A kind of high temperature resistant phosphonic acid-based concrete retarder and its preparation method
A technology of concrete and retarder, which is applied in the field of high-temperature-resistant phosphonic acid-based concrete retarder and its preparation, and can solve the problem of complex components of cementitious materials, increase of aggregate mud content and water absorption, and influence on adaptability, etc. problems, to achieve the effect of improving workability and slump retention ability, broad application prospects, and enhancing adsorption capacity
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[0058] (1) Preparation of prepolymer
[0059] In a reactor equipped with a thermometer, a stirrer and a dropping device, add 0.1mol methallyl chloride and 5g water, slowly add 0.2mol AMPS and 0.3mol acrylic acid, 0.006g AIBN, 0.006mol mercaptoethanol dropwise Mix solution with 15g of water, under stirring state, heat up to 40°C, add dropwise in 40 minutes, raise the temperature to 50°C, react for 3h, and the corresponding prepolymer can be prepared. Tested by GPC, the molecular weight is 10000, and the molecular weight distribution is 1.35.
[0060] (2) Amination
[0061] Add 0.11 mol of ethylenediamine to the above system, raise the temperature to 90° C., and react for 2 hours to prepare the corresponding aminated product with an organic amine conversion rate of 94%.
[0062] (3) Introduction of phosphate groups
[0063] To the above system, add 0.33mol of phosphorous acid, 0.33mol of formaldehyde, a certain amount of sulfuric acid and water, slowly raise the temperature t...
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