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30results about How to "Increased photodegradation rate" patented technology

Nanometer ZnO/graphene photo-catalyst and preparation method thereof

The invention relates to a nanometer ZnO / graphene photo-catalyst and a preparation method thereof. The photo-catalyst is a composite nanometer photo-catalyst which adopts the graphene as the frame and is carried with ZnO, wherein the mass rate of the graphene and the ZnO nanometer particles is 1:100-10:100. Because of adding of GS, the recombination rate of the electron-hole is reduced, and the photo-degradation ratio is greatly improved during the process of degrading methyl oranges under the irradiation of ultraviolet lights. If optimization of parameters is considered, If optimization of parameters, such as optimum ratio of the adding quantities of ZnO and GS, and the influences of pH and temperature are considered, so the prepared ZnO / GS combined catalyst has low cost, can be recycled and used, has good photo-catalyst effect, and can be applied to the photo-catalyst treatment of industrial waste water and waste gas.
Owner:SHANGHAI UNIV

Application of photocatalyst of TiO2 (titanium dioxide) loaded on glass fiber fabric to treating microcystin

The invention discloses application of photocatalyst of TiO2 (titanium dioxide) loaded on a glass fiber fabric to treating microcystin. The glass fiber fabric serves as a catalyst carrier with a load of 0.8-1.2g / 200cm2, and the TiO2 loaded on the glass fiber fabric is of a P25 type. After the TiO2 is treated, hydroxyl radicals are obviously increased during photocatalysis, so that oxidative degradation of the microcystin by means of photocatalysis is improved. Besides, the TiO2 has high photocatalytic activity and is higher in reuse rate.
Owner:HOHAI UNIV

Preparation method of vanadium and nitrogen co-doped titanium dioxide/activated carbon photocatalyst

The invention relates to a preparation method of a vanadium and nitrogen co-doped titanium dioxide / activated carbon photocatalyst. The preparation method comprises the following steps: washing activated carbon which is dried and grinded and then adding into ethanol solution of titanate; stirring to form a titanium source, wherein the activated carbon and titanium dioxide are in the mass ratio of 1:(0.05-0.5), and the stirring time is 4 to 12 hours; adding citric acid and urea into the deionized water in sequence, and stirring to obtain a solution serving as a nitrogen source; adding oxalic acid and ammonium vanadate into the deionized water, and stirring to obtain a solution serving as a vanadium source; mixing the nitrogen source and the vanadium source to obtain an aqueous solution; dripping the aqueous solution into the titanium source dropwise; vigorously stirring, standing, ageing, drying and grinding, and roasting for 4 hours at 400 DEG C in a nitrogen atmosphere. According to the method, the process is simple; the prepared titanium dioxide photocatalyst is high in visible-light activity, high in degradation speed and low in cost.
Owner:SHANGHAI NAT ENG RES CENT FORNANOTECH

Molybdenum disulfide/ferroferric oxide magnetic nanocomposite material and preparation method and application thereof

The invention relates to the technical field of magnetic nanocomposite materials, in particular to a molybdenum disulfide / ferroferric oxide magnetic nanocomposite material and a preparation method andapplication thereof. The molybdenum disulfide / ferroferric oxide magnetic nanocomposite material is of a flower type structure and is prepared by combining molybdenum disulfide and ferroferric oxide supported on the surface of molybdenum disulfide; and heterojunction is formed between molybdenum disulfide and ferroferric oxide. The photocatalytic degradation rate of organic pollutants for TC by the molybdenum disulfide / ferroferric oxide magnetic nanocomposite material is increased by 172.8% and 71.3% separately compared with a MoS2 material and a Fe3O4 material, and after recycling is performed for 5 times, the photodegradation rate of TC is only reduced by 3.5%. The test results show that the molybdenum disulfide / ferroferric oxide magnetic nanocomposite material is excellent in photocatalytic degradation effect on the organic pollutants and good in cycling stability.
Owner:NINGXIA UNIVERSITY

Enhancing photostabilization of oxymetazoline

InactiveCN101951886AProtected from photolytic degradationIncreased photolytic degradationOrganic active ingredientsPharmaceutical delivery mechanismMedicineOxymetazoline
The photostability of oxymetazoline in a topical decongestant composition is enhanced by lowering the pH of the composition using a buffer solution.
Owner:SCHERING PLOUGH HEALTHCARE PRODUCTS INC

Plant-based degradable 3D printing material

The invention provides a plant-based biodegradable 3D printing material. The 3D printing material is characterized by comprising the following raw materials in parts by weight: 20 to 45 parts of hot chromium polylactic acid ester containing straw fiber, 10 to 40 parts of polylactic acid ester containing bamboo fiber, 20 to 50 parts of biological rubber, 10 to 25 parts of nylon 11, 2 to 4 parts of hydroxy acrylic resin, 5 to 15 parts of ultra-fine fillers, 1.2 to 3.6 parts of a coupling agent, 1 to 5 parts of photosensitive resin, and 2 to 6 parts of an antioxidant. By performing the simulation of the biological decomposition process in natural environment containing water and microorganism on the 3D printing material according to a GB / T19276.1-2003 standard, the highest biological decomposition rate measured can reach 98 percent, the highest photodegradation rate can reach 92 percent, the highest tensile strength measured can reach 15 MPa, and the highest bending strength can reach 12 MPa.
Owner:SUZHOU BC TECH

Preparation method of 8-hydroxyquinoline iron organic dye photodegradation catalyst

The invention discloses a preparation method of an 8-hydroxyquinoline iron organic dye photodegradation catalyst, and belongs to the field of metal-organic complexes. The method comprises the following steps: firstly, preparing a photodegradation catalyst reaction solution, dissolving ligands in N,N-dimethylformamide or methanol, dissolving an iron salt in methanol or N,N-dimethylformamide, mixingthe obtained two solutions, carrying out stirring at room temperature, heating the prepared reaction liquid to 60-80 DEG C for a reaction, slowly carrying out cooling to room temperature after the reaction is finished to obtain a brown black block crystal, then carrying out washing in methanol, and carrying out airing, so as to obtain the 8-hydroxyquinoline catalyst with catalytic activity. Themethod provided by the invention has simple operation, mild condition and low cost, and the efficiency is high when the catalyst is applied to organic dye photodegradation, so that the method providedby the invention has feasibility in industrial application.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Method for preparing cellulose membrane based on chitosan

The invention discloses a method for preparing a cellulose membrane based on chitosan. The cellulose membrane prepared from the components such as modified titanium dioxide, pretreated cellulose and chitosan not only has excellent antibacterial and bactericidal effects, but also greatly improves the photocatalytic activity of the cellulose membrane, responds to visible light, and can effectively degrade organic matters; thiourea is used as a nitrogen-sulfur doping source, nitrogen-sulfur doped modified titanium dioxide is prepared through a sol-gel method, and nitrogen-sulfur doping can properly inhibit grain growth of titanium dioxide, so that the specific surface area of the titanium dioxide is increased, the titanium dioxide responds to visible light, and the photocatalytic activity ofthe titanium dioxide is improved; the preparation method is reasonable in process design and simple to operate, the cellulose membrane is prepared from chitosan, cellulose and other components; and meanwhile, the cellulose membrane has excellent antibacterial performance and photocatalytic performance, can be widely applied to the fields of sewage treatment, biomedical treatment and the like, andhas relatively high practicability.
Owner:陈昭桦

High-adsorption bismuth oxyiodide visible-light-driven photocatalyst and application thereof

The invention discloses a high-adsorption bismuth oxyiodide visible-light-driven photocatalyst and application thereof. The high-adsorption bismuth oxyiodide visible-light-driven photocatalyst is prepared by the following steps: (1) mixing a bismuth salt with an acid and an alcohol solution to obtain a mixed solution A, and preparing powder povidone iodine into an aqueous solution B; (2) slowly dropwise adding the mixed solution A into the aqueous solution B, continuously and uniformly stirring overnight at room temperature, transferring the mixed solution into a three-neck flask, and carrying out high-temperature reaction under stirring and reflux conditions; and (3) separating, washing and drying the obtained reaction product. According to the invention, the high-adsorption bismuth oxyiodide ultrafine powder has the advantages of large specific surface area, capability of better absorbing visible light and strong adsorbability to pollutants to be degraded; and the in-situ regenerated polyvinyl pyrrolidone coated bismuth oxyiodide can be directly attached to the surfaces of viscose and cotton fibers, other chemical reagents do not need to be added for after-finishing, and the finishing method is simple and efficient.
Owner:NANTONG TEXTILE & SILK IND TECH RES INST

Resin-based biodegradable 3D printing material and preparation method thereof

The invention discloses a resin-based degradable 3D printing material. The 3D printing material is prepared from the following components by weight: 40-50 parts of epoxy resin, 30-40 parts of hydroxyl acrylic resin, 12-18 parts of phenolic resin, 10-20 parts of bamboo-fiber-containing polylactate, 16-20 parts of microcrystalline wax, 6-8 parts of silk fibroin, 12-16 parts of filling fines, 6-10 parts of polyacrylamide, 0.6-1 part of a photoinitiator, 2-6 parts of a cross-linking agent and 0.2-0.4 parts of an auxiliary agent. With adoption of the technical scheme, the printing material based on the epoxy resin, the hydroxyl acrylic resin, the phenolic resin and bamboo-fiber-containing polylactate can be naturally degraded without environmental pollution, the biodegradation rate and photodegradation rate of the material are increased according to tests, and tensile strength and bending strength of the 3D printing material are also enhanced correspondingly.
Owner:ANHUI ORIGINAL POWER PRODUCTIVITY PROMOTION CENT CO LTD

Plastic garbage degradation treatment agent and preparation method thereof

The invention relates to a plastic garbage degradation treatment agent and a preparation method thereof, and belongs to the technical field of plastic garbage treatment. The preparation method comprises the following steps: firstly, taking polyhydroxy nanocellulose as a raw material, mixing the polyhydroxy nanocellulose with sodium silicate, adding hydrochloric acid, reacting and filtering to obtain filter residues, carrying out high-temperature reaction on the filter residues to obtain a degradation agent matrix, mixing mussel mucin liquid with the degradation agent matrix, adding catechol oxidase under an alkaline condition, reacting to obtain a modified degradation agent matrix, mixing the modified degradation agent matrix with ferric chloride and pulverized coal, reacting, filtering, and drying to obtain the plastic garbage degradation treatment agent. The plastic garbage degradation treatment agent has wide application prospects.
Owner:常州中科绿塑环保科技有限公司 +1

Biodegradable environment-friendly material for food package and preparation method thereof

The invention discloses a biodegradable environment-friendly material for food package and a preparation method thereof. The biodegradable environment-friendly material for food package is mainly prepared from, by weight, 20-30 parts of float glue, 30-40 parts of polylactic acid, 8-15 parts of corn starch, 5-8 parts of cortex acanthopanacis, 2-4 parts of celery, 1-5 parts of towel gourd stem, 0.5-0.8 part of sodium stearate, 2-6 parts of D-isoleucine, 4-8 parts of ethyl acetate and 0.5-0.9 part of chlorogenic acid. The obtained biodegradable environment-friendly material for food package meets the standard GB / T 19276.1-2003, the biological degradation process in a natural water environment is simulated, it is tested that the highest biological degradation rate of the material can be up to 98%, the highest photodegradation rate is up to 95%, and other performance indicators are excellent.
Owner:HENAN SHUIJINGTOU CULTURAL MEDIA CO LTD

Silver phosphate composite photocatalyst with magnetism as well as preparation method and application thereof

The invention discloses a silver phosphate composite photocatalyst with magnetism as well as a preparation method and application thereof. The preparation method of the silver phosphate composite photocatalyst is characterized by taking silver nitrate, disodium hydrogen phosphate and magnetic iron as raw materials, regulating a mass ratio of all reagents and reacting, thus obtaining a nano composite material (Ag3PO4@Fe3O4-100) of a magnetic iron loaded Ag3PO4 thin film; finally gently modifying the Ag3PO4@Fe3O4-100 by using Na2S, thus preparing an Ag2S doped Ag3PO4 thin film loaded type magnetic photocatalyst (Ag2S / Ag3PO4-Fe3O4-100) which is fast, efficient and light corrosion-resistant, wherein the Ag2S / Ag3PO4-Fe3O4-100 is used for photocatalytic degradation on organic pollutants such asdye, antibiotics and insecticides in a water body. The silver phosphate composite photocatalyst disclosed by the invention has the advantages that the degradation speed of the organic pollutants in the water body is fast, the efficiency is high, separation and recovery are easy, and the silver phosphate composite photocatalyst can resist light corrosion, can be cyclically utilized for many times and has wide application value.
Owner:ZHEJIANG SCI-TECH UNIV

Biodegradable foamed polypropylene and preparation method thereof

The invention discloses biodegradable foamed polypropylene, and particularly relates to the technical field of high polymer materials. The biodegradable foamed polypropylene is prepared from the following raw materials: a polypropylene resin, starch, calcium hydroxide, vinyl acetate, a dispersing agent, an antioxidant, a foaming nucleating agent, a photodegradation agent and a toughening agent. According to the invention, calcium hydroxide and the vinyl acetate are used for modifying starch, an alkaline earth metal calcium hydroxide is used for primarily modifying the starch so as to improve the compatibility of the starch, and then ceric ammonium nitrate is used for carrying out graft copolymerization reaction on the vinyl acetate and the starch so as to greatly improve the compatibility of the modified starch after graft copolymerization, so that the mixing effect of the starch and the polypropylene is good so as to effectively improve the biodegradation rate of the polypropylene material; the photodegradation rate of the polypropylene material can be effectively improved by adding the photodegradation agent while the foamed polypropylene material is treated by utilizing biodegradation and photodegradation so as to greatly improve the degradation rate of the foamed polypropylene material.
Owner:JIANGSU HAOSHENG PLASTIC IND TECH CO LTD

Antibacterial photo-degradation composite film as well as preparation method thereof and application thereof

The embodiment of the invention discloses an antibacterial photo-degradation composite film as well as a preparation method thereof and application thereof. The composite film is prepared from the following raw materials: modified nano TiO2, potassium sorbate, calcium propionate, Span 80, LLDPE (linear low density polyethylene) and HDPE (high-density polyethylene). The raw materials are speciallyselected, so that the prepared composite film has excellent mechanical property, antibacterial property and photo-degradation property.
Owner:LIAOYANG BOSHI FLUID EQUIP

A kind of preparation method of rutile phase titanium dioxide/graphene film

The invention discloses a preparation method of a rutile phase titanium dioxide / graphene film, comprising the following steps: adding 20 ml of tetrabutyl titanate into 15 ml of absolute ethanol and stirring for 1 hour to form A solution; adding 1.8 ml of acetyl Add acetone and 2 ml of deionized water to 15 ml of absolute ethanol and mix and stir for 1 hour to form B solution; slowly inject B solution into A solution, stir at room temperature for 1 hour, and age in an oven at 60°C to obtain TiO 2 Sol; Spin-coat 4 layers of TiO on Cu substrate / graphene film layer 2 The sol was dried in an oven at 110°C for 15 minutes for each spin-coated layer, and then annealed in an Ar gas atmosphere with a flow rate of 200 sccm. The present invention uses a sol-gel method on a Cu substrate and a TiO 2 A graphene layer is inserted between the films, which effectively improves the TiO 2 Photocatalytic activity of thin films against methylene blue (MB) dye solution.
Owner:XIAN UNIV OF SCI & TECH

Photodegradable environment-friendly plastic packaging bag and production process thereof

The invention relates to the technical field of packaging bag degradation, and particularly discloses a photodegradable environment-friendly plastic packaging bag and a production process thereof. The photodegradable environment-friendly plastic packaging bag is mainly prepared from the following raw materials: polyethylene, a cross-linking agent, a dispersing agent, a plasticizer, a photosensitizer, a photosensitive accelerant, a compatilizer and a transforming agent. The transforming agent is at least two of indocyanine green, nano iron sulfide and polyaniline. The photosensitizer is at least two of iron stearate, cerium stearate and stearic acid symbiotic rare earth. The production process of the photodegradable environment-friendly plastic packaging bag comprises the following steps of: (1) mixing and stirring raw materials, heating and dehydrating to obtain a mixture; (2) adding the mixture into a film blowing machine, heating, blowing the film, cooling and pressing edges to obtain a material film; and (3) preparing a finished degradable plastic packaging bag from the material film. The photodegradable environment-friendly plastic packaging bag prepared by the invention is high in degradation rate.
Owner:ZHENGZHOU YANFENG PLASTIC PACKAGING

Degradable environmentally-friendly material for food packaging

The invention discloses a degradable environmentally-friendly material for food packaging. The degradable environmental-protection material for the food packaging is prepared from, by weight, 20-30 parts of colloidal bismuth pectin, 30-40 parts of polylactide, 8-15 parts of corn starch, 5-8 parts of cortex acanthopanacis, 2-4 parts of dicranum scoparium, 1-5 parts of towel gourd stem, 0.5-0.8 part of sodium stearate, 2-6 parts of D-isoleucine, 4-8 parts of ethyl acetate, and 0.5-0.9 part of chlorogenic acid. The obtained degradable environmentally-friendly material for the food packaging is adopted a simulated biological decomposition process in the natural aqueous environment according to the GB / T 19276.1-2003 standard, the obtained biological decomposition rate after testing can reach 98% at most, the photodegradation rate of the material reaches 95% at most, and the other performance indexes are excellent.
Owner:宁波旅橙汽车科技有限公司

Rutile phase titanium dioxide/graphene film preparation method

The invention discloses a rutile phase titanium dioxide / graphene film preparation method, which comprises: adding 20 ml of tetrabutyl titanate into 15 ml of dehydrated alcohol, and stirring for 1 h toform a solution A; adding 1.8 ml of acetylacetone and 2 ml of deionized water into 15 ml of dehydrated alcohol, and carrying out mixed stirring for 1 h to form a solution B; slowly injecting the solution B into the solution A, stirring for 1 h at a room temperature, and aging in a drying oven at a temperature of 60 DEG C to obtain a TiO2 sol; coating a Cu substrate / graphene thin film layer with four layers of the TiO2 sol in a spin coating manner, wherein drying is performed for 15 min in a drying oven at a temperature of 110 DEG C after the spin-coating of the one layer; and annealing in anAr atmosphere with a flow rate of 200 sccm. According to the invention, the graphene layer is inserted between the Cu substrate and the TiO2 film through the sol-gel method, such that the photocatalytic activity of the TiO2 film to methylene blue (MB) dye solutions is effectively improved.
Owner:XIAN UNIV OF SCI & TECH

Degradable environment-friendly material for food packaging and preparation method thereof

The invention discloses a degradable environment-friendly material for food packaging and a preparation method thereof. The degradable environment-friendly material is prepared by, by weight, 20-30 parts of pectin, 30-40 parts of polylactic acid, 8-15 parts of corn starch, 5-8 parts of cortex acanthopanacis, 2-4 parts of dicranum scoparium, 1-5 parts of luffa stem, 0.5-0.8 part of sodium stearate, 2-6 parts of D-isoleucine, 4-8 parts of ethyl acetate, and 0.5-0.9 part of chlorogenic acid. Simulated biological decomposition tests, according to the standard of GB / T 19276.1-2003, of the degradable environment-friendly material in a natural water-containing environment show that the biological decomposition rate of the degradable environment-friendly material can reach up to 98%, and the light degradation ratio of the material reaches up to 95%, and other performance indexes of the material are excellent.
Owner:ZHENGZHOU LIFUAI BIOLOGICAL TECH CO LTD

Degradable food packaging material and method for preparing same

The invention discloses a degradable food packaging material and a method for preparing the same. The degradable food packaging material is mainly made of, by weight, 20-30 parts of carrageenan, 30-40 parts of polylactic acid, 8-15 parts of corn starch, 5-8 parts of cortex acanthopanacis, 2-4 parts of dicranum scoparium, 1-5 parts of herba plantaginis, 0.5-0.8 part of sodium stearate, 2-6 parts of D-isoleucine, 4-8 parts of ethyl acetate and 0.5-0.9 part of chlorogenic acid. The degradable food packaging material and the method have the advantages that biological decomposition procedures of the degradable food packaging material are simulated in natural water-containing environments according to GB / T 19276.1-2003 standards, the maximum tested biological decomposition rate of the degradable food packaging material can reach 98%, the maximum tested light degradation rate of the degradable food packaging material can reach 95%, and the degradable food packaging material is excellent in other performance indexes.
Owner:ZHENGZHOU LIFUAI BIOLOGICAL TECH CO LTD

Solid-air interface Fenton reaction coupled carbon nitride photocatalytic material and its preparation and application

The invention discloses a solid-gas interface Fenton reaction coupled carbon nitride photocatalytic material and preparation and application thereof. The surface of the photocatalytic material is grafted with hydroxyl groups, and ferrous ions or ferric ions or trivalent chromic ions capable of inducing the Fenton reaction are loaded. During preparation, melamine, alkali chloride and alkali containing alkali metal or alkaline-earth metal elements are adopted as raw materials, treatment is carried out in an electric furnace for a period of time at the temperature of 400 DEG C to 600 DEG C, the product is subjected to washing and suction filtration separation, the yellow carbon nitride photocatalytic material is obtained, and alkali chloride in washing liquid is recycled; the ferrous ions or the ferric ions or the trivalent chromic ions are loaded through a soaking method. According to the method, a catalyst forms a hydroxylated surface through a small amount of alkali, then a small number of ferrous ions or ferric ions or trivalent chromic ions are loaded through the soaking method, the modifying process is simple, easy to operate and low in cost, and the obtained product has excellent gas phase pollutant light degradation capacity.
Owner:TIANJIN UNIV

Degradable material for food package and preparation method of degradable material for food package

The invention discloses a degradable material for food package and a preparation method of the degradable material for food package. The degradable material for food package is prepared from, by weight, 20-30 parts of ichthyocolla, 30-40 parts of polylactic acid, 8-15 parts of sweet potato starch, 5-8 parts of cortex acanthopanacis, 2-4 parts of dicranum scoparium, 1-5 parts of herba plantaginis, 0.5-0.8 part of sodium stearate, 2-6 parts of D-isoleucine, 4-8 parts of ethyl acetate and 0.5-0.9 part of chlorogenic acid. The degradable material for food package has advantages that by simulation of a biological decomposition process in a natural watery environment according to GB / T 19276.1-2003 standards, the biological decomposition rate reaches 98% maximally in test, the light degradation rate of the material reaches 95% maximally, and other performance indexes are excellent.
Owner:HENAN SHUIJINGTOU CULTURAL MEDIA CO LTD

A kind of photodegradable polypropylene material and preparation method thereof

The invention relates to the field of polymer materials, and specifically discloses a photodegradable polypropylene material, comprising the following raw materials in parts by weight: 100-120 parts of polypropylene resin, 0.1-1 part of a photodegradation agent, and the photodegradation agent is tungsten Iron acid. Ferric eleostearate contains three conjugated double bonds, and iron ions are used as photosensitizers. Ferric eleostearate can absorb most of the short-wavelength ultraviolet light and has outstanding absorption ability, so that eleostearate can absorb enough energy from light. After obtaining enough energy, ferric eleostate excites iron ions to form an excited state, and the excited state iron ions interact with polypropylene to promote polypropylene to generate a large number of free radicals, and the generated free radicals will promote the degradation rate of polypropylene. The excited state iron ions will return to the normal state of iron ions after promoting the generation of free radicals in polypropylene, and continue to cooperate with eleostearic acid to absorb ultraviolet light, and the cycle is carried out. The photodegradation rate of polypropylene is greatly improved.
Owner:YUEYANG XINGCHANG PETRO CHEM

Preparation method of bismuth tungstate and cadmium sulfide hybrid nanocrystals

The invention relates to the fields of polymer materials, semiconductors, photocatalysis, photovoltaic industry and the like, in particular to a preparation method of bismuth tungstate and cadmium sulfide hybrid nanocrystals. The preparation method comprises the following steps: preparing four polymer vesicles containing soluble bismuth salt, soluble tungstate, soluble cadmium salt and soluble sulfide through an amphiphilic polymer, dispersing to form CdS / Bi2WO6 precursor polymer vesicles, and finally, carrying out heat treatment to obtain the hybrid nanocrystal containing clustered bismuth tungstate and acicular cadmium sulfide.
Owner:CHANGZHOU UNIV
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