The invention relates to a preparation method of a
gasoline desulfurization
microsphere catalyst. The method is characterized by: adding activated
zinc oxide accounting for 30-60wt% of the total
dry basis of the catalyst, expanded
perlite powder and / or diatomite accounting for 5-20wt% of total
dry basis, and a
nickel salt, in terms of
nickel oxide, accounting for 10-30wt% of the total
dry basis into chemical water for mixing and beating, and raising the temperature to 60-90DEG C, at the same time continuously adding a
sodium aluminate solution and an aluminum
sulfate solution with a concentration of 1-20 wt%, adjusting and controlling the
flow ratio of the two solutions to maintain the pH of the whole
slurry at 7.5-9.5; and with the total amount of
alumina in the
sodium aluminate and aluminum
sulfate accounting for 5-20wt% of the total dry basis of the catalyst, atomizing the uniformly mixed material
slurry into microspheres with an average particle
diameter of 50-80 microns, then conducting washing with chemical water till
sodium oxide is less than 1.0wt%, and after
drying, carrying out
roasting at a temperature of 450-650DEG C for 0.5-4 hours. The prepared catalyst has a pore volume of 0.1-0.4 ml / g, and is characterized by good strength,
high activity, large
sulfur capacity, as well as low loss of liquid yield and
gasoline octane number in a
gasoline desulfurization reaction.