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Transferable flexible electrode and preparation method and application thereof

A flexible electrode and primary electrode technology, applied in the direction of circuits, electrical components, electric solid devices, etc., can solve the problems of fragility, difficulty of flexible electrodes, and poor flexibility of ultra-thin glass, and achieve excellent heat dissipation performance and excellent mechanical properties. The effect of bending performance and good air stability

Active Publication Date: 2019-10-18
SHANGHAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Usually, the optional flexible substrates mainly include ultra-thin glass, metal foil, etc., but the flexibility of ultra-thin glass is not good, fragile, and the cost is high, the preparation is difficult, and ultra-thin glass cannot be used alone in the flexible packaging process. In use, polymer coating is required to protect the glass surface from mechanical damage and chemical reagent erosion, and the epoxy resin sealing technology at the edge cannot meet the requirements; the surface of the metal foil substrate is rough and needs to be planarized, and it is light-transmitting The performance is extremely poor, and the device can only adopt the top-emission structure that emits light from the upper part of the ultra-thin transparent electrode, which is not very practical.
[0004] Considering the brittleness and poor packaging performance of common flexible substrates, some new flexible substrates can solve some shortcomings of high brittleness and poor packaging performance. However, it is difficult to directly prepare flexible electrodes on new flexible substrates.

Method used

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  • Transferable flexible electrode and preparation method and application thereof
  • Transferable flexible electrode and preparation method and application thereof
  • Transferable flexible electrode and preparation method and application thereof

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preparation example Construction

[0029] The invention provides a method for preparing a transferable flexible electrode, comprising the following steps:

[0030] (1) Coating photoresist, coating PDMS layer and stacking thin graphite sheets in sequence on the substrate to obtain the primary electrode;

[0031] (2) removing the photoresist of the primary electrode in the step (1), causing the substrate to fall off, and annealing the remaining PDMS layer and graphite flakes to obtain a transferable flexible electrode.

[0032] In the present invention, unless otherwise specified, all raw materials are commercially available products well known to those skilled in the art.

[0033] In the invention, the photoresist is coated on the substrate to obtain the primary substrate. In the present invention, the substrate is preferably a PET (polyethylene terephthalate), PEN (polyethylene naphthalate), PI (polyimide) or glass substrate. In the present invention, the method of coating photoresist is preferably: according...

Embodiment 1

[0044] PDMS (polydimethylsiloxane) was purchased from Aladdin.

[0045] (1) Preparation of flake graphite: dilute graphene oxide sol to 2mg / mL, ultrasonically disperse for half an hour, transfer the diluted sol to an open container, place a piece of glass substrate at the bottom, place the container in a water bath, 80°C Heat in a water bath for 45 minutes to make the surface of the sol self-assemble into a film, deposit the film on a glass substrate and transfer it to a water platform, and dry it naturally in a dust-free environment to obtain a film-coated glass substrate. Add an appropriate amount of hydrogen iodide solution to another container, place the glass substrate with the film down, place it at a position 2cm away from the hydroiodic acid liquid surface, and use an oil bath at 85°C to reduce graphene oxide to graphene and make the graphene film It fell off from the substrate, and after 1 hour, the film was taken out, placed in a container filled with distilled water...

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Abstract

The invention belongs to the technical field of organic electroluminescent devices, in particular to a transferable flexible electrode and a preparation method and application thereof, and provides the preparation method of the transferable flexible electrode. The preparation method comprises the following steps: (1) coating a photoresist, a PDMS layer and a laminated sheet graphite on a substratein sequence to obtain a primary electrode; (2) removing the photoresist of the primary electrode in the step (1) so that the substrate is stripped and annealing the remaining PDMS layer and the sheetgraphite so as to obtain the transferable flexible electrode. The problem that the traditional flexible electrode material needs to be fixed on the substrate and cannot be transferred can be solved so that the technical effect of separating the flexible electrode material from the substrate can be realized and the use scheme of the flexible electrode can be enriched. The experiment shows that thetransferable flexible electrode has excellent mechanical bending performance, air stability and heat dissipation performance.

Description

technical field [0001] The invention belongs to the technical field of organic electroluminescent devices, and in particular relates to a transferable flexible electrode and its preparation method and application. Background technique [0002] Organic electronic devices are semiconductor devices with specific functions prepared on the basis of conductive organic materials. Since most of the organic materials in organic electronic devices are composed of carbon and hydrogen, using them to make electronic devices has many advantages, such as easy fabrication, low cost, chemical adjustment, transparency and flexibility, etc. Flexible organic light-emitting devices can be used in display technology. With their outstanding advantages such as light weight, high efficiency, easy processing and deformability, they are suitable for use in wearable devices, plastic bioelectronics and prosthetic electronic skin, and will be commercialized in the next generation Display market realizes...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/52H01L51/56
CPCH10K50/805H10K71/00
Inventor 谢俊洋刘康平王倩楠王双龙丁星伟魏斌徐韬
Owner SHANGHAI UNIV