Molecular sieve catalyst for preparing olefins from organic oxygen-containing compounds and its preparation method and method for preparing olefins from organic oxygen-containing compounds

A technology of molecular sieves and compounds, which is applied in the fields of organic oxygenates, molecular sieve catalysts for organic oxygenates to olefins and their preparation, and organic oxygenates for olefins. It can solve the problems of low selectivity of propylene and butene and unsuitable catalysts, etc. , to achieve the effects of increased selectivity, slow coking deactivation speed, and high wear strength

Active Publication Date: 2021-11-05
CHNA ENERGY INVESTMENT CORP LTD +1
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0015] The purpose of the present invention is to overcome the defects in the prior art that the selectivity of methanol conversion to propylene and butene is low and the prepared catalyst is not suitable for fluidized bed systems, and to provide a molecular sieve catalyst for the production of olefins from organic oxygen-containing compounds and its Process for the preparation and process of producing olefins from organic oxygenates

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Molecular sieve catalyst for preparing olefins from organic oxygen-containing compounds and its preparation method and method for preparing olefins from organic oxygen-containing compounds
  • Molecular sieve catalyst for preparing olefins from organic oxygen-containing compounds and its preparation method and method for preparing olefins from organic oxygen-containing compounds
  • Molecular sieve catalyst for preparing olefins from organic oxygen-containing compounds and its preparation method and method for preparing olefins from organic oxygen-containing compounds

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0038] The invention provides a method for preparing a molecular sieve catalyst for producing olefins from an organic oxygen-containing compound, the method comprising:

[0039] (1) mixing the first binder with an acid, so that the first binder is peptized;

[0040] (2) mixing the second binder with the first binder sol prepared in step (1) to obtain a mixed binder sol;

[0041] (3) Mix high-silicon ZSM-5 molecular sieve, mixed binder sol and carrier and perform aging treatment;

[0042] (4) The slurry obtained by aging treatment is spray-dried and molded and roasted successively;

[0043] The weight ratio of the ZSM-5 molecular sieve, the first binder, the second binder, the carrier and the acid is 1:0.1-0.5:0.05-0.3:0.5-1.5:0.01-0.25.

[0044] Among them, the preparation method of high-silicon ZSM-5 molecular sieve includes: sequentially mixing liquid alkaline silicon source, aluminum source, ZSM-5 molecular sieve seed crystal, template agent, alkali, urea and water, aging...

Embodiment

[0086] The determination of X-ray diffraction (XRD) crystal phase diagram was performed on a Bruker D8ADVANCE X-ray diffractometer.

[0087] The scanning electron microscope used was a FEI Company Nova NanoSEM 450 model.

preparation example 1

[0089] (1) Weigh 20g of urea (AR Sinopharm Chemical Reagent Co., Ltd.) and 0.9g of seed crystals (ZSM-5 molecular sieve, the same as other examples), add 54g of deionized water to mix, stir well and then add 1.824g of NaOH (AR Sinopharm Group Chemical Reagent Co., Ltd.) and 49.36g tetrapropylammonium hydroxide (25% aqueous solution, industrial grade), after stirring for 1h, add 0.08g sodium aluminate (AR Sinopharm Group Chemical Reagent Co., Ltd.), continue stirring for 10min and add 60.8 g silica sol (30%, industrial grade, pH value is 9), that is, the molar ratio of liquid alkaline silicon source, aluminum source, templating agent, alkali, urea and water is 1:0.0016:0.2:0.15:0.9:24.4, ZSM-5 Molecular Sieve Seed and SiO in Liquid Alkaline Silicon Source 2 The weight ratio of = 5:100. Aging of the obtained mixed solution at room temperature for 16 hours, the aged reaction solution was transferred into a high-pressure reactor, crystallized at 165°C for 24 hours, washed 5 times...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
specific surface areaaaaaaaaaaa
Login to view more

Abstract

The invention relates to the field of catalysts for converting organic oxygen-containing compounds to olefins, and discloses a molecular sieve catalyst for preparing organic oxygen-containing compounds to olefins, a preparation method thereof, and a method for preparing organic oxygen-containing compounds to olefins. The preparation method of the olefin molecular sieve catalyst prepared from organic oxygen-containing compounds: mixing the first binder with an acid to make the first binder peptize; mixing the second binder with the obtained first binder sol to prepare Obtain a mixed binder sol; mix the high-silica ZSM-5 molecular sieve, mixed binder sol, and carrier and perform aging treatment; spray-dry, shape and roast the obtained slurry in sequence; obtain an organic oxygen-containing compound converted into an olefin Catalyst; also relates to a molecular sieve catalyst for preparing olefins from organic oxygen-containing compounds and a method for preparing olefins. The catalyst of the invention has excellent activity and service life, is more suitable for fluidized bed reactors, and can significantly improve the selectivity of low-carbon olefins when used in the reaction of organic oxygen-containing compounds to olefins.

Description

technical field [0001] The invention relates to the field of catalysts for converting organic oxygen-containing compounds, such as methanol and / or dimethyl ether, to olefins, especially low-carbon olefins, such as propylene and / or butene, in particular, to a molecular sieve for producing olefins from organic oxygen-containing compounds Catalyst and its preparation method and method for producing olefins from organic oxygen-containing compounds. Background technique [0002] Trienes and triphenyls are important basic raw materials for the modern chemical industry. The existing low-carbon olefin production technology relies heavily on petroleum resources, and the traditional methods for preparing ethylene, propylene, and butene are light oil (naphtha, light diesel oil) cracking technology and refinery by-products. In recent years, the total amount of C4 resources in my country has increased with the development of oil refining, steam cracking to ethylene production capacity a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): B01J29/40C07C11/06C07C11/08C07C1/20
CPCB01J29/40B01J35/1019B01J2229/10B01J2229/12B01J2229/38C07C1/20C07C11/06C07C11/08Y02P20/52
Inventor 邢爱华张新锋姜继东冯琦瑶
Owner CHNA ENERGY INVESTMENT CORP LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products