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Method for producing undecanedioic acid by fermentation of candida viswanathii

A technology for Candida viscera and dibasic acid, which is applied in the field of Candida viscera fermentation to produce undecanoic dibasic acid, can solve the problem of taking up a long time in production equipment, complicated operation steps, and inability to solve the problem of industrialization of dibasic acid. and other problems, to achieve the effect of dense crystalline form

Active Publication Date: 2019-12-13
张艾琳
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The best fermentation production result of undecane dibasic acid reported at present is: after 150 hours of fermentation, the DC11 content in the fermentation serum was 156g / L, the conversion rate of nC11 was 86.7%, and the production rate was 1.04g / h·L, but The operation steps of the above method are relatively complicated, and the entire fermentation cycle is not shortened, and the production equipment takes a long time, which cannot solve the problem of dibasic acid industrialization

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The process of fermentative synthesis of long-chain dibasic acids is as follows:

[0033] 1. Culture medium preparation

[0034] ① Incline medium: malt juice agar medium;

[0035] ②Seed medium: glucose 25g / L, disodium hydrogen phosphate 6g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 0.5 g / L.

[0036] ③ Fermentation medium: glucose 40g / L, disodium hydrogen phosphate 8g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 0.5 g / L.

[0037] 2. Seed cultivation stage

[0038] A piece of Candida viswanathii ws-1101 was spread on a solid slant medium in a large test tube of 20×180 mm, and cultured at 27°C for 72 hours. Inoculate the activated seed culture on the slant into a 500ml Erlenmeyer flask containing 200ml of seed medium, and culture it with shaking at 27°C and 250r / min for 48 hours, and the detected strain OD is between 0.6 and 0.85.

[0039] 3. Fermentation acid production stage: ...

Embodiment 2

[0043] The process of fermentative synthesis of long-chain dibasic acids is as follows:

[0044] 1. Culture medium preparation

[0045] ① Incline medium: malt juice agar medium;

[0046] ②Seed medium: glucose 25g / L, disodium hydrogen phosphate 6g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 0.5 g / L.

[0047] ③ Fermentation medium: glucose 35g / L, disodium hydrogen phosphate 8g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 1.5 g / L.

[0048] 2. Seed cultivation stage

[0049] A piece of Candida viswanathii ws-1101 was spread on a solid slant medium in a large test tube of 20×180 mm, and cultured at 27°C for 72 hours. Inoculate the activated seed culture on the slant into a 500ml Erlenmeyer flask containing 200ml of seed medium, and culture it with shaking at 27°C and 250r / min for 48 hours. In a base 10L fermenter, the initial pH is 6.0, the temperature is 27°C, the ventilation rate is 1:0...

Embodiment 3

[0054] The process of fermentative synthesis of long-chain dibasic acids is as follows:

[0055] 1. Culture medium preparation

[0056] ① Incline medium: malt juice agar medium;

[0057] ②Seed medium: glucose 25g / L, disodium hydrogen phosphate 6g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 0.5 g / L.

[0058] ③ Fermentation medium: glucose 35g / L, disodium hydrogen phosphate 8g / L, yeast extract 3g / L, corn steep liquor 5g / L, urea 1.5g / L, NaCl 0.5g / L, KCl 1g / L, Tween 1.5 g / L.

[0059] 2. Seed cultivation stage

[0060] A piece of Candida viswanathii ws-1101 was spread on a solid slant medium in a large test tube of 20×180 mm, and cultured at 27°C for 72 hours. Inoculate the activated seed culture on the slant into a 500ml Erlenmeyer flask containing 200ml of seed medium, and culture it with shaking at 27°C and 250r / min for 48 hours. In the base 5L fermenter, the initial pH is 6.0, the temperature is 27°C, the ventilation rate is 1:...

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Abstract

The invention relates to a method for synthesizing and producing long-chain undecanedioic acid by using a candida viswanathii biological method, which comprises the following steps: a seed culture stage, a fermentation culture stage and a undecanedioic acid separation and recovery stage, and a preservation number of the candida viswanathii is CCTCC M No. 2019077. Wherein the strain growth OD valueof a seed solution obtained in the seed culture stage reaches 0.6-0.85. The n-undecanedioic acid produced by the method disclosed by the invention has a satisfactory crystal form, and can more easilymeet the European dust-free and low-dust product export requirements; and the material is especially suitable for being used as raw material for high-grade lubricating oil and high-grade car sprayingmaterials.

Description

technical field [0001] The invention belongs to the field of biochemical industry, and relates to a method for fermenting and producing undecanedioic acid by Candida viesis, a product and a strain. Background technique [0002] Long-chain dibasic acids refer to dibasic acids with ten or more carbon atoms, and generally refer to straight-chain dibasic acids. Undecane dibasic acid (DC11) is an undecane dibasic acid used as advanced metalworking fluid, aromatic intermediate, high-grade lubricating oil, lubricating oil preservative and high-end car spraying material. It is used for polyamide engineering plastics, cutting The main raw material of liquid, hot melt adhesive, hindered amine light stabilizer long-chain dibasic acid diester. [0003] DC11 can be produced by microbial fermentation or chemical synthesis. The traditional chemical method for producing long-chain diacids requires 9 complicated reaction steps, high temperature, high pressure and catalysts; fireproof, expl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P7/64C12N1/16C12R1/72
CPCC12P7/6409C12N1/16C12R2001/72C12N1/165
Inventor 王绍冰修德恒万贺飞
Owner 张艾琳