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Method for producing tetradecanedioic acid by fermentation of candida viswanathii

A technology of tetradecanedibasic acid and Candida viesis, applied in the direction of microorganism-based methods, biochemical equipment and methods, fermentation, etc., can solve the problem of long production equipment time and product purity not reaching long-chain binary Problems such as acid esters and low fermentation level, etc., to achieve the effect of dense crystal form

Active Publication Date: 2019-12-13
张艾琳
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  • Abstract
  • Description
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  • Application Information

AI Technical Summary

Problems solved by technology

[0003]However, in the existing method of biological synthesis of tetradecane dibasic acid, the level of fermentation is still not high, and the purity of the product cannot reach the level of preparation of long-chain dibasic acid Ester requirements, especially in dibasic acid products due to the difference in the α and ω-oxidation sites of the fermentation strains, a certain amount of monobasic acid impurities will be produced. The result of the fermentation method of the prior art is: after 148 hours of fermentation, the DC14 content is 197.4 g / L, the yield is 93.3%, the product is analyzed by gas chromatography, the total acid purity is 98.9%, the monoacid content is 98.5%, and the average acid production rate is 1.3g / L h
However, the operation steps of the above method are relatively complicated, and the entire fermentation cycle is not shortened, and the production equipment takes a long time, which cannot solve the problem of dibasic acid industrialization

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The process of fermentative synthesis of long-chain dibasic acids is as follows:

[0031] 1. Culture medium preparation

[0032] ① Incline medium: malt juice agar medium;

[0033] ②Seed medium: glucose 25g / L, disodium hydrogen phosphate 6g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 0.5 g / L.

[0034] ③ Fermentation medium: glucose 40g / L, disodium hydrogen phosphate 8g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 0.5 g / L.

[0035] 2. Seed cultivation stage

[0036] A piece of Candida viswanathii ws-1401 was spread on a solid slant medium in a large test tube of 20×180 mm, and cultured at 27°C for 72 hours. Inoculate the activated seed culture on the slant into a 500ml Erlenmeyer flask containing 200ml of seed medium, and culture it with shaking at 27°C and 250r / min for 48 hours, and the detected strain OD is between 0.6 and 0.85.

[0037] 3. Fermentation acid production stage: ...

Embodiment 2

[0041] The process of fermentative synthesis of long-chain dibasic acids is as follows:

[0042] 1. Culture medium preparation

[0043] ① Incline medium: malt juice agar medium;

[0044] ②Seed medium: glucose 25g / L, disodium hydrogen phosphate 6g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 0.5 g / L.

[0045] ③ Fermentation medium: glucose 35g / L, disodium hydrogen phosphate 8g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 1.5 g / L.

[0046] 2. Seed cultivation stage

[0047] A piece of Candida viswanathii ws-1401 was spread on a solid slant medium in a large test tube of 20×180 mm, and cultured at 27°C for 72 hours. Inoculate the activated seed culture on the slant into a 500ml Erlenmeyer flask containing 200ml of seed medium, and culture it with shaking at 27°C and 250r / min for 48 hours. In a base 10L fermenter, the initial pH is 6.0, the temperature is 27°C, the ventilation rate is 1:0...

Embodiment 3

[0052] The process of fermentative synthesis of long-chain dibasic acids is as follows:

[0053] 1. Culture medium preparation

[0054] ① Incline medium: malt juice agar medium;

[0055] ②Seed medium: glucose 25g / L, disodium hydrogen phosphate 6g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 0.5 g / L.

[0056] ③ Fermentation medium: glucose 35g / L, disodium hydrogen phosphate 8g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 1.5 g / L.

[0057] 2. Seed cultivation stage

[0058] A piece of Candida viswanathii ws-1401 was spread on a solid slant medium in a large test tube of 20×180 mm, and cultured at 27°C for 72 hours. Inoculate the activated seed culture on the slant into a 500ml Erlenmeyer flask containing 200ml of seed medium, and culture it with shaking at 27°C and 250r / min for 48 hours. In the base 5L fermenter, the initial pH is 6.0, the temperature is 27°C, the ventilation rate is 1:...

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Abstract

The invention relates to a method for synthesizing and producing long-chain tetradecanedioic acid by using a candida viswanathii biological method, which comprises the following steps: a seed culturestage, a fermentation culture stage and a tetradecanedioic acid separation and recovery stage, and a preservation number of the candida viswanathii is CCTCC M No. 2019075. Wherein the strain growth ODvalue of a seed solution obtained in the seed culture stage reaches 0.6-0.85. The n-tetradecanedioic acid produced by the method disclosed by the invention has a satisfactory crystal form, and can more easily meet the European dust-free and low-dust product export requirements; and the material is especially suitable for being used as a raw material of high-grade nylon and polyamide materials.

Description

technical field [0001] The invention belongs to the field of biochemical industry, and relates to a method for fermenting and producing tetradecanedibasic acid by Candida viesis, a product and a strain. Background technique [0002] Long-chain dibasic acids refer to dibasic acids with ten or more carbon atoms, and generally refer to straight-chain dibasic acids. Tetradecane dibasic acid (DC14) is an important raw material for synthesizing high-performance nylon engineering plastic nylon and high-grade nylon hot-melt adhesives and advanced coatings for clothing. DC14 can be produced by microbial fermentation or chemical synthesis. The traditional chemical method for producing long-chain diacids requires 9 complicated reaction steps, high temperature, high pressure and catalysts; fireproof, explosion-proof and poison-proof devices are required during production, which leads to low yield, high cost and serious environmental pollution. The biological fermentation method has a ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P7/64C12N1/16C07C55/02C12R1/74
CPCC12P7/6409C07C55/02C12R2001/74C12N1/165
Inventor 王绍冰修德恒万贺飞
Owner 张艾琳