Packaging adhesive and packaging structure
A packaging glue and adhesive technology, which is applied in nanotechnology, electrical components, nanotechnology, etc. for materials and surface science, can solve the problem of unsatisfactory thermal conductivity and heat dissipation performance, unsatisfactory thermal conductivity and heat dissipation performance of packaging glue, and electronic components. Problems such as performance stability and unsatisfactory life, to achieve the effect of improving continuous heat dissipation, ensuring stability, and prolonging service life
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[0030] Based on the modified hollow microspheres described in the invention examples above, the present invention also provides a method for preparing the modified hollow microspheres. The method for preparing the modified hollow microspheres includes the following steps:
[0031] Carry out surface grafting treatment on the hollow microsphere matrix to graft organic compounds onto the surface of the hollow microspheres to form hollow microspheres with organic compounds bound to the surface. The general structural formula of the organic compounds is A1-D-A2. A1 and A2 are respectively electron withdrawing groups, and the D is an organic group with a symmetric molecular structure.
[0032] In one embodiment, the step of performing surface grafting treatment on the hollow microsphere matrix to graft the organic compound to the surface of the hollow microsphere includes:
[0033] Preparation of organic solution containing isocyanate groups;
[0034] Adding hollow microspheres and a catal...
Embodiment 11
[0061] This embodiment provides a modified hollow microsphere and a preparation method thereof. The modified hollow microspheres include a polyurethane hollow microsphere matrix and the above-mentioned L1 compound bonded to the polyurethane hollow microsphere matrix.
[0062] The modified hollow microspheres described in Example 11 were prepared according to the following method:
[0063] (1) Preparation of polyurethane hollow microsphere matrix: adopt Pickering suspension polymerization method to prepare thermal hollow microspheres, and weigh 0.5g nanometer Mg(OH) 2 , 0.25g NaCl, 0.01g NaNO 2 Dissolve in 50mL deionized water, stir for 15 minutes and mix well as the aqueous phase of suspension polymerization; weigh 14g acrylonitrile, 4g methyl methacrylate, 2g butyl acrylate, 0.08g trimethylolpropane trimethacrylate, 0.4g azobisisobutyronitrile and 7g isooctane were stirred at room temperature for 30 minutes and mixed uniformly as the oil phase; after mixing the water phase and the...
Embodiment 12
[0066] This embodiment provides a modified hollow microsphere and a preparation method thereof. The modified hollow microspheres include a polyurethane hollow microsphere matrix and the aforementioned L3 compound bonded to the polyurethane hollow microsphere matrix.
[0067] The modified hollow microspheres described in Example 12 were prepared according to the following method:
[0068] (1) Preparation of polyurethane hollow microsphere matrix: refer to step (1) preparation in Example 11;
[0069] (2) Modification of the polyurethane hollow microsphere matrix: refer to the preparation in step (2) of Example 11, except that L3 is used to modify the polyurethane hollow microsphere matrix.
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