A kind of mo-si-c alloy rod and preparation method thereof

An alloy rod, mo-si-c technology, applied in the field of Mo-Si-C alloy rod and its preparation, can solve the problems of poor high temperature strength, loss of function, limited prospects, etc., to achieve high hardness, low density, The effect of lowering the sintering temperature

Active Publication Date: 2018-11-02
NORTHWEST INSTITUTE FOR NON-FERROUS METAL RESEARCH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the poor high-temperature strength of these molybdenum alloy materials limits its application. This is due to the fact that the existing strengthening and toughening mechanisms of these materials are at high temperatures under the conditions of long-term dynamic thermal / mechanical coupling loading in ultra-high temperature environments. may have lost its usefulness in service
Therefore, although the high-temperature mechanical properties and fatigue strength of traditional molybdenum alloys can be improved to a certain extent through alloying modification, the prospect of greatly improving its mechanical properties and its application in the next generation of high thrust-to-weight ratio engines is limited.

Method used

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  • A kind of mo-si-c alloy rod and preparation method thereof
  • A kind of mo-si-c alloy rod and preparation method thereof

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Effect test

Embodiment 1

[0025] The Mo-Si-C alloy rod in this embodiment is made of the following atomic percentages of raw materials: 20% silicon, 25% carbon, and the balance is molybdenum and unavoidable impurities.

[0026] The method for preparing Mo-Si-C alloy rods in this embodiment comprises the following steps:

[0027] Step 1. Put silicon powder, carbon powder and molybdenum powder in a ball mill, use absolute ethanol as a dispersant, and ball mill for 30 hours at a speed of 300r / min and a ball-to-material ratio of 10:1 by mass. Finally, dry it under vacuum conditions at 85°C to obtain mixed powder; the volume of the absolute ethanol is twice the sum of the mass of silicon powder, carbon powder and molybdenum powder, and the unit of the volume of absolute ethanol is mL. Silicon powder, carbon powder The unit of the total mass of powder and molybdenum powder is g; the mass purity of the silicon powder is not less than 99.5%, the mass purity of the carbon powder is not less than 99.5%, and the ...

Embodiment 2

[0033] The Mo-Si-C alloy rod in this embodiment is made of the following atomic percentages of raw materials: 25% silicon, 35% carbon, and the balance is molybdenum and unavoidable impurities.

[0034] The method for preparing Mo-Si-C alloy rods in this embodiment comprises the following steps:

[0035] Step 1. Put silicon powder, carbon powder and molybdenum powder in a ball mill, use absolute ethanol as a dispersant, and ball mill for 40 hours at a speed of 400r / min and a ball-to-material ratio of 15:1 by mass. Finally, dry under vacuum conditions at 90°C to obtain mixed powder; the volume of the absolute ethanol is 3 times the total mass of silicon powder, carbon powder and molybdenum powder, and the unit of the volume of absolute ethanol is mL, silicon powder, carbon powder The unit of the total mass of powder and molybdenum powder is g; the mass purity of the silicon powder is not less than 99.5%, the mass purity of the carbon powder is not less than 99.5%, and the mass p...

Embodiment 3

[0041] The Mo-Si-C alloy rod in this embodiment is made of the following atomic percentages of raw materials: 15% silicon, 15% carbon, and the balance is molybdenum and unavoidable impurities.

[0042] The method for preparing Mo-Si-C alloy rods in this embodiment comprises the following steps:

[0043] Step 1. Put silicon powder, carbon powder and molybdenum powder in a ball mill, use absolute ethanol as a dispersant, and ball mill for 20 hours at a speed of 200r / min and a ball-to-material ratio of 5:1 by mass ratio. Finally, dry under vacuum conditions at 80°C to obtain mixed powder; the volume of the absolute ethanol is 1 time of the total mass of silicon powder, carbon powder and molybdenum powder, and the unit of the volume of absolute ethanol is mL. The unit of the total mass of powder and molybdenum powder is g; the mass purity of the silicon powder is not less than 99.5%, the mass purity of the carbon powder is not less than 99.5%, and the mass purity of the molybdenum...

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Abstract

The invention discloses a Mo-Si-C alloy rod which is prepared from the following raw materials in atom percentage: 15-25% of silicon, 15-35% of carbon and the balance of molybdenum and inevitable impurities. The invention further discloses a method for preparing the Mo-Si-C alloy rod. The method comprises the following steps: I, performing ball milling on raw material powder, and drying so as to obtain mixed powder; II, pressing and molding the mixed powder so as to obtain a blank, and performing sintering treatment so as to obtain a Mo-Si-C alloy sintering body; III, smelting the Mo-Si-C alloy sintering body by using electronic beams so as to obtain Mo-Si-C alloy ingots, and cutting the ingots so as to obtain half-finished rods; and IV, smelting the half-finished rods in an electronic beam area, thereby obtaining the Mo-Si-C alloy rod. The Mo-Si-C alloy rod disclosed by the invention has the characteristics of high purity and low oxygen quality content, is very high in hardness and tension strength and excellent in fatigue resistance and high temperature strength, and has wide application prospects in super high temperature environments.

Description

technical field [0001] The invention belongs to the technical field of alloy preparation, and in particular relates to a Mo-Si-C alloy rod and a preparation method thereof. Background technique [0002] With the development of aerospace technology and the improvement of flight distance and flight speed of various new aircraft, the engine is required to have a higher thrust-to-weight ratio and work efficiency. People have proposed more and more high-temperature structural materials with light weight, high strength and oxidation resistance high demands. However, the nickel-based superalloy used in existing engines is limited by its own melting point, and the upper limit of the service temperature is only 1100°C. Therefore, it is imperative to develop ultra-high temperature materials that can replace nickel-based superalloys. Molybdenum alloys have been extensively studied in the 1950s as candidate materials for aerospace, nuclear engineering and aircraft engines. Although m...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C27/04C22C1/02C22C1/10B22F3/10
CPCB22F3/1007B22F2998/10C22C1/1036C22C27/04B22F1/0003B22F3/02
Inventor 喻吉良刘辉张如王晖张文李来平郑欣李延超
Owner NORTHWEST INSTITUTE FOR NON-FERROUS METAL RESEARCH
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