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Performance diagnosis method for fuel cell

A fuel cell and performance technology, used in fuel cells, circuits, measuring electricity, etc., can solve the problems of inaccurate feedback of the working state of the stack, errors, affecting the accuracy of diagnostic results, etc., to shorten the sampling period and achieve high accuracy , the effect of improving the accuracy

Active Publication Date: 2018-02-09
CHINA JILIANG UNIV
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  • Abstract
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Problems solved by technology

However, most of the auxiliary variables selected by the existing diagnostic methods are still the external characteristics of PEMFC, which cannot accurately feed back the internal working status of the stack.
At the same time, there is a certain error between the amount of water produced by the internal reaction of the stack obtained by modeling and the actual one, which will affect the accuracy of the diagnostic results.

Method used

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Embodiment Construction

[0048] Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings. First, a fuel cell performance diagnosis method will be described. Next, a fuel cell performance diagnosis recovery method will be described.

[0049] The fuel cell performance diagnosis method of the present invention comprises the following steps:

[0050] Step 1: If figure 1 As shown, when the fuel cell is in a stable operating state, based on the PEMFC equivalent circuit, determine the high-frequency signal frequency f 1 , f 2 . f 1 is the frequency corresponding to the intersection of the impedance spectrum and the real axis, and f 1 ≥20kHz; calculated PEMFC high frequency corner frequency f 2 , as shown in formula (1):

[0051]

[0052] where: R a =R f +R d ;

[0053] Step 2: Transmit two sets of high frequency (f 1 , f 2 ) AC signal and sequentially collect the response signal of the fuel cell, and calculate the impedance Z of the corresp...

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Abstract

The invention discloses a performance diagnosis method for a fuel cell. The method comprises the following steps: introducing an impedance secant angular difference value delta alpha as a performancediagnosis judgment index of the fuel cell; using an improved electrochemical impedance spectroscopy method to solve to obtain the current impedance secant angle alpha t; at the same time, based on anestablished model, calculating to obtain a secant angle alpha 0 under the normal condition under the current density, temperature and humidity currently by a controller; and judging the current watermanagement state of the fuel cell by the controller according to the difference value delta alpha of the two secant angles, and generating a control signal to perform humidity adjustment on the fuel cell, so as to ensure that the fuel cell is in a normal working condition. The performance diagnosis method for the fuel cell provided by the invention can quickly and accurately judge the water management state of the fuel cell and recover the performance of the fuel cell under the condition of only using an alternating current signal generator and a data acquisition system, and improve the outputperformance of the fuel cell.

Description

Technical field: [0001] The invention relates to a performance diagnosis method of a fuel cell. Background technique: [0002] Driven by economic globalization, the world economy has developed by leaps and bounds. Energy shortages have restricted economic development, and energy issues have become a key problem that the world needs to solve urgently. At the same time, the environmental problems caused by the increasing consumption of traditional energy are also threatening the survival of human beings. At this time, it is urgent to develop new energy to replace traditional energy. Among all the alternatives to fossil fuels, fuel cells have become the most promising energy supply method due to their good operating performance and environmental friendliness for power generation. The proton exchange membrane fuel cell (Proton Exchange Membrane Fuel Cell, PEMFC) has the advantages of no pollution, zero noise and stable power, suitable for large-scale commercial development of h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/04992H01M8/04828G01R31/36
CPCG01R31/3648H01M8/04835H01M8/04992Y02E60/50
Inventor 卫东徐创李志勇王央康高志常亚文
Owner CHINA JILIANG UNIV
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