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Treatment method for catalytically igniting VOCs for self-sustaining combustion at normal temperature

A technology of catalytic ignition and treatment methods, applied in the direction of combustion methods, combustion types, incinerators, etc., can solve the problems of lack of economic benefits, small total amount, and insufficient attention to waste gas emission treatment, etc., to achieve simple process, The effect of protecting the environment

Active Publication Date: 2020-05-08
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, petrochemical small-scale and pilot-scale test devices produce VOCs waste gas containing a certain amount of low unsaturated hydrocarbons. enough attention
So far, there is still a lack of catalytic combustion technology that is considered to have relatively high economic value for this type of VOCs exhaust gas at home and abroad.

Method used

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  • Treatment method for catalytically igniting VOCs for self-sustaining combustion at normal temperature
  • Treatment method for catalytically igniting VOCs for self-sustaining combustion at normal temperature

Examples

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Embodiment 1

[0035] This example is used to illustrate a method for treating VOCs waste gas containing a certain amount of low unsaturated hydrocarbons by catalytic ignition at room temperature of the present invention.

[0036] Finished catalyst A is packed in the reactor, and catalyst loading is 0.02L, accounts for 80 volume % of fixed-bed reactor. When the temperature of the catalyst bed in the reactor equipped with the doped noble metal composite oxide catalyst was 33°C, the VOCs waste gas (composition shown in Table 1) and the hydrogen gas of 1.5L / h were mixed with a volume flow rate of 12L / h They are passed into the reactor together, and then 20L / h of air is introduced to make the VOCs exhaust gas catalytically ignite, and the temperature of the catalyst bed rises rapidly to 450°C; it enters the catalytic self-sustaining combustion stage, and then stops the introduction of hydrogen and reduces the volume of the VOCs exhaust gas. The flow rate is adjusted to 6L / h, and air with a volum...

Embodiment 2

[0045] This embodiment is used to illustrate a kind of room temperature catalytic ignition of the present invention contains the VOCs waste gas treatment method of a certain amount of low unsaturated hydrocarbons and hydrogen.

[0046] Finished catalyst A is packed in the reactor, and catalyst loading is 0.02L, accounts for 80 volume % of fixed-bed reactor. When the temperature of the catalyst bed in the reactor equipped with the doped noble metal composite oxide catalyst was 33°C, the VOCs exhaust gas (composition shown in Table 2) with a volume flow rate of 12L / h was passed into the reactor, and then Introduce 20L / h of air to make the VOCs exhaust gas catalytically ignite, and the temperature of the catalyst bed rises rapidly to 450°C; enter the catalytic self-sustaining combustion stage, then adjust the volume flow rate of the VOCs exhaust gas to 6L / h, and feed 75L / h With the volume flow of air, the temperature of the catalyst bed rises rapidly to about 650 °C, and the VOCs...

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Abstract

The invention relates to the technical field of VOCs-containing waste gas treatment, in particular to a treatment method for catalytically igniting VOCs for self-sustaining combustion at normal temperature. The treatment method comprises the following steps that in a catalytic ignition stage, at normal temperature and normal pressure, when the temperature of a catalyst bed layer in a reactor filled with a doped noble metal composite oxide catalyst is 30-45 DEG C, VOCs waste gas and H<2> are introduced into the reactor, and then air is introduced to enable the VOCs waste gas to be catalyticallyignited and enter a catalytic self-sustaining combustion stage, H<2> introduction is stopped, the feeding flow of the VOCs waste gas is adjusted, the volume flow of introduced air is adjusted, the reaction is developed into the self-sustaining combustion reaction of the VOCs waste gas, and the VOCs waste gas is thoroughly oxidized into carbon dioxide and water and then discharged through an outlet of the reactor. Compared with a traditional VOCs catalytic combustion ignition technology, the method does not need external auxiliary heating, does not need a new ignition device, can be realized at normal temperature, is simple in process and is beneficial to environment protection.

Description

technical field [0001] The present invention relates to the technical field of VOCs-containing waste gas treatment, and furthermore, relates to a treatment method of normal temperature catalytic ignition VOCs self-sustained combustion. Background technique [0002] Common VOCs purification technologies include condensation method, adsorption method, absorption method, catalytic method, biological method, etc., and these methods are widely used. Among them, the catalytic method is to heat VOCs to the light-off temperature (200-450°C) to realize the catalytic and non-catalytic combustion reactions of VOCs to generate carbon dioxide and water. [0003] Patent CN106979526A provides a low-temperature plasma rapid ignition method for catalytic self-sustained combustion of VOCs at normal temperature and pressure. By placing a catalyst in the discharge area of ​​the plasma reactor, the gas discharge generates a low-temperature plasma after applying a voltage, and the reactor passes...

Claims

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Application Information

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IPC IPC(8): F23G7/07
CPCF23G7/07Y02A50/20
Inventor 杨沙沙王国清王育张利军刘小波彭晖刘俊杰马天石
Owner CHINA PETROLEUM & CHEM CORP
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