Biomass lubricant for drilling fluid and preparation method thereof
A biomass and lubricant technology, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of difficult dispersion, drilling fluid foaming, non-environmental protection, etc., and achieve good environmental protection, fast drilling, good interaction effect
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[0048] The present invention also provides a preparation method of the biomass lubricant for drilling fluid described in the above technical scheme, comprising the following steps:
[0049] a) reacting the front fraction of natural fatty alcohol, organic acid and lipase catalyst to obtain biomass base oil;
[0050] b) mixing the biomass base oil obtained in step a) with an ionic liquid anti-wear agent, an emulsifier, a defoamer, a viscosity raising agent and water to obtain a biomass lubricant for drilling fluid.
[0051] In the present invention, firstly, the first part of natural fatty alcohol, organic acid and lipase catalyst are reacted to obtain biomass base oil. In the present invention, the front fraction of the natural fatty alcohol preferably includes one of the front fraction of palm oil natural fatty alcohol, the front fraction of soybean oil natural fatty alcohol and the front fraction of rapeseed oil natural fatty alcohol or more, more preferably the front fracti...
Embodiment 1
[0065] (1) Preparation of biomass base oil:
[0066] In an airtight container equipped with a condensation tube, add successively the front fraction of palm oil natural fatty alcohol, acetic acid and Candida rugosa lipase with a molar ratio of 1: 1: 0.02n (n is the content of palm oil natural fatty alcohol) The molar weight of hydroxyl groups in the previous fraction), under the stirring speed of 100r / min, heated to 30°C for 6h, cooled to room temperature, and took out to obtain biomass base oil.
[0067] According to the method of "The mensuration of nonionic surfactant hydroxyl value" (GB / T 7383-1997), the hydroxyl group (-OH) in the front fraction of palm oil natural fatty alcohol is titrated, thereby determine the numerical value of n, After determination, the molar weight n of hydroxyl groups in the fore fraction of palm oil natural fatty alcohol is 0.31 (the same below).
[0068] (2) Preparation of biomass lubricant:
[0069] According to the percentage by weight of ra...
Embodiment 2
[0071] (1) Preparation of biomass base oil:
[0072] In an airtight container equipped with a condensing tube, sequentially add the front fraction of soybean oil natural fatty alcohol, butyric acid and Candida antarctica lipase (n is the content of soybean oil natural fatty alcohol) in a molar ratio of 1:1:0.05n The molar weight of the hydroxyl groups in the previous fraction), under the stirring speed of 300r / min, heated to 50°C for 12h, cooled to room temperature and taken out to obtain biomass base oil.
[0073] It was determined that the molar amount n of hydroxyl groups in the front fraction of soybean oil natural fatty alcohol was 0.27.
[0074] (2) Preparation of biomass lubricant:
[0075]Prepare raw materials according to percentage by weight, successively with the biomass base oil that 30% step (1) obtains, 5% [EEM][EP] ionic liquid anti-wear agent, 5% diacetyl tartrate monoglyceride emulsifier, 1% Add simethicone-500 defoamer, 0.1% CMC-HV viscosifier and 58.9% dei...
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