet mixing rubber drying technology to realize the uniform dispersion of graphene in latex and distribution to prevent the aggregation of graphene after dispersion, and obtain a graphene / rubber composite material with uniform distribution and good dispersion of graphene, excellent mechanical properties, and significantly improved comprehensive mechanical properties and dynamic mechanical properties. Background technique: [0002] With the continuous advancement of science and technology and the continuous development of material science, the materials used by human beings are also updated and improved. Polymer materials and their products have occupied various fields, industries and departments of life, as large as space shuttles. A certain p...

Claims

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Application Information

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IPC IPC(8): C08L7/02C08K9/06C08K3/04C08K3/36C08K3/22B29B7/00
CPCC08K3/04C08K3/22C08K3/36C08K9/06B29B7/002C08K2003/2296C08K2201/011C08L7/02B29B7/7495B29B7/286B29B7/823B29B7/183
Inventor 边慧光刘洁李泽汉李海涛汪传生沈波尹凤福李绍明
Owner QINGDAO UNIV OF SCI & TECH
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