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Preparation method and regeneration method of composite ammonia nitrogen adsorbent

An adsorbent and composite technology, applied in chemical instruments and methods, adsorption water/sewage treatment, other chemical processes, etc., can solve the problems of limiting the application of ammonia nitrogen wastewater, adsorption rate and regeneration rate are not ideal, and achieve excellent ammonia nitrogen adsorption The effect of increasing the amount, increasing the adsorption amount and adsorption rate, and increasing the adsorption capacity

Active Publication Date: 2021-06-04
SHANGHAI NAT ENG RES CENT FORNANOTECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although commonly used adsorbents have good ammonia nitrogen adsorption capacity, their adsorption rate and regeneration rate are still not ideal, which limits their application in ammonia nitrogen wastewater treatment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Add 10 g of a mixture containing 10% diatomaceous earth, 10% activated carbon, and 80% zeolite into 100 mL of NH 4 Cl and KH 2 PO 4 Each 1 mol / L solution was stirred for 1 h; 5 mol / L MgCl was added dropwise 2 Solution 24 mL, adjust the pH to 10 with 5 mol / L NaOH solution after the dropwise addition; after stirring for 10 min, the solid matter was collected by filtration, 40 o Dry and mature at C for 4 h, and then at 100 o The high-efficiency composite ammonia-nitrogen adsorbent 1 was obtained by roasting at C for 2 h, and the ammonia volatilized during the roasting process was absorbed by dilute sulfuric acid.

[0033] The experimental data of ammonia nitrogen adsorption and composite ammonia nitrogen adsorbent regeneration results are shown in Table 1.

Embodiment 2

[0035] Add 10 g of a mixture containing 10% activated carbon and 90% zeolite into 100 mL of NH 4 Cl and KH 2 PO 4 Each 1 mol / L solution was stirred for 1 h; 5 mol / L MgCl was added dropwise 2 Solution 24 mL, adjust the pH to 10 with 5 mol / L NaOH solution after the dropwise addition; after stirring for 10 min, the solid matter was collected by filtration, 40 o Dry and mature at C for 4 h, and then at 100 o The high-efficiency composite ammonia-nitrogen adsorbent 2 was obtained by roasting at C for 2 h, and the ammonia volatilized during the roasting process was absorbed by dilute sulfuric acid.

[0036] The experimental data of ammonia nitrogen adsorption and composite ammonia nitrogen adsorbent regeneration results are shown in Table 1.

Embodiment 3

[0038] Add 10 g of zeolite to 100 mL of NH 4 OH and KH 2 PO 4 Each 2 mol / L solution was stirred for 1 h; 10 mol / L MgCl was added dropwise 2 Solution 24 mL, adjust the pH to 10 with 5 mol / L NaOH solution after the dropwise addition; after stirring for 10 min, the solid matter was collected by filtration, 40 o Dry and mature at C for 4 h, and then at 100 o The high-efficiency composite ammonia-nitrogen adsorbent 3 was obtained by roasting at C for 2 h, and the ammonia volatilized during the roasting process was absorbed by dilute sulfuric acid.

[0039] The experimental data of ammonia nitrogen adsorption and composite ammonia nitrogen adsorbent regeneration results are shown in Table 1.

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PUM

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Abstract

The invention relates to the preparation and regeneration method of an efficient composite ammonia nitrogen adsorbent. The method is to combine one or more of diatomite, activated carbon and zeolite in a certain proportion, and then add the mixture to the 4 + 、PO 4 3‑ In the solution, stir to suspend the solid mixture in the solution, add a certain amount of magnesium salt solution dropwise after a period of time, after the dropwise addition, adjust the pH to 9~10, after stirring for a period of time, the solid matter is filtered, dried, roasted, A high-efficiency composite ammonia nitrogen adsorbent is obtained. After the composite ammonia nitrogen adsorbent of the present invention is adsorbed and saturated, the adsorbent can be recycled after being filtered, dried and roasted. The high-efficiency composite ammonia nitrogen adsorbent has excellent ammonia nitrogen adsorption capacity for ammonia nitrogen, and has certain adsorption treatment effects for heavy metals, COD, chroma, etc.; it can be recycled and used, and the regeneration method is simple.

Description

technical field [0001] The invention relates to a preparation method of an adsorbent for wastewater treatment and a regeneration method thereof, in particular to a preparation method of a composite ammonia nitrogen adsorbent and a regeneration method thereof. [0002] technical background [0003] With the rapid development of my country's industrialization and the improvement of national environmental protection awareness, the purification treatment of industrial wastewater has attracted more and more attention. The large amount of nitrogen and phosphorus in wastewater is the main cause of water eutrophication, among which NH 4 -N is considered to be one of the greatest toxins to microorganisms in the wastewater treatment process, so before the biological treatment process of wastewater, NH must be removed or reduced 4 -N concentration. [0004] At present, the treatment methods of ammonia nitrogen wastewater mainly include stripping method, chemical precipitation method, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/20B01J20/28B01J20/30C02F1/28C02F101/16
CPCB01J20/041B01J20/14B01J20/165B01J20/20B01J20/28054C02F1/281C02F2101/16
Inventor 何丹农邓洁童琴代卫国赵昆峰金彩虹
Owner SHANGHAI NAT ENG RES CENT FORNANOTECH