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Modified fly ash adsorbent for flue gas demercuration and preparation method thereof

An adsorbent and fly ash technology, which is applied in the field of modified fly ash adsorbent and its preparation, can solve the problems of low mercury removal efficiency of fly ash, mercury removal efficiency of power plants cannot meet the emission standards of co-pollutants, and increase injection costs, etc. , to achieve the effects of improving the apparent structure and pore structure, increasing the type and quantity, and improving the adsorption and oxidation capacity

Active Publication Date: 2020-09-22
CHONGQING UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented new catalyst for removing harmful gases (mercaptans) from combustion exhaust fumes contains cuprous iron hydroxides together with other metals like zinc, cobalt, manganese, etc., along with oxygen containing halogen atoms such as fluorous acid. These metal compounds enhance the activity towards reducing nitrogen dioxide emissions by converting them into carbon monoxide and water vapor. By adding these components during manufacture, the resulting modified flyash material becomes more effective than existing materials due to its unique chemical structures. Additionally, the addition of different types of redozole helps activated sulfuric acids efficiently convert Hg0 molecules onto their surfaces without forming insoluble salts. Overall, this new catalysis system provides technical benefits including efficient reduction of pollutants released through various methods, reduced costs associated with production processes, increased usability of fly Ashes used in emission control systems, and promoting use of injected technologies.

Problems solved by technology

This technical problem addressed in this patented text relates to reducing environmental concerns caused by combustion emissions such as nitrogen dioxide ("NOX"), sulfur compounds, particulate matter, hydrocarbon gases, heavy metals like selenium or chromium, and other substances released during operation. Current technologies aimed towards achieving better control over these contaminating elements include regulations set forth under China Code Regulation No. 2004-2003. These regulators require stricter levels of exhaust gas emitted per country than previously acceptable limits while also requiring effective treatment techniques to effectively reduce airborne hazardous materials including ammonia and formaldehydes.

Method used

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  • Modified fly ash adsorbent for flue gas demercuration and preparation method thereof
  • Modified fly ash adsorbent for flue gas demercuration and preparation method thereof
  • Modified fly ash adsorbent for flue gas demercuration and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0026] Weigh 1.5g CuCl 2 2H 2 O into the beaker, and then weighed 0.5gFeCl 3 ·6H 2 O and CuCl 2 2H 2 O mixed, adding 100 g of deionized water, after the chloride was completely dissolved, a mixed chloride solution was obtained. Weigh 5g of fly ash into a beaker, stir in an electromagnetic stirrer for 3h, let it stand for 10h, filter off the supernatant, put the remaining solid in a drying oven, and dry it in a drying oven at 50°C for 12h. The dried solid is ground into powder to obtain 1.5% CuCl 2 -0.5% FeCl 3 Modified fly ash adsorbent.

Embodiment 2

[0028] Weigh 1gCuCl 2 2H 2 O into the beaker, and then weigh 1gFeCl 3 ·6H 2 O and CuCl 2 2H 2 O mixed, adding 100 g of deionized water, after the chloride was completely dissolved, a mixed chloride solution was obtained. Weigh 5g of fly ash into a beaker, stir in an electromagnetic stirrer for 5h, let it stand for 12h, filter off the supernatant, put the remaining solid in a drying oven, and dry it in a drying oven at 60°C for 10h. The dried solid is ground into powder to obtain 1% CuCl 2 -1% FeCl 3 Modified fly ash adsorbent.

Embodiment 3

[0030] Weigh 0.5gCuCl 2 2H 2 O put into a beaker, and weigh 1.5g FeCl 3 ·6H 2 O and CuCl 2 2H 2 O mixed, adding 100 g of deionized water, after the chloride was completely dissolved, a mixed chloride solution was obtained. Weigh 5g of fly ash into a beaker, stir in an electromagnetic stirrer for 7h, let stand for 13h, filter off the supernatant, put the remaining solid in a drying oven, and dry it in a drying oven at 80°C for 9h. The dried solid is ground into powder to obtain 0.5% CuCl 2 -1.5% FeCl 3 Modified fly ash adsorbent.

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Abstract

The invention provides a modified fly ash adsorbent for flue gas demercuration. The modified fly ash adsorbent comprises copper chloride, ferric chloride and fly ash in a mass ratio of (1-6): (1-6): 5. The copper-iron-chlorine modified fly ash adsorbent is low in cost, simple and convenient in preparation method and high in mercury removal efficiency. The copper-iron-chlorine modified fly ash adsorbent can remove mercury in flue gas, so that the utilization efficiency of fly ash can be remarkably improved, and the injection cost is reduced.

Description

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Claims

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Application Information

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Owner CHONGQING UNIV
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