Device and method for preparing fuel by continuous bio-oil hydrodeoxygenation
A technology for hydrodeoxygenation and bio-oil, which is applied in hydrotreating process, petroleum industry, treatment of hydrocarbon oil, etc., can solve the problems of difficult conversion, unstable phenolic substances in bio-oil, and inability to carry out continuous conversion, etc. The effect of efficient conversion
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Embodiment 1
[0022] Embodiment 1: refer to figure 1 , is a structural schematic diagram of Example 1 of the present invention, a device for preparing fuel by continuous hydrodeoxygenation of bio-oil, which is characterized in that it includes a raw material tank (21), a gasification chamber (6), a reaction device and a collection device. The raw material tank (21) communicates with the gasification chamber (6), and the reaction device at least includes a reactor A (18) and a reactor B (8), and the reactor A (18) and reactor B (8) The gasification chamber (6) is connected with the gas inlets of reactor A (18) and reactor B (8) through pipelines, and the gasification chamber (6) A valve A (20) and a valve B (7) are respectively provided on the connecting pipeline with the reactor A (18) and the reactor B (8), and the collection device is respectively connected with the reactor A (18) and the reactor B ( 8) The gas outlet is connected through a pipeline, and the valve C (17) and valve D (10)...
Embodiment 2
[0024] Embodiment 2: a method for preparing fuel by continuous hydrodeoxygenation of bio-oil, characterized in that: it is prepared by the above-mentioned device, and the specific steps are as follows:
[0025] (a) Preparation of raw materials: using bio-oil-based phenol derivative guaiacol as the reactant and isopropanol as the hydrogen donor for hydrodeoxygenation, the molar ratio of guaiacol and isopropanol is 1: Add the ratio of 10 to the raw material tank 21, with Ni / HZSM-5-La 2 o 3 Charge reactor A18 and reactor B8 for catalyst;
[0026] (b), device purification: the gas supply device 1 is equipped with N 2 , the gas supply device 1 inflates the gasification chamber 6 to make N 2 Replace the air in the gasification chamber 6, the reactor A18, the reactor B8 and the collection tank 13, and perform 3 gas cycle replacements with a gas flow rate of 300ml / min;
[0027] (c) Heating and pressurizing the reaction device: heating and pressurizing the reactor A18 and reactor B...
Embodiment 3
[0030] Embodiment 3: a method for preparing fuel by continuous bio-oil hydrodeoxygenation, characterized in that: it is prepared by the above-mentioned device, and the specific steps are as follows:
[0031] (a) Preparation of raw materials: using bio-oil-based phenol derivative guaiacol as the reactant and isopropanol as the hydrogen donor for hydrodeoxygenation, the molar ratio of guaiacol and isopropanol is 1: The ratio of 13 is added to the raw material tank 21, with Ni / HZSM-5-La 2 o 3 Charge reactor A18 and reactor B8 for catalyst;
[0032] (b), device purification: the gas supply device 1 is equipped with N 2 , the gas supply device 1 inflates the gasification chamber 6 to make N 2 Replace the air in the gasification chamber 6, the reactor A18, the reactor B8 and the collection tank 13, and carry out 3 gas cycle replacements with a gas flow rate of 350ml / min;
[0033] (c) Heating and pressurizing the reaction device: heating and pressurizing the reactor A18 and react...
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