Zinc-nickel-zirconium mesoporous composite oxide catalyst for hydrogen production by autothermal reforming of acetic acid
A composite oxide, autothermal reforming technology, applied in the direction of metal/metal oxide/metal hydroxide catalyst, physical/chemical process catalyst, chemical/physical process, etc. It is easy to be oxidized and other problems to achieve the effect of improving catalytic activity, improving anti-sintering and inhibiting oxidation.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
example 1
[0025] Weigh 3.009g of Ni(NO 3 ) 2 ·6H 2 O, 9.236g of Zn(NO 3 ) 2 ·6H 2 O and 3.688g of ZrO(NO 3 ) 2 2H 2 O, add 55mL of deionized water to prepare solution #1; weigh 7.727g of NaOH and 1.280g of anhydrous Na 2 CO 3 , add 102mL of deionized water to prepare solution #2; under the condition of 78°C and pH of the solution at 10.5±0.5, add solution #1 and solution #2 dropwise into the beaker and keep stirring for co-precipitation reaction, and continue Stir and age for 18 hours; after the aging, the mixture was suction filtered and washed three times, and the resulting precipitate was dried in a 105°C oven for 24 hours, and the precipitate was calcined at 700°C for 4 hours to obtain CDUT-ZNZ-101 catalyst. The chemical composition of the catalyst is (ZnO) 2.25 (NiO) 0.75 ZrO 2 , The weight percentage is: zinc oxide is 50.5%, nickel oxide is 15.5%, zirconium oxide is 34.0%.
[0026] The reactivity evaluation of autothermal reforming of acetic acid was carried out in a ...
Embodiment 1
[0029] Weigh 3.094g of Ni (NO 3 ) 2 ·6H 2 O, 7.385g of Zn (NO 3 ) 2 ·6H 2 O and 4.739g of ZrO(NO 3 ) 2 2H 2 O, add 53mL of deionized water to prepare solution #1; weigh 9.079g of NaOH and 1.504g of anhydrous Na 2 CO 3 , add 121mL of deionized water to prepare solution #2; under the condition of 78°C and pH of the solution at 10.5±0.5, add solution #1 and solution #2 dropwise into the beaker and keep stirring for co-precipitation reaction, and continue Stirring and aging for 18 hours; after the aging, the mixture was suction filtered and washed 3 times, and the obtained precipitate was dried in a 105°C oven for 24 hours, and the precipitate was roasted at 700°C for 4 hours to obtain a compound containing ZnO, t-ZrO 2 , m-ZrO 2 and NiO Ni / ZnO-ZrO 2 Composite oxide catalyst, the typical structure of its composite oxide is as attached figure 1 As shown, the CDUT-ZNZ-102 catalyst is obtained; the catalyst is a mesoporous material, and the typical pore size distribution ...
Embodiment 2
[0032] Weigh 2.880g of Ni(NO 3 ) 2 ·6H 2 O, 4.420g of Zn (NO 3 ) 2 ·6H 2 O and 6.618g of ZrO(NO 3 ) 2 2H 2 O, add 50.5mL of deionized water to prepare solution #1; weigh 11.093g of NaOH and 1.837g of anhydrous Na 2 CO 3 , add 148mL of deionized water to prepare solution #2; under the condition of 78°C and pH of the solution at 10.5±0.5, add solution #1 and solution #2 dropwise into the beaker and keep stirring for co-precipitation reaction, and continue Stirring and aging for 18 hours; after the aging, the mixture was suction filtered and washed 3 times, and the obtained precipitate was dried in a 105°C oven for 24 hours, and the precipitate was roasted at 700°C for 4 hours to obtain Ni / ZnO-ZrO 2 Composite oxide catalyst, the typical structure of its composite oxide is as attached figure 1 As shown, the CDUT-ZNZ-103 catalyst is obtained; the catalyst is a mesoporous material, and the typical pore size distribution of its mesoporous structure is shown in the attached ...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com