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A kind of binder preparation process for solar cell back electrode paste

The invention relates to a technology for preparing a binder and a solar cell, which is applied in the field of solar cells and can solve the problems such as the decrease of the adhesion between the electrode paste and the photovoltaic panel, the influence of the photoelectric conversion efficiency of the electrode paste, and the inability of the electrode paste to disperse well. Achieve the effect of improving photoelectric conversion efficiency, high viscosity and high bonding strength

Active Publication Date: 2020-11-10
合肥芮欣电子商务有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although the existing binder is environmentally friendly, its performance will deteriorate after long-term exposure to light, resulting in a decrease in the adhesion between the electrode slurry and the photovoltaic panel. At the same time, the mixing of raw materials will easily lead to the agglomeration of the electrode slurry and affect the photoelectric conversion efficiency. The existing Chinese patent document (notification number: CN105469854B) discloses a plant source composite binder for polycrystalline silicon solar cell light back electrode slurry, the content of each component is calculated by weight: 6-10 parts of gum arabic, brown algae 2-6 parts of glue, 0.2-2 parts of squash glue, 0.05-0.2 parts of talcum powder, and 100 parts of water. Although the binder is environmentally friendly, it has a high degree of crosslinking and is easy to agglomerate, so that the electrode slurry cannot be well dispersed. , affecting the photoelectric conversion efficiency
[0004] Chinese patent document (notification number: CN106675449B) discloses a high-safety negative electrode slurry binder for lithium ion batteries, which is made of raw materials such as sodium carboxymethyl cellulose, styrene-butadiene rubber, sodium alginate and binder additives , although the binder has good bonding performance, but the raw material of styrene-butadiene rubber will affect the photoelectric conversion efficiency of the electrode slurry

Method used

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  • A kind of binder preparation process for solar cell back electrode paste
  • A kind of binder preparation process for solar cell back electrode paste
  • A kind of binder preparation process for solar cell back electrode paste

Examples

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Embodiment 1

[0024] A preparation process of a binder for solar cell back electrode paste in this embodiment comprises the following steps:

[0025] Step 1, mix 40 parts of modified konjac flour and 20 parts of defatted starch, then add 25 parts of deionized water, add while stirring, then add 5 parts of modified montmorillonite, the stirring speed is raised to 300r / min, and stir 20min, then reduce the rotating speed to 80r / min, stir for 50min, then add 4 parts of modified nano-titanium dioxide, then transfer to a high-pressure reactor, react for 30min, and the reaction is completed to obtain a premix;

[0026] The preparation method of the modified konjac flour is as follows: konjac flour and lignin phenolization solution are mixed according to the weight ratio of 5:1, and then sent to a four-neck flask for reaction for 30 minutes at a reaction temperature of 65°C, and then glacial acetic acid is added Adjust the pH to 5.0, then ultrasonically disperse for 10 minutes, then let stand and a...

Embodiment 2

[0036] A preparation process of a binder for solar cell back electrode paste in this embodiment comprises the following steps:

[0037]Step 1, mix 50 parts of modified konjac flour and 30 parts of defatted starch, then add 35 parts of deionized water, add while stirring, then add 15 parts of modified montmorillonite, increase the stirring speed to 400r / min, stir 30min, then reduce the rotating speed to 140r / min, stir for 60min, then add 8 parts of modified nano-titanium dioxide, then transfer to a high-pressure reactor, react for 40min, and the reaction is completed to obtain a premix;

[0038] The preparation method of the modified konjac flour is as follows: konjac flour and lignin phenolization liquid are mixed according to the weight ratio of 5:1, and then sent to a four-necked flask for reaction for 40 minutes at a reaction temperature of 75°C, and then glacial acetic acid is added Adjust the pH to 5.0, then ultrasonically disperse for 20 minutes, then let stand and age f...

Embodiment 3

[0048] A preparation process of a binder for solar cell back electrode paste in this embodiment comprises the following steps:

[0049] Step 1, mix 45 parts of modified konjac flour and 25 parts of defatted starch, then add 30 parts of deionized water, add while stirring, then add 10 parts of modified montmorillonite, the stirring speed rises to 350r / min, stir 25min, and then reduce the rotating speed to 110r / min, stir for 55min, then add 6 parts of modified nano-titanium dioxide, then transfer to the high-pressure reactor, react for 35min, and the reaction is completed to obtain the premix;

[0050] The preparation method of the modified konjac flour is as follows: konjac flour and lignin phenolization solution are mixed according to the weight ratio of 5:1, then sent to a four-neck flask for reaction for 35min, the reaction temperature is 70°C, and then glacial acetic acid is added Adjust the pH to 5.0, then ultrasonically disperse for 15 minutes, then let stand and age for ...

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Abstract

The invention discloses a binder preparation process for solar cell back electrode paste. The method comprises the following steps of: the step 1, mixing 40-50 parts of modified konjac flour and 20-30parts of degreased starch, then adding 25-35 parts of deionized water into the mixture with stirring, adding 5-15 parts of modified montmorillonite into the mixture, and stirring the mixture at a rotational speed up to 300-400 r / min for 20-30min. The modified konjac flour aqueous solution is large in viscosity, has higher viscosity intensity than these of other biological adhesives, can be used as the main material of the binder and is modified by employing the lignin phenolating liquid to enhance the activity of the konjac flour and increase the hydroxyl groups contained on the surface, andthe defatted starch contains a lot of hydroxyl groups.

Description

technical field [0001] The invention relates to the technical field of solar cells, in particular to a preparation process of a binder used for solar cell back electrode paste. Background technique [0002] Solar energy is a new energy source, which has attracted more and more attention. To convert solar energy into electrical energy requires the use of photovoltaic panels. Photovoltaic panel components are a power generation device that generates direct current when exposed to sunlight. Solar energy is utilized by almost all Composed of solid photovoltaic cells made of semiconductor materials (such as silicon), since there are no moving parts, they can operate for a long time without causing any loss. Simple photovoltaic cells can provide energy for watches and computers. More complex photovoltaic systems It can provide lighting, traffic lights and monitoring systems for houses, and can be connected to the grid for power supply. Photovoltaic panel components can be made int...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/0224H01L31/18H01B13/00
CPCH01B13/00H01L31/022425Y02E10/50Y02P70/50
Inventor 陆志鹏
Owner 合肥芮欣电子商务有限公司