Ultraviolet absorbing coating materil and film coated with said coating material
A polymerizable monomer, benzotriazole-based technology, used in radiation-absorbing coatings, coatings, layered products, etc., can solve the problems of low light resistance, no light resistance, and reduced light absorption capacity, and achieve absorption The effect of excellent performance, excellent UV absorption performance and UV shielding performance, excellent absorption performance and excellent UV shielding performance
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment
[0065] Hereinafter, the present invention will be described in more detail with examples and comparative examples of benzotriazole-based (co)polymers, coating materials and coating-coated films including these examples, but the present invention is not limited to these embodiments. In addition, "%" described in a synthesis example, an Example, and a comparative example shows "weight%", and "part" shows a "weight part."
[0066] [1. Synthesis of benzotriazole-based monomers]
Synthetic example 1
[0068] [Compound (a): 2-(3-tert-butyl-2-hydroxy-5-methoxyphenyl)-2H-benzotriazole-5-carboxylic acid-2-methacryloyloxyethyl ester Synthesis][Chemical 3]
[0069]
[0070] Install a spherical condenser, a thermometer, and a stirring device on a 200ml four-necked flask, add 100ml of water, 6.5g (0.061mol) of sodium carbonate, and 20.0g (0.110mol) of 4-amino-3-nitrobenzoic acid to dissolve, add 22.7 g (0.118 mol) of 36% sodium nitrite aqueous solution. Install a spherical condenser, a thermometer, and a stirring device on a 500ml four-necked flask, add 100ml of water, 43.0g (0.274 moles) of 62.5% sulfuric acid and mix, cool to 3-7°C to obtain the product, and add the above-mentioned The product was stirred at the same temperature for 2 hours to obtain an aqueous diazonium salt solution. Install a spherical condenser, a thermometer, and a stirring device on a 1000ml four-necked flask, add 18.0g (0.100 moles) of 2-tert-butyl-4-methoxyphenol, 10ml of isopropanol, and 140ml of wa...
Synthetic example 2
[0091] [Compound (b): Synthesis of 2-(2-hydroxy-5-methoxyphenyl)-2H-benzotriazole-5-carboxylic acid-2-methacryloyloxyethyl ester] [Chem. 4 ]
[0092]
[0093] Except changing 2-tert-butyl-4-methoxyphenol into 4-methoxyphenol, the compound (b ). The melting point is 94°C, the maximum absorption wavelength λmax is 309.8nm and 373.2nm, and the molar absorptivity ε of these wavelengths are 14700 and 13100, respectively.
[0094] In addition, the purity of compound (b) was determined by HPLC analysis.
[0095]
[0096] Device: L-2130 (manufactured by Hitachi High-Technologies Co., Ltd.)
[0097] Column used: Inertsil ODS-3 4.6×150mm 5 μm
[0098] Column temperature: 25°C
[0099] Mobile phase: acetonitrile / water=9 / 1 (phosphoric acid 3ml / L)
[0100] Flow rate: 1.0ml / min
[0101] Detection: UV250nm
[0102]
[0103] HPLC peak area percentage purity 93.4%
[0104] In addition, as a result of NMR measurement of the compound (b), a result supporting the above-mentioned str...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com