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Method for producing rare earth metals and alloys

A rare earth metal and alloy technology, applied in the electrolysis process, electrolysis components, etc., can solve the problems such as the inability to accurately control the amount of materials required by the electrolysis cell, the inability to supply on demand, and the increase of production costs, so as to accurately grasp the real-time raw material consumption, The effect of reducing workload and saving electricity

Active Publication Date: 2019-03-19
QIANDONG RARE EARTH GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] This application overcomes the problem that the existing feeding method in this industry cannot accurately control the amount of materials required in the electrolytic cell for a long time, and cannot supply on demand, which seriously affects the quality of the product, leads to unstable production, and increases the production cost.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] For electrolytic praseodymium neodymium alloy, during electrolysis, set the electrolysis period to 150s (that is, every 150s is an electrolysis period), the coefficient value is set to 2.4, and the raw material is a mixture of PrNdO, LiF and PrNdF. Taking one of the electrolysis periods as an example, the ampere-hour meter collects the real-time current value of an electrolysis period, and the real-time current value fluctuates in the range of 4500-6000A, and converts the current value of each collection period into an ampere-hour value, and then converts the ampere-hour value It is transmitted to the control system, and the control system calculates that the cumulative ampere-hour change of this electrolysis period is 229.1AH (AH, the unit of ampere-hour), and then further calculates this according to the relationship between the feeding amount of the period, the cumulative value of the ampere-hour and the coefficient value of the period. The amount of material to be ad...

Embodiment 2

[0033] Electrolytic metal neodymium, during electrolysis, set the electrolysis period to 200s (that is, every 200s is an electrolysis period), the coefficient value is set to 2.0, and the raw material is a mixture of NdO, LiF and NdF. Taking one of the electrolysis periods as an example, the ampere-hour meter collects the real-time current value of an electrolysis period, and the real-time current value fluctuates in the range of 6000-8000A, and converts the current value of each collection period into an ampere-hour value, and then converts the ampere-hour value It is transmitted to the control system, and the control system calculates that the cumulative ampere-hour change in this electrolysis period is 388.5AH (AH, the unit of ampere-hour), and then further calculates this according to the relationship between the feeding amount of the period, the cumulative value of the ampere-hour and the coefficient value of the period. The amount of material to be added during the electr...

Embodiment 3

[0035] Electrolysis of Dy-Fe alloy, during electrolysis, the electrolysis period is set to 100s (that is, every 100s is an electrolysis period), the coefficient value is set to 1.7, and the raw material is DyO. Taking one of the electrolysis periods as an example, the ampere-hour meter collects the real-time current value of an electrolysis period, and the real-time current value fluctuates in the range of 4000-5500A, and converts the current value of each collection period into an ampere-hour value, and then converts the ampere-hour value It is transmitted to the control system, and the control system calculates that the cumulative ampere-hour change of this electrolysis period is 140.3AH (AH, the unit of ampere-hour), and then further calculates this according to the relationship between the feeding amount of the period, the cumulative value of the ampere-hour and the coefficient value of the period. The amount of material to be added during the electrolysis period is 238.5g,...

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PUM

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Abstract

The invention relates to a method for producing rare earth metals or alloys. In a period of electrolysis time, an ampere-hour collecting system converts collected current values into ampere-hour values and transmits the ampere-hour values to a control system, the control system accumulates the ampere-hour values in the whole electrolysis period to form an electrolysis period accumulated value, thecontrol system calculates the feeding amount of the electrolysis period according to the coefficient relationship between the electrolysis period ampere-hour accumulated value and the feeding amountand instructs a feeding machine to conduct feeding in the next electrolysis period, the collecting, calculating and feeding steps are circularly and continuously conducted, and the metals or alloys are produced through electrolysis. According to the method, not only is the labor intensity of workers reduced, but also the product quality is improved, and production is stabilized; precise feeding inthe rare earth electrolysis process is really achieved, and feeding is conducted as needed; and the method is simple and low in maintenance rate in the operation and implementation process, the production efficiency is greatly improved, the production cost is greatly reduced, and a solid foundation is laid for achievement of industrialization and informatization of industries.

Description

technical field [0001] The application of the present invention belongs to the field of rare earth metallurgy, and specifically relates to a method for producing rare earth metals and alloys. Background technique [0002] During the electrolysis process of the rare earth fluoride molten salt electrolysis system, due to the volatilization and leakage of the molten salt, the participation of fluoride in the electrolysis and other reasons, the electrolyte will be lost and the proportion will be changed. When the amount of molten salt is reduced, it will lead to lower output and higher cost, and when the fluoride content is lower or higher, it will lead to lower product quality and higher production cost. Therefore, it is very important to ensure the stability of the electrolyte system. [0003] In the existing electrolysis process, the electrolyte, rare earth fluoride and lithium fluoride are added separately. Since the melting point of lithium fluoride is lower than that of t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25C3/34C25C3/36C25C7/06
CPCC25C3/34C25C3/36C25C7/06
Inventor 龚斌章立志邓聚金郭雪锋龙厚炳詹彩霞
Owner QIANDONG RARE EARTH GRP
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