Preparation method of organic tin-free chlorine ether resin
A technology of chloroether resin and organotin, which is applied to the emulsion polymerization preparation of chloroether resin and the preparation field of chloroether resin, can solve the problems such as the limitation of the application field of chloroether resin and the use of organic tin compounds, and achieves short reaction time, The effect of high polymerization rate and good thermal stability
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Embodiment 1
[0036]Add 150g of deionized water, 1.5g of sodium lauryl sulfate, 0.25g of sodium sulfite and 0.8g of sodium bicarbonate into the polymerization kettle, stir, raise the temperature to 54°C, add 0.8g of ammonium persulfate, and start to drop continuously from 50g A mixture of deionized water, 2.5g sodium lauryl sulfate, 0.9g sodium bicarbonate, 75g vinyl chloride, 25g isobutyl vinyl ether and 3.2g glycidyl tert-carbonic acid ester was added for 5 hours to react with 1.6g epoxy Soybean oil, and after heat preservation and pressure reduction, stop polymerization, recovery, demulsification, washing, dehydration, and drying to obtain chloroether resin. The measured viscosity of the 20% toluene solution was 45 mPa.s.
Embodiment 2
[0038] Add 150g of deionized water, 1.5g of sodium lauryl sulfate, 0.35g of sodium bisulfite and 0.8g of sodium carbonate into the polymerization kettle, stir, raise the temperature to 45°C, add 0.9g of potassium persulfate, and start to drop continuously A mixture consisting of 50 g deionized water, 2.5 g sodium lauryl sulfate, 0.9 g sodium bicarbonate, 80 g vinyl chloride, 20 g isobutyl vinyl ether, and 2 g 2,3-epoxypropyl acrylate, reaction 6 Add 2g of epoxy linseed oil every hour, and after heat preservation and pressure reduction, stop polymerization, recover, demulsify, wash, dehydrate, and dry to obtain chloroether resin. The measured viscosity of the 20% toluene solution was 60 mPa.s.
Embodiment 3
[0040] Add 150g of deionized water, 1.5g of sodium lauryl sulfate, 0.25g of sodium sulfite and 0.8g of sodium bicarbonate into the polymerization kettle, stir, raise the temperature to 60°C, add 0.7g of ammonium persulfate, and start to continuously drop from 50g Deionized water, 2.5 g sodium lauryl sulfate, 0.9 g sodium carbonate, 65 g vinyl chloride, 35 g isobutyl vinyl ether, 0.8 g glycidyl methacrylate, and 1.1 g acrylate-2,3-epoxypropylene Add 2.2g of epoxidized soybean oil to the mixture composed of ester, and after heat preservation and pressure reduction, stop polymerization, recover, demulsify, wash, dehydrate, and dry to obtain ether resin. The measured viscosity of the 20% toluene solution was 25 mPa.s.
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