Unlock instant, AI-driven research and patent intelligence for your innovation.

SCR (selective catalytic reduction) catalyst and preparation method thereof

A technology of SCR catalyst and high-temperature activation, which is applied in chemical instruments and methods, physical/chemical process catalysts, separation methods, etc., can solve problems such as narrow operating temperature window, threat to human health, poor selectivity, etc., and achieve stable selectivity and catalytic Good effect and high selectivity

Inactive Publication Date: 2018-05-25
LUOYANG SHENJIA KILN
View PDF5 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are many problems with this catalyst, such as the biological toxicity of V 2 o 5 Shedding occurs during use, threatening human health, narrow operating temperature window, high temperature section N 2 Poor selectivity, at high temperature V 2 o 5 volatilization and TiO 2 The crystal transformation leads to poor stability

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The activated carbon carrier was placed in a muffle furnace at 500°C for high-temperature activation, and the activation time was 3 hours; the MnO 2 and WO 3 The soluble salt of the solution is made into a solution, and then the activated carbon is put into the active component solution for impregnation. When impregnated, the ratio of the mass of activated carbon to the volume of the active component solution is 1:4; after 20 hours of immersion, the activated carbon and activated carbon The components were activated in a microwave oven at 500W for 6 minutes, and then the activated carbon was put in a muffle furnace and calcined at 600° C. for 3 hours to obtain the SCR catalyst.

[0029] The catalyst prepared above was tested for activity on a catalyst activity evaluation device. The test conditions were: temperature 200-400°C, reaction gas simulated motor vehicle exhaust, and reaction space velocity 40000h -1 , the results show that in the temperature range of 200-400 ...

Embodiment 2

[0031] The activated carbon carrier was placed in a muffle furnace at 700°C for high-temperature activation, and the activation time was 2 hours; the MnO 2 and MoO 3 The soluble salt of the solution is made into a solution, and then the activated carbon is put into the active component solution for impregnation. When impregnated, the ratio of the mass of activated carbon to the volume of the active component solution is 1:4; after immersion for 15 hours, the activated carbon and activated The components were activated in a microwave oven at 350W for 6 minutes, and then activated carbon was placed in a muffle furnace and calcined at 670° C. for 3 hours to obtain the SCR catalyst.

[0032] The catalyst prepared above was tested for activity on a catalyst activity evaluation device. The test conditions were: temperature 200-400°C, reaction gas simulated motor vehicle exhaust, and reaction space velocity 40000h -1 , the results show that in the temperature range of 200-400 °C, NO...

Embodiment 3

[0034] The activated carbon carrier was placed in a muffle furnace at 600°C for high-temperature activation, and the activation time was 2 hours; the MoO 3 and WO 3 The soluble salt of the solution is made into a solution, and then the activated carbon is put into the active component solution for impregnation. When impregnated, the ratio of the mass of activated carbon to the volume of the active component solution is 1:4; after 20 hours of immersion, the activated carbon and activated carbon The components were activated in a microwave oven at 400W for 8 minutes, and then activated carbon was put in a muffle furnace and calcined at 650° C. for 3 hours to obtain the SCR catalyst.

[0035] The catalyst prepared above was tested for activity on a catalyst activity evaluation device. The test conditions were: temperature 200-400°C, reaction gas simulated motor vehicle exhaust, and reaction space velocity 40000h -1 , the results show that in the temperature range of 200-400 °C, ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to an SCR catalyst and a preparation method thereof. The SCR catalyst is composed of a catalyst carrier and active components, wherein the catalyst carrier is activated at high temperature, impregnated in active component solution and then activated and calcinated into the SCR catalyst; the active components are a mixture of two or three of MnO2, WO3 and MoO3, and the weightof the active component is 30-40% of that of the catalyst carrier. According to the SCR catalyst, activated carbon which has a certain absorbing function serves as the catalyst carrier and can furtherimprove the absorbing capability after being activated to absorb and remove nitrogen oxide; meanwhile, the active components are combination of MnO2, WO3 and MnO3, wherein WO3 and MoO3 are antioxidant and anti-poisoning auxiliary components, and MnO3 is high in reducibility, so that the prepared SCR catalyst is stable in selectivity, high in activity, long in service life and good in catalytic effects. The preparation method of the SCR catalyst simplifies the production process, is energy-saving and environmentally friendly, reduces the production cost and improves the yield rate of the SCR catalyst.

Description

technical field [0001] The invention relates to the technical field of catalyst preparation, in particular to an SCR catalyst and a preparation method thereof. Background technique [0002] The Selective Catalytic Reduction (SCR) flue gas denitration process has been widely used in the reduction of nitrogen oxides in thermal power plants in my country. At present, more than 90% of the nitrogen oxides reduction at home and abroad adopts the SCR flue gas denitrification process. Denitrification catalyst is an important raw material for SCR flue gas denitrification process. [0003] At present, the SCR catalysts for industrial application are mainly WO 3 or MoO 3 Doped V 2 o 5 / TiO 2 catalyst. However, there are many problems with this catalyst, such as the biological toxicity of V 2 o 5 Shedding occurs during use, threatening human health, narrow operating temperature window, high temperature section N 2 Poor selectivity, at high temperature V 2 o 5 Volatilization a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): B01J23/34B01D53/90B01D53/56
CPCB01D53/8628B01D53/90B01D2255/2073B01D2255/20769B01D2255/20776B01J23/34
Inventor 王红超
Owner LUOYANG SHENJIA KILN