Resin-based biodegradable 3D printing material and preparation method thereof

A 3D printing and resin-based technology, which is applied in the field of resin-based degradable 3D printing materials and its preparation, can solve the problems that materials are difficult to photodegrade and biodegrade, and the development of 3D printing technology encounters bottlenecks, etc. The effect of improving the degradation rate

Inactive Publication Date: 2017-11-10
ANHUI ORIGINAL POWER PRODUCTIVITY PROMOTION CENT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Materials are the material basis of 3D printing, and they are also the bottleneck restricting the development of 3D printing. At present, the materials used in 3D printing are all from industrial synthetic materials. After the printed products are discarded, the industrial chemically synthesized materials are difficult to photodegrade or biodegrade. The environment has caused a lot of pressure, making the development of 3D printing technology encounter a bottleneck. Therefore, we propose a resin-based degradable 3D printing material and its preparation method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A resin-based degradable 3D printing material, comprising the following components by weight percentage: 40 parts of epoxy resin, 30 parts of hydroxyl acrylic resin, 12 parts of phenolic resin, 10 parts of polylactate containing bamboo fiber, 16 parts of microcrystalline paraffin 6 parts of silk fibroin, 12 parts of fine filling material, 6 parts of polyacrylamide, 0.6 part of photoinitiator, 2 parts of crosslinking agent, 0.2 part of auxiliary agent, and the fine filling material is calcium carbonate with a fineness of 2-6um , calcium stearate mixture, the crosslinking agent is a mixture of one or two of titanate coupling agents or silane coupling agents, and the auxiliary agent is one or two of plasticizers or toughening agents mixture.

[0020] A preparation method of a resin-based degradable 3D printing material, the specific preparation method is as follows:

[0021] (1) Put epoxy resin, hydroxyacrylic resin, phenolic resin, and polylactic acid ester containing ba...

Embodiment 2

[0026] A resin-based degradable 3D printing material, comprising the following components by weight percentage: 44 parts of epoxy resin, 34 parts of hydroxyl acrylic resin, 14 parts of phenolic resin, 14 parts of polylactate containing bamboo fiber, 17 parts of microcrystalline paraffin 6 parts of silk fibroin, 13 parts of fine filling material, 7 parts of polyacrylamide, 0.7 part of photoinitiator, 3 parts of crosslinking agent, 0.2 part of auxiliary agent, and the fine filling material is calcium carbonate with a fineness of 2-6um , calcium stearate mixture, the crosslinking agent is a mixture of one or two of titanate coupling agents or silane coupling agents, and the auxiliary agent is one or two of plasticizers or toughening agents mixture.

[0027] A preparation method of a resin-based degradable 3D printing material, the specific preparation method is as follows:

[0028] (1) Put epoxy resin, hydroxyacrylic resin, phenolic resin, and polylactic acid ester containing ba...

Embodiment 3

[0033] A resin-based degradable 3D printing material, comprising the following components by weight percentage: 45 parts of epoxy resin, 35 parts of hydroxyacrylic resin, 15 parts of phenolic resin, 15 parts of polylactate containing bamboo fiber, and 18 parts of microcrystalline paraffin 1 part, 7 parts of silk fibroin, 14 parts of filler fine material, 8 parts of polyacrylamide, 0.8 part of photoinitiator, 4 parts of crosslinking agent, 0.3 part of auxiliary agent, and the filler fine material is calcium carbonate with a fineness of 2-6um , calcium stearate mixture, the crosslinking agent is a mixture of one or two of titanate coupling agents or silane coupling agents, and the auxiliary agent is one or two of plasticizers or toughening agents mixture.

[0034] A preparation method of a resin-based degradable 3D printing material, the specific preparation method is as follows:

[0035] (1) Put epoxy resin, hydroxyacrylic resin, phenolic resin, and polylactic acid ester conta...

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PUM

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Abstract

The invention discloses a resin-based degradable 3D printing material. The 3D printing material is prepared from the following components by weight: 40-50 parts of epoxy resin, 30-40 parts of hydroxyl acrylic resin, 12-18 parts of phenolic resin, 10-20 parts of bamboo-fiber-containing polylactate, 16-20 parts of microcrystalline wax, 6-8 parts of silk fibroin, 12-16 parts of filling fines, 6-10 parts of polyacrylamide, 0.6-1 part of a photoinitiator, 2-6 parts of a cross-linking agent and 0.2-0.4 parts of an auxiliary agent. With adoption of the technical scheme, the printing material based on the epoxy resin, the hydroxyl acrylic resin, the phenolic resin and bamboo-fiber-containing polylactate can be naturally degraded without environmental pollution, the biodegradation rate and photodegradation rate of the material are increased according to tests, and tensile strength and bending strength of the 3D printing material are also enhanced correspondingly.

Description

technical field [0001] The invention relates to the technical field of 3D printing materials and preparation methods thereof, in particular to a resin-based degradable 3D printing material and a preparation method thereof. Background technique [0002] 3D printing is a rapid prototyping technology, known as the core technology of the "third industrial revolution". The complex forging process can get the final product, which can realize structural optimization, material saving and energy saving in production. [0003] Materials are the material basis of 3D printing, and they are also the bottleneck restricting the development of 3D printing. At present, the materials used in 3D printing are all from industrial synthetic materials. After the printed products are discarded, the industrial chemically synthesized materials are difficult to photodegrade or biodegrade. The environment has caused a lot of pressure, making the development of 3D printing technology encounter a bottle...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08L33/12C08L61/06C08L67/04C08L97/02C08L91/06C08L89/00C08L33/26C08K3/26C08K5/098B33Y70/00
CPCC08L63/00B33Y70/00C08K2003/265C08K2201/003C08L2201/06C08L2205/02C08L2205/035C08L2205/16C08L33/12C08L61/06C08L67/04C08L97/02C08L91/06C08L89/00C08L33/26C08K3/26C08K5/098
Inventor 徐忠张学兵
Owner ANHUI ORIGINAL POWER PRODUCTIVITY PROMOTION CENT CO LTD
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