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Building wall tile modified by superhydrophobic nanotechnology and preparation method thereof

A nanotechnology and super-hydrophobic technology, which is applied in the field of architectural wall tiles modified by superhydrophobic nanotechnology and its preparation, can solve the problems of expensive raw materials, poor wear resistance, and high production cost of hydrophobic wall tiles, and achieve good aesthetics. The effect of not easy to fall off and low production cost

Active Publication Date: 2018-06-15
ZHEJIANG OCEAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention aims to overcome the problems of expensive raw materials, high preparation cost and poor wear resistance of hydrophobic wall tiles in the prior art, and provides a wall tile with low raw material price, low preparation cost, bactericidal properties and good wear resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A building wall tile modified by superhydrophobic nanotechnology, the wall tile includes a green tile substrate and a ceramic glaze coated on the surface of the green tile substrate, and the ceramic glaze is made of the following raw materials in parts by weight: 70 parts of vitreous frit, 7 parts of metallic copper micron particles with an average particle size of 1 μm, and Fe with a particle size of 2 μm 2 o 3 2 parts of micron particles, 5 parts of kaolin.

[0022] Wherein, the glass frit is made of the following raw materials in parts by weight: 9 parts of CaO, 8 parts of ZnO, 8 parts of Al 2 o 3 7 copies, B 2 o 3 0.5 parts, SiO 2 56 copies.

[0023] A method for preparing a building wall tile modified by superhydrophobic nanotechnology, comprising the following steps:

[0024] (1) After mixing the ceramic glaze, sodium tripolyphosphate with a mass fraction of 0.1% of the ceramic glaze, and carboxymethyl cellulose with a mass fraction of 0.1% of the ceramic...

Embodiment 2

[0028] A building wall tile modified by superhydrophobic nanotechnology, the wall tile includes a green tile substrate and a ceramic glaze coated on the surface of the green tile substrate, and the ceramic glaze is made of the following raw materials in parts by weight: 72 parts of vitreous frit, 10 parts of metallic copper micron particles with an average particle size of 2.2 μm, Fe with a particle size of 4 μm 2 o 3 3 parts of micron particles, 6 parts of kaolin.

[0029] Among them, the glassy frit is made of the following raw materials in parts by weight: 10 parts of CaO, 1 part of BaO, 9 parts of ZnO, 1 part of PbO, 1 part of Al 2 o 3 7 copies, B 2 o 3 1 part, SiO 2 56 copies.

[0030] A method for preparing a building wall tile modified by superhydrophobic nanotechnology, comprising the following steps:

[0031] (1) After mixing the ceramic glaze, sodium tripolyphosphate with a mass fraction of 0.15% of the ceramic glaze, and carboxymethyl cellulose with a mass...

Embodiment 3

[0035] A building wall tile modified by superhydrophobic nanotechnology, the wall tile includes a green tile substrate and a ceramic glaze coated on the surface of the green tile substrate, and the ceramic glaze is made of the following raw materials in parts by weight: 75 parts of vitreous frit, 12 parts of metallic copper micron particles with an average particle size of 2.5 μm, and Fe with a particle size of 5 μm 2 o 3 4 parts of micron particles, 7 parts of kaolin.

[0036] Among them, the glass frit is made of the following raw materials in parts by weight: 11 parts of CaO, 2 parts of BaO, 10 parts of ZnO, 1.2 parts of PbO, 1.2 parts of Al 2 o 3 8 copies, B 2 o 3 1.5 parts, SiO 2 60 parts, ZrO 2 0.5 servings.

[0037] A method for preparing a building wall tile modified by superhydrophobic nanotechnology, comprising the following steps:

[0038] (1) After mixing the ceramic glaze, sodium tripolyphosphate with a mass fraction of 0.2% of the ceramic glaze, and c...

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Abstract

The invention relates to the technical field of ceramic materials and particularly relates to a building wall tile modified by a superhydrophobic nanotechnology and a preparation method thereof. The wall tile comprises a green tile substrate and ceramic glaze coating the surface of the green tile substrate. The ceramic glaze is prepared from 70-80 parts by weight of glass frit, 7-15 parts by weight of metal copper microparticles, 2-8 parts by weight of Fe2O3 microparticles, and 5-10 parts by weight of kaolin. Through a spray-coating method, the prepared suspension liquid coats the surface of the green tile substrate. The building wall tile has strong super hydrophobic performances, antibacterial effects and friction resistance.

Description

technical field [0001] The invention relates to the technical field of ceramic materials, in particular to a building wall tile modified by superhydrophobic nanotechnology and a preparation method thereof. Background technique [0002] In recent years, with the urgent need for energy saving and improving the durability of building materials, the application and development of superhydrophobic building materials is imminent. Nano-hydrophobic ceramic glazes can be preformed by adding metal nanoparticles loaded on sepiolite fibers. This method is basically consistent with the standard manufacturing process of tiles, but the nanoparticles of sepiolite on metal are due to high product cost and low market supply. A new challenge is to develop new nano-functional glazes using existing materials on the market. At present, self-cleaning surface products will be a relatively high-end product in the market, both for the public and for manufacturing companies. The main issues that ha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C8/18C04B41/86C04B33/34
CPCC03C8/18C04B33/34C04B41/009C04B41/5022C04B41/86C04B41/4539C04B33/13
Inventor 张海龙
Owner ZHEJIANG OCEAN UNIV
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