Modified fly ash adsorbent for flue gas demercuration and preparation method thereof
An adsorbent and fly ash technology, which is applied in the field of modified fly ash adsorbent and its preparation, can solve the problems of low mercury removal efficiency of fly ash, mercury removal efficiency of power plants cannot meet the emission standards of co-pollutants, and increase injection costs, etc. , to achieve the effects of improving the apparent structure and pore structure, increasing the type and quantity, and improving the adsorption and oxidation capacity
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Embodiment 1
[0026] Weigh 1.5g CuCl 2 2H 2 O into the beaker, and then weighed 0.5gFeCl 3 ·6H 2 O and CuCl 2 2H 2 O mixed, adding 100 g of deionized water, after the chloride was completely dissolved, a mixed chloride solution was obtained. Weigh 5g of fly ash into a beaker, stir in an electromagnetic stirrer for 3h, let it stand for 10h, filter off the supernatant, put the remaining solid in a drying oven, and dry it in a drying oven at 50°C for 12h. The dried solid is ground into powder to obtain 1.5% CuCl 2 -0.5% FeCl 3 Modified fly ash adsorbent.
Embodiment 2
[0028] Weigh 1gCuCl 2 2H 2 O into the beaker, and then weigh 1gFeCl 3 ·6H 2 O and CuCl 2 2H 2 O mixed, adding 100 g of deionized water, after the chloride was completely dissolved, a mixed chloride solution was obtained. Weigh 5g of fly ash into a beaker, stir in an electromagnetic stirrer for 5h, let it stand for 12h, filter off the supernatant, put the remaining solid in a drying oven, and dry it in a drying oven at 60°C for 10h. The dried solid is ground into powder to obtain 1% CuCl 2 -1% FeCl 3 Modified fly ash adsorbent.
Embodiment 3
[0030] Weigh 0.5gCuCl 2 2H 2 O put into a beaker, and weigh 1.5g FeCl 3 ·6H 2 O and CuCl 2 2H 2 O mixed, adding 100 g of deionized water, after the chloride was completely dissolved, a mixed chloride solution was obtained. Weigh 5g of fly ash into a beaker, stir in an electromagnetic stirrer for 7h, let stand for 13h, filter off the supernatant, put the remaining solid in a drying oven, and dry it in a drying oven at 80°C for 9h. The dried solid is ground into powder to obtain 0.5% CuCl 2 -1.5% FeCl 3 Modified fly ash adsorbent.
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