503results about "Diamond" patented technology

Luminescent diamond is made by subjecting a volume of diamond grains to high-pressure / high-temperature conditions with or without a catalyst to cause the grains to undergo plastic deformation to produce nitrogen vacancy defects in the diamond grains, increasing the luminescent activity / intensity of the resulting diamond material. The consolidated diamond material may be further treated to further increase luminescent activity / intensity, which treatment may comprise reducing the consolidated diamond material to diamond particles, heat treatment in vacuum, and air heat treatment, which reducing process further increases luminescent activity / intensity. The resulting luminescent diamond particles display a level of luminescence intensity greater than that of conventional luminescent nanodiamond, and may be functionalized for use in biological applications.

The invention relates to a purification method of high-purity diamond, and relates to the technical field of diamond purification. The purification method comprises raw material pretreatment, microwave-assisted ionic liquid stripping, solid-liquid separation and ionic liquid recovery, deep purification, separation and drying, and the raw material pretreatment comprises the following steps: crushing an impurity-containing coarse diamond raw material into particles of 2-5mm, then carrying out wet ball milling in ethanol for 4-6 hours, refining the particles to 50-200 microns, and carrying out microwave-assisted ionic liquid stripping on the particles to obtain refined particles; immersing the particles into a mixed solution of 10% diluted hydrochloric acid and 2% ammonium bifluoride, performing ultrasonic treatment for 2 hours, and performing centrifugal washing with ultrapure water until the particles are neutral; the microwave-assisted ionic liquid stripping method comprises the following steps: mixing the pretreated raw material with an ionic liquid according to a mass ratio of 1: (5-10), and carrying out microwave treatment for 10-30 minutes to obtain a reaction mixture. According to the purification method, diamond impurities are efficiently removed, meanwhile, the surface structure of the diamond can be protected against damage, waste liquid can be recycled, and the influence on the environment is small.

Luminescent diamond is made by subjecting a volume of diamond grains to high-pressure / high-temperature conditions with or without a catalyst or pressure transfer media to cause the grains to undergo plastic deformation to produce internal vacancy defects, increasing the luminescent activity / intensity of the resulting diamond material. The luminescent material is then subjected to further treatment to create quantum dots on the surface of the diamond particles. Quantum dot formation can include placing the diamond particles in liquid and subjecting the particles to laser pulses. The consolidated diamond material may be treated to further increase luminescent activity / intensity including reducing the consolidated diamond material to diamond particles, heat treatment in vacuum, and / or air heat treatment. The resulting luminescent diamond particles display a level of luminescence intensity greater than that of conventional luminescent nanodiamond, and may be functionalized for use in biological applications.

The invention provides a high-performance nitrogen vacancy color center diamond material under yttrium oxide protection and a preparation method and application thereof, and belongs to the technical field of quantum materials. The preparation method comprises the following steps: firstly carrying out electron irradiation and cleaning on a diamond substrate, then processing by adopting nitrogen plasma, then depositing an yttrium oxide coating, and annealing the diamond substrate deposited with the yttrium oxide coating under a vacuum condition to obtain the high-performance nitrogen vacancy color center diamond material. According to the method, the diamond is treated through the nitrogen plasma, so that the displacement nitrogen concentration in the diamond can be increased, and the NV-color center concentration can be increased in the subsequent annealing treatment process; meanwhile, the yttrium oxide coating is deposited on the diamond substrate, so that defects on the surface of the diamond can be reduced, the NV-color center concentration is increased, and the prepared diamond material has excellent corrosion resistance. The diamond material prepared by the preparation method can be used for preparing quantum sensors used under extreme conditions.

The invention discloses an octahedral diamond synthesis method which comprises the following steps: preparing raw materials: selecting high-purity graphite powder and a powder catalyst, adding AlCl3 and KBH4 into the graphite powder to obtain graphite mixed powder, mixing the graphite mixed powder and the powder catalyst according to a weight ratio of (2-5): (5-8) to obtain mixed powder, adding a dispersing agent into the mixed powder, and uniformly mixing to obtain the raw materials, wherein the ratio of the dispersing agent to the mixed powder is 0.5: 6; the raw materials are put into a granulator to be granulated, and raw stone particles within 100 meshes are obtained; adding the raw stone particles into a mold, and pressing by adopting a four-column press to obtain a graphite core column; according to the method, in the diamond synthesis stage, the method of pressure subsection slow rising and power subsection slow rising is adopted, a good environment is provided for production of the octahedral diamond, the quality of the octahedral diamond is improved, the crystal form consistency is high, meanwhile, a high-position repeated mode is adopted in the pressure stage, and the performance of the diamond is improved.

The present invention relates to a process for preparing diamond particles, comprising subjecting a nanodiamond precursor material to a pressure of at least 8 GPa and a temperature of at least 900°C, wherein the diamond precursor material comprises a polycyclic aromatic compound which contains from 10 to 200 fused six-membered aromatic rings.

The present disclosure discloses a high-temperature and high-pressure preparation method for hexagonal diamond, which belongs to the field of superhard material synthesis technology. The method comprises making high-purity graphite into a precursor, assembling the synthesis block, and then subjecting it to heating, pressurizing, temperature holding, and pressure holding processes to obtain hexagonal diamond. The preparation method for hexagonal diamond according to the present disclosure allows high-purity graphite to achieve higher pressure along the c-axis direction, further promoting the phase transition of graphite. In addition, the temperature field where the precursor is located has a certain temperature gradient, which facilitates the transformation of high-purity graphite into hexagonal diamond and achieves a better conversion rate of hexagonal diamond.

The utility model relates to the technical field of diamond micro-powder purification, in particular to an efficient diamond micro-powder separation and purification device, which can automatically remove diamond micro-powder from acid liquor in the process of pickling and purifying the diamond micro-powder, and is convenient to use and high in practicability. Comprising a bottom plate, a support and a box, and the box is fixedly mounted at the upper end of the bottom plate through the support; a pickling cavity is formed in the left portion of the box body, a cleaning cavity is formed in the right portion of the box body, the pickling cavity and the cleaning cavity are separated through the partition plate, the partition plate is fixedly installed on the box body, acid liquor is arranged in the pickling cavity, clear water is arranged in the cleaning cavity, a cavity is formed in the cylinder body, and the lower cover and the upper cover are arranged in the cavity. A plurality of groups of filter holes communicated with the filter cavity are formed in the cylinder body, and filter cloth is arranged on the inner side wall of the cylinder body.

The invention discloses a metalized diamond particle, a diamond / gallium-based liquid metal composite material and a preparation method thereof, and belongs to the field of composite thermal interface materials. The metallized diamond particle comprises a diamond particle, the surface of the diamond particle is coated with an immiscible alloy layer, the immiscible alloy layer contains a diffusion barrier component and a reaction wetting component, and the content of the diffusion barrier component in the immiscible alloy layer is not higher than 15 at% of the total content of the diffusion barrier component and the reaction wetting component; wherein the diffusion barrier component is one or more of tungsten, molybdenum and tantalum, and the reaction wetting component is one or more of silver and copper. The metallized diamond particles and the gallium-based liquid metal are combined to form the composite material, so that the diamond / gallium-based liquid metal composite material has more excellent thermal conductivity.

The invention provides a preparation method of a diamond NV color center. The preparation method comprises the following steps: preparing one or more slotted nano structures on the surface of diamond; placing the diamond with the slotted nano-structure in a nitrogen source solution without metal elements, and performing pulse laser induced nitrogen injection by aligning laser to the area where the slotted nano-structure is located; and carrying out annealing treatment on the diamond subjected to pulse laser induced nitrogen injection to obtain the diamond with the NV color center. Nitrogen element shallow layer injection and nanoscale positioning in NV color center preparation are achieved at the same time.

The embodiment of the invention discloses a preparation method of a high-purity large-size hexagonal diamond, which comprises the following steps: S1, cutting along the c axis of highly oriented pyrolytic graphite to obtain cylindrical highly oriented pyrolytic graphite as a raw material precursor; s2, assembling the raw material precursor in a high-pressure heating synthesis assembly; s3, the high-pressure heating synthesis assembly is heated and pressurized to set pressure and set temperature, heat preservation is conducted for set time, and the high-purity hexagonal diamond is obtained; wherein the set temperature ranges from 1300 DEG C to 1900 DEG C, the set pressure ranges from 20 GPa to 25 GPa, and the set time ranges from 10 min to 20 min. According to the preparation method of the high-purity large-size hexagonal diamond disclosed by the embodiment of the invention, cylindrical high-orientation pyrolytic graphite cut along a c axis is used as a raw material precursor, the high-orientation pyrolytic graphite is completely converted into the high-purity large-size hexagonal diamond under set conditions, and the size is 1-2 mm; the method has important application prospects in the fields of superhard materials, semiconductor devices and the like.

The present application relates to a modified diamond micro-powder and a preparation method and application thereof. The preparation method of the modified diamond micro-powder comprises the following steps: performing hydroxylation treatment on diamond micro-powder to obtain surface hydroxylated diamond micro-powder; performing pretreatment on the surface hydroxylated diamond micro-powder in a mixed solution of a silane coupling agent and an organic solvent under ultrasonic conditions with a frequency of 25KHz-40KHz and an intensity of 1W / cm 2 -3W / cm 2 to obtain pretreated diamond micro-powder; and performing vacuum heat treatment on the pretreated diamond micro-powder to obtain modified diamond micro-powder. The preparation method greatly improves the bonding force between the modified layer and the diamond and improves the micro-powder agglomeration, so that the pretreatment link before chemical plating has the feasibility of batch processing, which not only doubles the production efficiency, but also reduces the production cost to one third of the traditional method.

The invention discloses an electrophoretic sedimentation purification and separation method for submicron diamonds, relates to the field of diamond grading and purification, and aims to solve the problems of high separation difficulty, low purity, low efficiency and easiness in agglomeration in the prior art. According to the technical scheme, the method comprises the following steps: firstly, carrying out vibratory screening on diamond powder, and then treating the surface of the powder by using a strong oxidizing solution; and preparing the treated diamond powder into slurry, filling the slurry into an insulating vessel with an electric field, and carrying out electrophoretic separation and classification. After treatment with the strong oxidizing solution, the problem of powder agglomeration can be effectively solved, the purity of the diamond powder can be effectively improved, the diamond powder can have excellent dispersing performance, and a high-precision separation effect can be achieved through electrophoretic separation and grading. Furthermore, the high-oxidability solution for treating the diamond powder and the purified water for preparing the slurry can be recycled, so that the material consumption is greatly reduced, the whole separation process is carried out at normal temperature or lower temperature, and the energy consumption is lower.

The invention discloses a diamond smoothing and patterning method and device based on catalytic agent energy field auxiliary etching, and belongs to the technical field of diamond smoothing and patterning, smoothing or patterning of diamond is achieved through the combined action of a catalytic agent and an energy field, and the contact part of the diamond and a catalytic agent disc is in contact with the catalytic agent disc under the catalytic action of the catalytic agent. Enabling the part, in contact with the catalyst, of the diamond to be subjected to etching reaction or graphitization reaction with oxygen atoms, and enabling the part, not in contact with the catalyst disc, not to be subjected to reaction, so that the diamond generates a structure corresponding to the surface of the catalyst disc; and the material removal rate of the diamond is remarkably improved, and damage to the surface and the subsurface of the diamond is avoided.

The present invention relates to diamond abrasive grains and a manufacturing method thereof, and provides tetradecahedral diamond abrasive grains with uniform size and shape. The manufacturing method of diamond abrasive grains according to the present invention allows for shape control and minimizes impurities and crystal defects, thereby manufacturing diamond abrasive grains for ultra-precision grinding in chemical mechanical planarization (CMP) processes.

Luminescent diamond is made by creating vacancies in diamond grains and heat treating the diamond grains by controlling a thickness of the diamond grains on a substrate. The heat treatment may occur in a temperature range that does not burn the diamond grains, and the controlled thickness produces an even color change and / or promotes oxygen terminations on the diamond particle surfaces.

The invention discloses easy-to-disperse diamond grinding fluid and a preparation method thereof, and relates to the technical field of grinding fluid. The easy-to-disperse diamond grinding fluid is prepared from the following raw materials in parts by weight: 1 to 20 parts of modified diamond micro powder, 40 to 80 parts of deionized water, 1 to 10 parts of polyethylene glycol 6000, 0.5 to 1.2 parts of sodium carboxymethyl cellulose, 1 to 20 parts of glycerol, 1 to 10 parts of triethanolamine, 0.3 to 0.7 part of sodium polyacrylate, 0.05 to 5 parts of 1, 2-benzisothiazolin-3-ketone and 1 to 10 parts of a modified silane coupling agent. According to the easy-to-disperse diamond grinding fluid, through the synergistic effect of the modified diamond micro powder and the modified silane coupling agent, the dispersity is excellent, and the stability is high; the formula is scientific, polyethylene glycol and other assistants are matched, precise process parameters and graded filtration are combined, the grinding efficiency is high, the surface smoothness of a workpiece is good, the antibacterial property and storage stability are good, and the application scene is wide.

A cutting blade (10) is provided with: a plate-shaped base material (20); a coarse-grain film (31) comprising particles having an average particle diameter of 0.5 [mu] m or more; and a fine particle film (32) comprising particles having an average particle diameter of less than 0.5 [mu] m. Furthermore, the base material (20) has a cutting edge (21) and a cutting edge part (22), the cutting edge (21) is at least a part of the outer edge, and the thickness of the cutting edge part (22) becomes smaller when the cutting edge part (22) is closer to the cutting edge (21). The coarse grain film (31) covers the surface of the cutting blade part (22) and the blade tip (21), and the fine grain film (32) covers the surface of the coarse grain film (31) on the blade tip (21).

The diamond member has a rake face and a flank. The ridge between the rake face and the flank forms a cutting edge. The arithmetic mean roughness of the rake face is 0.1 μm or more and 1.0 μm or less. The diamond member is measured for energy loss associated with the excitation of K-shell electrons of carbon by electron energy loss spectroscopy using a transmission electron microscope. The energy loss is used to measure the π bond originating from the carbon π bond in the graphite phase. * The intensity of the peaks and the σ due to the σ bond of carbon in the graphite phase and the diamond phase are * The peak intensity is calculated. * The peak intensity is σ * Divide the value by the peak intensity to obtain I π* / I σ* When the diamond material on the surface of the rake face is π* / I σ* is between 0.2 and 2.

Low temperature synthesis, growth and doping methods and resulting materials are disclosed. According to an aspect, a method for material transformation includes providing a target material comprising carbon and / or hydrocarbon. The method also includes placing the target material within a fluid comprising a hydrogen source. Further, the method includes applying energy to the target material such that at least some of the target material is transformed to the same material with new beneficial bonding configuration.

The invention discloses a copper-diamond composite board with high heat conductivity and low expansion coefficient and a preparation method thereof, and belongs to the technical field of preparation of heat-conducting packaging materials for electronic equipment. The preparation method comprises the following steps: grinding and cleaning a base copper plate, milling a rectangular groove to obtain a pretreated base copper plate, and performing electrochemical etching on the pretreated base copper plate to obtain an etched base copper plate; filling a rectangular groove in the etched base copper plate with the carbon nano tube and modified diamond, and compacting for 1-2 minutes under 20-30 MPa to obtain a mixed base copper plate; and the copper covering plate covers one side of the mixed base copper plate filled with the carbon nano tube modified diamond, and then the mixed base copper plate is placed in a graphite mold to be subjected to direct current hot pressing sintering to obtain the copper-diamond composite plate. The prepared copper-diamond composite board has good heat conduction performance and low thermal expansion performance, the bending strength is high, and the problem that the brittleness of the material is too high is effectively solved.

This invention provides a highly efficient method for separating or concentrating lattice defect-containing nanoparticles (NDs). [Solution] A method for separating or concentrating lattice defect-containing ND particles, comprising irradiating a dispersion containing at least two types of ND particles selected from nanodiamond (ND) particles having at least one type of lattice defect and ND particles without the lattice defect with at least one type of excitation laser light having an energy greater than or equal to the resonance absorption energy of the lattice defect and at least one type of stimulated emission laser light, thereby selectively moving the ND particles having the lattice defect by the absorption optical pressure generated by the absorption of at least one type of excitation laser light and the stimulated recoil force generated by the action of at least one type of stimulated emission laser light, wherein the excitation laser light transitions electrons in the ground state of the ND particles to an excited state, and the stimulated emission laser light transitions electrons in the excited state to the ground state faster than spontaneous emission to generate stimulated recoil force.

The invention discloses an artificial diamond cleaning and purifying device, and relates to the technical field of artificial diamond cleaning and purifying, the artificial diamond cleaning and purifying device comprises a machine box, two U-shaped frames and concave strip plates are arranged on the left side and the right side of the machine box, the concave strip plates are respectively fixed on the top surfaces of the two U-shaped frames, the two transverse plates are respectively fixed on the two sides of the inner walls of the two concave strip plates, and the two U-shaped frames and the concave strip plates are arranged on the left side and the right side of the machine box. The threaded rod penetrates through and is rotatably installed in the middle of the sides, close to each other, of the two transverse plates, the inner threaded block is slidably installed on the outer wall of the threaded rod, the inner wall of the inner threaded block is meshed with the inner wall of a threaded groove of the threaded rod, and the outer wall of the inner threaded block is in sliding contact with the inner walls of the two concave strip plates; according to the artificial diamond cleaning device, the two sides of the inner screw block are limited through the rubber mats, and therefore the problem that the artificial diamond cleaning effect is poor due to the fact that the filter cartridge shifts during displacement is solved.

Provided is a single-crystal diamond wherein: the half width of an X-ray diffraction rocking curve is 20 seconds or less, the half width of the X-ray diffraction rocking curve being measured using CuKα rays in X-ray diffraction by means of a double-crystal method in which a diamond crystal is used as a first crystal, with a (0004) plane parallel arrangement; the half width of a peak at the Raman shift of 1332 cm-1 to 1333 cm-1 in the Raman spectrum is 2.0 cm-1 or less; the etch pit density is 10000 / cm2 or less, the etch pit density being measured by means of an etching test; and the nitrogen content in terms of the number of atoms is more than 0.1 ppm and at most 50 ppm.

The present invention relates to highly pure high performance polycrystalline diamond monolith, a method for manufacturing a single-crystal diamond, and uses thereof.

The invention relates to the technical field of diamond preparation, in particular to a quantum diamond with an ultrahigh-density NV-color center and a preparation method and application of the quantum diamond. At present, the preparation of the quantum diamond generally adopts an electron irradiation and vacuum annealing method, and the quantum diamond prepared by the method is difficult to obtain the ultra-high density characteristic; therefore, the ultra-high-density quantum diamond is difficult to prepare at present. The quantum diamond with the NV-color center density larger than or equal to 15 ppm is prepared by greatly improving the irradiation dose, adjusting the annealing pressure and other technological conditions. The problem that ultra-high-density quantum diamond cannot be prepared in a common method is solved; and a favorable condition is provided for wide application.

The present invention discloses a synthetic device for synthetic diamonds from life, which includes: a growth chamber, in which a plurality of mutually isolated growth chambers are provided, and a synthetic cavity assembly is provided in each growth chamber; wherein, the synthetic cavity assembly includes a heating assembly and a synthetic assembly, the heating assembly is arranged at the upper and lower ends of the synthetic assembly, the heating assembly includes a heating sheet and a heating electrode, the heating sheet is arranged close to the synthetic assembly, and the heating electrode is arranged on the heating sheet. The present application achieves the purpose of being able to place one seed crystal in each of the multiple growth chambers in a growth chamber, so that multiple seed crystals can be cultivated simultaneously in one growth chamber, thereby realizing the technical effect of improving the cultivation efficiency of synthetic diamonds from life and reducing the cultivation cost, and then solving the problem that in the synthesis process of synthetic diamonds from life in the related art, only one seed crystal can be placed in each diamond growth chamber, so the production efficiency is much lower than that of ordinary cultivated diamonds, resulting in the high manufacturing cost of synthetic diamonds from life.

In certain examples, a poly crystalline (PC) diamond layer is processed to enhance the layer's TC (thermal conductivity) by a localized anneal confined to a subset region of the layer's processing surface. The temperature(s) of the localized anneal is sufficiently high to have damaged the processing surface if all of the processing surface were subjected to an anneal at such temperature(s). The localized anneal truncates grains extending into or beyond the processing surface to set or correspond with a low roughness attribute (e.g., not more than 1 nm). In another example, the localized anneal is preceded by performing a global anneal. The localized anneal results in unique physical attributes of the PC diamond layer including, e.g., the processing surface not being anneal-damaged, truncated diamond grains sufficient to set or correspond with an RMS roughness measure, and the TC being set as a function of grain sizes in the PC diamond layer and its thickness.

A method for processing a PCD element includes placing the PCD element in a vessel. A first fluid may be applied to the PCD element when the PCD element is in the vessel. A second fluid may be applied to the PCD element when the PCD element is in the vessel. A first temperature may be applied to the PCD element when the PCD element is in the vessel. A second temperature may be applied to the PCD element when the PCD element is in the vessel.