Antibacterial low-VOC (low-volatile organic compound) PBT (polybutylene terephthalate) composite material and preparation method thereof

A composite material and antibacterial agent technology, which is applied in the field of low VOC antibacterial PBT composite materials and its preparation, can solve the problems of unsatisfactory antibacterial performance and demand of PBT materials, achieve good VOC performance, excellent antibacterial performance, and improve VOC performance.

Inactive Publication Date: 2019-01-08
ANHUI JIANGHUAI AUTOMOBILE GRP CORP LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a low-VOC antibacterial PBT composite material and its preparation method to solve the problem that the antibacterial properties of existing PBT materials cannot meet the needs of some aspects

Method used

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  • Antibacterial low-VOC (low-volatile organic compound) PBT (polybutylene terephthalate) composite material and preparation method thereof
  • Antibacterial low-VOC (low-volatile organic compound) PBT (polybutylene terephthalate) composite material and preparation method thereof
  • Antibacterial low-VOC (low-volatile organic compound) PBT (polybutylene terephthalate) composite material and preparation method thereof

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preparation example Construction

[0050] A preparation method of low-VOC antibacterial PBT composite material, comprising the following steps:

[0051] (1) Weigh 60-80 parts of PBT, 4-6 parts of antibacterial agent, 8-10 parts of VOC improved masterbatch, 0.1-0.5 part of antioxidant;

[0052] (2) extruding and granulating the mixture obtained in the step (1) to obtain the PBT composite material.

[0053] The twin-screw extruder in the step (2) includes six temperature zones arranged in sequence, the temperature in the first zone is 200-220°C, the temperature in the second zone is 240-260°C, the temperature in the third zone is 240-260°C, and the temperature in the fourth zone The temperature is 240-260°C, the temperature of the fifth zone is 240-260°C, the temperature of the sixth zone is 240-260°C, the temperature of the head is 240-260°C, and the screw speed is 200-280r / min.

Embodiment 1

[0055] (1) Weigh 60 parts of PBT, 4 parts of antibacterial agent, 8 parts of VOC modified masterbatch, and 0.1 part of Irganox1010;

[0056] (2) Extrude and granulate the mixture obtained in the step (1) to obtain the PBT composite material P1.

[0057] Among them, the temperature and screw speed of each zone of the twin-screw extruder are respectively; the temperature of the first zone is 200°C, the temperature of the second zone is 240°C, the temperature of the third zone is 240°C, the temperature of the fourth zone is 240°C, the temperature of the fifth zone is 240°C, the temperature of the sixth zone is 240°C, The head temperature is 240°C, and the screw speed is 200r / min.

Embodiment 2

[0059] (1) Weigh 80 parts of PBT, 6 parts of antibacterial agent, 10 parts of VOC modified masterbatch, 0.2 part of Irganox1010, 0.2 part of Irganox1330, 0.1 part of Irganox168;

[0060] (2) Extrude and granulate the mixture obtained in the step (1) to obtain the PBT composite material P2.

[0061] Among them, the temperature and screw speed of each zone of the twin-screw extruder are respectively; the temperature of the first zone is 220°C, the temperature of the second zone is 260°C, the temperature of the third zone is 260°C, the temperature of the fourth zone is 260°C, the temperature of the fifth zone is 260°C, the temperature of the sixth zone is 260°C, The head temperature is 260°C, and the screw speed is 280r / min.

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Abstract

The invention relates to an antibacterial low-VOC (low-volatile organic compound) PBT (polybutylene terephthalate) composite material and a preparation method thereof. The antibacterial low-VOC PBT composite material is prepared from components in parts by weight as follows: 60-80 parts of PBT, 4-6 parts of an antibacterial agent, 8-10 parts of VOC modified masterbatch and 0.1-0.5 parts of an antioxidant, wherein the antibacterial agent is a coral reef supported Ag<+> type antibacterial agent. A complex which is prepared from Ag<+> and 1-methyl-2-pyrrolidinone by adopting 1-methyl-2-pyrrolidinone as a stabilizer and 2-hydroxy-1-ethanethiol as a reducing agent is stably dispersed in the solvent, Ag<+> is reduced to zero valence from positive monovalence by 2-hydroxy-1-ethanethiol and is continuously gathered on a nucleus on the coral reef surface under the synergistic effect of 1-methyl-2-pyrrolidinone, and the coral reef supported Ag<+> type antibacterial agent is obtained.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, in particular to a low-VOC antibacterial PBT composite material and a preparation method thereof. Background technique [0002] Polybutylene terephthalate (PBT) is an important thermoplastic material, which is widely used in the fields of automobiles, household appliances, mechanical parts, office supplies and communication equipment. PBT material has the advantages of light weight, non-toxic, odorless and good water absorption. In some specific material application fields, there are not only requirements for antibacterial performance of PBT materials, but also high requirements for VOC performance, which cannot be met by ordinary PBT materials. [0003] In view of this reason, this technical solution innovatively produces a PBT composite material with excellent antibacterial performance and good VOC performance. This material has not been reported so far, which has very important prac...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08K13/06C08K9/02C08K9/00C08K9/04C08K3/26C08K3/36C08K7/26C08K5/20C08K5/134C08K5/526C08J3/22
CPCC08J3/226C08J2367/04C08J2467/04C08K3/36C08K5/1345C08K5/20C08K5/526C08K7/26C08K9/00C08K9/02C08K9/04C08K13/06C08K2003/265
Inventor 刘凯孙启林吴向东
Owner ANHUI JIANGHUAI AUTOMOBILE GRP CORP LTD
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