Long-acting anti-fog silicon-based gel antifogging agent for lens and preparation method and application thereof

An anti-fogging agent, silicon-based technology, applied in the field of long-lasting anti-fogging silicon-based gel anti-fogging agent for lenses and its preparation, can solve the problems of virus transmission route and mechanism not fully revealed, pulmonary fibrosis, petrochemical, etc. Achieve the effects of avoiding human health threats, increasing surface adsorption, and inhibiting volatilization

Active Publication Date: 2020-08-11
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The pneumonia epidemic caused by the new coronavirus that broke out at the end of 2019 has led to an extreme shortage of medical resources and protective materials. At the same time, the transmission route and mechanism of the virus have not been fully revealed, resulting in the need for long-term wearing of masks and goggles by medical staff and on-duty personnel fighting on the front line. and protective clothing
Because of the relatively confined space, the nanoparticles in the anti-fog film on the surface of the goggles will be inhaled by the respiratory tract and deposited in the lungs, resulting in lung fibrosis or petrification; or they can freely pass through the cell membrane through the skin to interact with human proteins, bacteria and viruses. Very high risk of inducing underlying disease

Method used

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  • Long-acting anti-fog silicon-based gel antifogging agent for lens and preparation method and application thereof
  • Long-acting anti-fog silicon-based gel antifogging agent for lens and preparation method and application thereof

Examples

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Effect test

Embodiment 1

[0033] A long-term anti-fog silicon-based gel anti-fog agent for lenses, which is composed of a silicon-based sol solution and a long-chain polysaccharide / amino molecule cross-linking solution, wherein:

[0034] The preparation method of the silicon-based sol solution is: add 2wt% tetraethyl orthosilicate to the mixed solution of ethanol and isopropanol with a volume ratio of 1:1, and then use 0.1mol / L citric acid aqueous solution to adjust the mixing The pH of the liquid is within the range of 1-3, then add 5wt% cyclopentasiloxane and 1wt% polydimethylsiloxane crosslinked polymer, and make up the remaining water to 100%, and keep the magnetic force on The mixture was stirred for 60 minutes, and finally stood in the dark for 1 day to obtain the organosilicon sol solution.

[0035]The preparation method of the long-chain polysaccharide / amino molecule cross-linking solution is as follows: add 10wt% glucuronic acid-N-ethylthioglucosamine and 1wt% polyvinyl alcohol into deionized ...

Embodiment 2

[0043] A long-term anti-fog silicon-based gel anti-fog agent for lenses, which is composed of a silicon-based sol solution and a long-chain polysaccharide / amino molecule cross-linking solution, wherein:

[0044] The production method of the silicon-based sol solution is: add 2wt% tetraethyl orthosilicate to the mixed solution of ethanol and isopropanol with a volume ratio of 5:1, and then use 0.01-0.5mol / L citric acid aqueous solution to adjust The pH of the mixed liquid is within the range of 1-3, then add 3wt% cyclopentasiloxane and 1wt% polydimethylsiloxane crosslinked polymer, and make up the remaining water to 100%, and keep Magnetically stir the mixed solution for 10-60 minutes, and finally leave it in the dark for 1 day to obtain the organosilicon sol solution.

[0045] The preparation method of the long-chain polysaccharide / amino molecule cross-linking solution is as follows: add 4wt% glucuronic acid-N-ethylthioglucosamine and 1wt% polyvinyl alcohol into deionized wate...

Embodiment 3

[0047] A long-term anti-fog silicon-based gel anti-fog agent for lenses, which is composed of a silicon-based sol solution and a long-chain polysaccharide / amino molecule cross-linking solution, wherein:

[0048] The preparation method of the silicon-based sol solution is: add 6wt% tetraethyl orthosilicate to the mixed solution of ethanol and isopropanol with a volume ratio of 1:1, and then use 0.01-0.5mol / L citric acid aqueous solution to adjust The pH of the mixed liquid is within the range of 1-3, then add 15wt% cyclopentasiloxane and 10wt% polydimethylsiloxane cross-linked polymer, and make up 100% of the remaining water, and keep Magnetically stir the mixed solution for 10-60 minutes, and finally leave it in the dark for 1 day to obtain the organosilicon sol solution.

[0049] The preparation method of the long-chain polysaccharide / amino molecule cross-linking solution is as follows: add 10wt% glucuronic acid-N-ethylthioglucosamine and 5wt% polyvinyl alcohol into deionized...

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Abstract

The invention relates to a long-acting anti-fog silicon-based gel antifogging agent for a lens and a preparation method and application thereof. The antifogging agent is composed of a silicon-based sol solution and a long-chain polysaccharide/amino molecule crosslinking solution, the silicon-based sol solution comprises tetraethyl orthosilicate, cyclopentasiloxane, a polydimethylsiloxane crosslinking polymer and an organic solvent; the long-chain polysaccharide/amino molecule crosslinking solution comprises deionized water, polysaccharide molecules, polyvinyl alcohol, an amino molecule surfactant and a photocatalytic adhesive agent cerium oxide. Silica sol in the anti-fog sol is crosslinked with hydrophilic polysaccharide molecules and amino molecules to form a core-shell structure with arigid center and a soft long chain, water drops are enabled to evenly and rapidly expand whole surface through capillary action, and moisture absorption and antifogging effects are achieved; the long-chain polysaccharide/amino molecule is used as an end-capping reagent to inhibit the volatilization of a surfactant, cerium oxide is introduced to increase the surface adsorption force of silica sol,and the problem of poor light transmittance caused by poor adhesive force of an original water-based anti-fog coating film is solved.

Description

technical field [0001] The invention belongs to the technical field of surface coating modification materials, and in particular relates to a long-acting anti-fog silicon-based gel anti-fog agent for lenses, a preparation method and application thereof. Background technique [0002] The pneumonia epidemic caused by the new coronavirus that broke out at the end of 2019 has led to an extreme shortage of medical resources and protective materials. At the same time, the transmission route and mechanism of the virus have not been fully revealed, resulting in the need for long-term wear of masks and goggles by medical staff and on-duty personnel fighting on the front line. and protective clothing. The current commercial goggles with anti-fog performance are prone to fogging after continuous use for more than 1 hour, affecting the visual function of the user to varying degrees, and in severe cases, causing the user to lose sight and lose working ability. Feedback from medical staf...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/04C09D105/00C09D129/04C09D7/65C09D7/61C08J3/24C08J7/054G02B1/18G02C7/02C08L5/00C08L29/04C08L101/00
CPCC08J3/246C08J2300/00C08J2305/00C08J2405/00C08J2429/04C08J2483/04C08K2003/2213C08L2201/10C08L2205/025C08L2205/035C09D105/00C09D183/04C09D7/61C09D7/65G02C7/02G02B1/18C08L83/04C08L5/00C08L29/04C08K3/22
Inventor 郭芳威胡凌越洪蔚刘悦徐亦斌朱彦彦赵晓峰
Owner SHANGHAI JIAO TONG UNIV
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