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Modified high-ignition-point transformer oil and preparation method thereof

A transformer oil, high ignition point technology, applied in the petroleum industry, lubricating composition and other directions, can solve the problems of high cost, inability to form a wide range of applications, insulation oil cooling performance, insulation and other performance anti-oxidation performance can not meet the requirements and other problems, to achieve fire protection The effect of strong performance, important practical significance and commercial value, and low price

Active Publication Date: 2020-06-16
STATE GRID HUNAN ELECTRIC POWER +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to solve the above problems, some scholars have successively developed polychlorinated biphenyl (PCB)-based insulating oil, silicone oil, synthetic ester (pentaerythritol ester), alpha oil, beta oil, polyalphaolefin, HMWH oil (polymer carbon Hydrogenated oil), vegetable insulating oil and other non-flammable or non-fuel products, but because these insulating oils either cannot meet the requirements of cooling performance, insulation performance and oxidation resistance, etc., or are high in cost, and need to be used at present. Transformation of mineral insulating oil transformers, otherwise there is a great risk, so it is impossible to form a wide range of applications

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A modified high ignition point transformer oil of the present invention, comprising the following components by mass fraction: 91% mineral insulating oil, 8% modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant, 1% liquid flame retardant agent cresyl diphenyl phosphate. Among them, the modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant is prepared by modifying the surface active agent oleic acid.

[0026] Taking the mass sum of nano magnesium hydroxide and nano aluminum hydroxide as 100%, the mass fraction of nano magnesium hydroxide is 70%, and the mass fraction of nano aluminum hydroxide is 30%.

[0027] In the nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant of this embodiment, the particle size of the nano-magnesium hydroxide is in the range of 20nm-50nm, and the particle size of the nano-aluminum hydroxide is in the range of 30nm-60nm.

[0028] In this embodiment, the mineral...

Embodiment 2

[0035] A modified high ignition point transformer oil of the present invention, comprising the following components by mass fraction: 93% mineral insulating oil, 6.5% modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant, 0.5% toluene diphenyl phosphate ester. Among them, the modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant is prepared by modifying the surface active agent oleic acid.

[0036] Taking the mass sum of nano magnesium hydroxide and nano aluminum hydroxide as 100%, the mass fraction of nano magnesium hydroxide is 80%, and the mass fraction of nano aluminum hydroxide is 20%.

[0037] In the nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant of this embodiment, the particle size of the nano-magnesium hydroxide is in the range of 20nm-50nm, and the particle size of the nano-aluminum hydroxide is in the range of 30nm-60nm.

[0038] In this embodiment, the mineral insulating oil is...

Embodiment 3

[0045] A modified high ignition point transformer oil of the present invention, comprising the following components by mass fraction: 92% mineral insulating oil, 7% modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant, 1% toluene diphenyl phosphate ester. Among them, the modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant is prepared by modifying the surface active agent oleic acid.

[0046] Taking the mass sum of nano magnesium hydroxide and nano aluminum hydroxide as 100%, the mass fraction of nano magnesium hydroxide is 70%, and the mass fraction of nano aluminum hydroxide is 30%.

[0047] In the nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant of this embodiment, the particle size of the nano-magnesium hydroxide is in the range of 20nm-50nm, and the particle size of the nano-aluminum hydroxide is in the range of 30nm-60nm.

[0048] In this embodiment, the mineral insulating oil is nap...

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Abstract

The invention discloses modified high-ignition-point transformer oil and a preparation method thereof. The modified high-ignition-point transformer oil is mainly composed of mineral insulating oil, amodified nano magnesium hydroxide / nano aluminum hydroxide composite flame retardant and cresyl diphenyl phosphate, wherein the modified nano magnesium hydroxide / nano aluminum hydroxide composite flameretardant is mainly prepared by modifying nano magnesium hydroxide and nano aluminum hydroxide with oleic acid. The preparation method comprises the following steps: (1) preparing the modified nano magnesium hydroxide / nano aluminum hydroxide composite flame retardant; (2) adding the composite flame retardant; and (3) adding the cresyl diphenyl phosphate. The modified high-ignition-point transformer oil disclosed by the invention has the characteristics of excellent heat dissipation performance and insulating performance of mineral insulating oil, low price and the like; the low-ignition-pointmineral insulating oil has the characteristics of high flame retardancy and high fire resistance, can replace the original conventional low-ignition-point mineral insulating oil without changing theexisting transformer, can be widely applied and popularized, and has important practical significance and commercial value.

Description

technical field [0001] The invention belongs to the technical field of insulating oil, and relates to a modified high ignition point transformer oil and a preparation method thereof, in particular to a nano flame retardant modified high ignition point transformer oil and a preparation method thereof. Background technique [0002] At present, transformers are basically oil-immersed transformers, and the most widely used transformer oil is mineral insulating oil, because mineral insulating oil has excellent electrical insulation, cooling performance and low cost. However, due to the low ignition point of mineral insulating oil, the transformer is prone to fire when a serious fault occurs, and the probability of fire is 5% to 15%. Therefore, there is an urgent need to develop high ignition point transformer oil to solve the above problems. [0003] In order to solve the above problems, some scholars have successively developed polychlorinated biphenyl (PCB)-based insulating oi...

Claims

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Application Information

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IPC IPC(8): C10M169/04C10N40/16
CPCC10M169/045C10M2201/062C10M2223/04C10M2207/126C10M2207/021
Inventor 魏加强黄颖万涛周挺黄海波龚尚昆周舟吴俊杰徐松刘奕奕
Owner STATE GRID HUNAN ELECTRIC POWER
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