Chalcone double Mannich base compound, its preparation method and use
A technology of chalcone double Mannich base and double Mannich base, which is applied in the field of chalcone double Mannich base compounds, their preparation and application, and can solve the problem of poor long-term curative effect and action target of AD patients Single, many side effects and other issues
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Embodiment 1
[0033] Embodiment 1 General method for the preparation of chalcone double Mannich base compound (I)
[0034] Add 2.0 mmol of the corresponding hydroxyacetophenone Mannich base compound (1), 2.5 mmol of the corresponding hydroxybenzaldehyde Mannich base compound (2) and 30 ml of ethanol into the reaction flask, stir well, and add dropwise 30% KOH aqueous solution 15.0 mmol, stirred and reacted at room temperature for 2.0 to 48.0 hours (the reaction process was followed by TLC); after the reaction, cooled to room temperature, adjusted the pH of the reaction solution to strong acidity with 10% hydrochloric acid aqueous solution, and then saturated sodium bicarbonate aqueous solution Adjust the pH of the reaction solution to weak alkalinity, evaporate ethanol under reduced pressure, add 80 mL of deionized water to the residual liquid, and extract three times with 240 mL of dichloromethane. After drying with sodium sulfate, filter, evaporate the solvent under reduced pressure, and ...
Embodiment 2
[0041] Example 2 Preparation method of chalcone double Mannich base compound (I) and acid salt formation
[0042] Add 2.0 mmol of the chalcone double Mannich base compound (I) obtained in the above-mentioned Example 1 and 50 ml of acetone into the reaction flask, stir evenly, add 8.0 mmol of the corresponding acid, heat and reflux and stir for 20 minutes, and react After cooling to room temperature, the solvent is evaporated under reduced pressure to obtain the salt of chalcone bis-Mannich base compound (I), whose chemical structure is 1 Confirmed by H NMR and ESI-MS.
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