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Method for treating titanium white waste acid by steel slag

A technology of titanium dioxide waste acid and steel slag, which is applied in natural water treatment, water treatment parameter control, chemical instruments and methods, etc., can solve the problems that the sulfuric acid titanium dioxide industry is difficult to develop healthily, and achieve the solution that cannot be achieved at low cost and large-scale The effect of consumption, good promotion prospect and low cost

Inactive Publication Date: 2018-07-10
NORTHEASTERN UNIV LIAONING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Panzhihua is known as "the capital of vanadium and titanium in China". In 2016, Panzhihua's sulfuric acid titanium dioxide production capacity was 334,000 tons. During the production of one ton of titanium dioxide, the hydrolysis of metatitanic acid will produce 8 to 10 tons of waste acid, of which 25 to 35% are returned Process reuse, the actual discharge of waste acid is 6 to 6.5 tons; according to statistics, based on the current titanium dioxide production, the total waste acid discharge is as high as 1.8 million tons; now, the waste acid treatment generally adopts the calcium oxide neutralization method, neutralization The waste acid produced by one ton of titanium dioxide needs to consume 3 to 3.5 tons of calcium oxide and generate 8 tons of wet slag; based on an annual output of 300,000 tons of titanium dioxide, 2.4 million tons of waste residue will be generated, which will consume millions of tons of calcium oxide; The price of one ton of calcium oxide is about 160 yuan, and this cost is 160 million yuan; how to consume titanium dioxide waste acid on a large scale at low cost has become a technical problem in the sulfuric acid titanium dioxide industry. It will be difficult for the titanium dioxide industry to develop healthily; therefore, there is an urgent need for a method that can process a large amount of titanium dioxide waste acid at low cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Put 100g of sulfuric acid mass percent 20% titanium white waste acid into a closed reactor, add steel slag 11.43g for the first time, the calcium oxide mass percent in the described steel slag is 50%, particle size 60 mesh; The pH value of the mixed material was measured to be 4.3; 11.43 g of high steel slag was added again, and the reaction was stirred at 60°C for 30 minutes. At this time, the pH value of the mixed material was measured to be 7.7; the reaction was stopped and the precipitation was complete for 10 minutes, and the solid phase was separated by filtration and the liquid phase; the liquid phase is directly discharged or returned to be used as industrial water, and the solid phase sediment is washed and dried and thrown to the slag yard.

Embodiment 2

[0022] Put 120g of sulfuric acid mass percent 18% titanium white waste acid in a closed reactor, add 30.86g of steel slag, the mass percent of calcium oxide in the steel slag is 40%, and the particle size is 200 mesh; after stirring and reacting at 30°C for 120 minutes, The measured pH value is 7.9; the reaction is stopped and the precipitation is complete for 8 minutes, and the solid phase and liquid phase are separated by filtration; the liquid phase is directly discharged or returned for use as industrial water, and the solid phase precipitate is washed and dried and then thrown to the slag yard.

Embodiment 3

[0024] The mass percent concentration of sulfuric acid is 22% and 90 g of titanium white waste acid is placed in a closed reactor, and 11 g of steel slag is added. The mass percent of calcium oxide in the steel slag is 35 percent, and the particle size is 200 mesh; after 20 minutes of stirring reaction at 90 ° C, At this time, the pH value of the mixed material was 2.3; 12.33 g of steel slag was added again, and stirred and reacted at 90° C. for 20 minutes. At this time, the pH value of the mixed material was measured to be 4.7; 9.03 g of steel slag was added for the third time, stirred and reacted at 90° C. for 20 minutes. Minutes, at this time the measured pH value is 7.6; stop the reaction and let it stand for 8 minutes to precipitate completely, filter and separate the solid phase and liquid phase; the liquid phase is directly discharged or returned for use as industrial water, and the solid phase precipitate is washed and dried and thrown into the slag field.

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Abstract

The invention relates to a method for treating titanium white waste acid by steel slag. The steel slag is added into the titanium white waste acid; stirring reaction is performed in a sealed reactor for 10 to 120 min at the reaction temperature of 20 to 90 DEG C; when the pH value of the mixed material of the steel slag and the titanium white waste acid is 6 to 8, the reaction is stopped; still standing precipitation is performed; a solid phase and a liquid phase are obtained. The method provided by the invention solves the technical and environment protection problem that the titanium white waste acid cannot realize low-cost large-scale consumption; the social benefits are very obvious; good popularization prospects are realized.

Description

technical field [0001] The invention belongs to the field of environmental protection and chemical industry, and specifically designs a method for treating titanium white waste acid by using steel slag. Background technique [0002] Panzhihua is known as "the capital of vanadium and titanium in China". In 2016, Panzhihua's sulfuric acid titanium dioxide production capacity was 334,000 tons. During the production of one ton of titanium dioxide, the hydrolysis of metatitanic acid will produce 8 to 10 tons of waste acid, of which 25 to 35% are returned Process reuse, the actual discharge of waste acid is 6 to 6.5 tons; according to statistics, based on the current titanium dioxide production, the total waste acid discharge is as high as 1.8 million tons; now, the waste acid treatment generally adopts the calcium oxide neutralization method, neutralization The waste acid produced by one ton of titanium dioxide needs to consume 3 to 3.5 tons of calcium oxide and generate 8 tons o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04C02F103/34
CPCC02F1/52C02F1/66C02F2103/34C02F2209/06C02F2305/00
Inventor 张廷安张伟光吕国志豆志河刘燕
Owner NORTHEASTERN UNIV LIAONING