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Device and method for preparing fuel by continuous bio-oil hydrodeoxygenation

A technology for hydrodeoxygenation and bio-oil, which is applied in hydrotreating process, petroleum industry, treatment of hydrocarbon oil, etc., can solve the problems of difficult conversion, unstable phenolic substances in bio-oil, and inability to carry out continuous conversion, etc. The effect of efficient conversion

Pending Publication Date: 2019-02-26
SOUTH CHINA AGRI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] What the present invention aims to solve is that the phenolic substances in the bio-oil are unstable and difficult to transform when the existing bio-oil is upgraded. 2 The problem of large consumption and inability to perform continuous conversion

Method used

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  • Device and method for preparing fuel by continuous bio-oil hydrodeoxygenation

Examples

Experimental program
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Effect test

Embodiment 1

[0022] Embodiment 1: refer to figure 1 , is a structural schematic diagram of Example 1 of the present invention, a device for preparing fuel by continuous hydrodeoxygenation of bio-oil, which is characterized in that it includes a raw material tank (21), a gasification chamber (6), a reaction device and a collection device. The raw material tank (21) communicates with the gasification chamber (6), and the reaction device at least includes a reactor A (18) and a reactor B (8), and the reactor A (18) and reactor B (8) The gasification chamber (6) is connected with the gas inlets of reactor A (18) and reactor B (8) through pipelines, and the gasification chamber (6) A valve A (20) and a valve B (7) are respectively provided on the connecting pipeline with the reactor A (18) and the reactor B (8), and the collection device is respectively connected with the reactor A (18) and the reactor B ( 8) The gas outlet is connected through a pipeline, and the valve C (17) and valve D (10)...

Embodiment 2

[0024] Embodiment 2: a method for preparing fuel by continuous hydrodeoxygenation of bio-oil, characterized in that: it is prepared by the above-mentioned device, and the specific steps are as follows:

[0025] (a) Preparation of raw materials: using bio-oil-based phenol derivative guaiacol as the reactant and isopropanol as the hydrogen donor for hydrodeoxygenation, the molar ratio of guaiacol and isopropanol is 1: Add the ratio of 10 to the raw material tank 21, with Ni / HZSM-5-La 2 o 3 Charge reactor A18 and reactor B8 for catalyst;

[0026] (b), device purification: the gas supply device 1 is equipped with N 2 , the gas supply device 1 inflates the gasification chamber 6 to make N 2 Replace the air in the gasification chamber 6, the reactor A18, the reactor B8 and the collection tank 13, and perform 3 gas cycle replacements with a gas flow rate of 300ml / min;

[0027] (c) Heating and pressurizing the reaction device: heating and pressurizing the reactor A18 and reactor B...

Embodiment 3

[0030] Embodiment 3: a method for preparing fuel by continuous bio-oil hydrodeoxygenation, characterized in that: it is prepared by the above-mentioned device, and the specific steps are as follows:

[0031] (a) Preparation of raw materials: using bio-oil-based phenol derivative guaiacol as the reactant and isopropanol as the hydrogen donor for hydrodeoxygenation, the molar ratio of guaiacol and isopropanol is 1: The ratio of 13 is added to the raw material tank 21, with Ni / HZSM-5-La 2 o 3 Charge reactor A18 and reactor B8 for catalyst;

[0032] (b), device purification: the gas supply device 1 is equipped with N 2 , the gas supply device 1 inflates the gasification chamber 6 to make N 2 Replace the air in the gasification chamber 6, the reactor A18, the reactor B8 and the collection tank 13, and carry out 3 gas cycle replacements with a gas flow rate of 350ml / min;

[0033] (c) Heating and pressurizing the reaction device: heating and pressurizing the reactor A18 and react...

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Abstract

The invention belongs to a device for preparing a fuel by continuous bio-oil hydrodeoxygenation. The device comprises a raw material tank, a gasification chamber, a reaction device and a collection device, wherein the raw material tank communicates with the gasification chamber, the reaction device comprises a reactor A and a reactor B, the reactor A and the reactor B are respectively provided with an air inlet and an air outlet, the gasification chamber communicates with the air inlets of the reactor A and the reactor B by pipes, the collection device communicates with the air outlets of thereactor A and the reactor B by pipes respectively, a gas supply device is further arranged on the gasification chamber, and the gas supply device can replace air in inner cavities of the gasificationchamber, the reaction device and the collection device. Compared with the prior art, aiming at the problems that phenolic substances in bio-oil are difficult to convert, the consumption of H2 is largeand the continuous hydrodeoxygenation cannot be carried out, the invention provides the device and the method capable of efficiently converting the phenolic substances in the bio-oil and implementingcontinuous hydrodeoxygenation by using a hydrogen donor instead of a hydrogen source.

Description

technical field [0001] The invention belongs to the field of biomass energy, and in particular relates to a method for preparing fuel by continuous hydrogenation and deoxygenation of bio-oil. Background technique [0002] The energy crisis and environmental degradation are constantly threatening the sustainable development of human society. Therefore, it is urgent to find a new energy source that is rich in sources, renewable, and conducive to environmental improvement and sustainable development. Biomass energy is a kind of abundant, cheap, easy-to-obtain and environmentally friendly renewable energy that green plants directly or indirectly convert solar energy into chemical energy and store in biomass through photosynthesis. Biomass can be converted into gas, liquid and solid fuels. Its total consumption is second only to coal, oil and natural gas, and it is the fourth largest energy consumption in the world. Therefore, the development and utilization of biomass energy has...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G67/04
CPCC10G67/04
Inventor 蒋恩臣李治宇许细薇孙焱王明峰任永志简秀梅
Owner SOUTH CHINA AGRI UNIV
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