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Normal-temperature curable resin system for replicating antenna reflecting surface and preparation method thereof

A technology of room temperature curing and reflective surface, which is applied to antennas, electrical components, etc., can solve the problems that the antenna reflective surface cannot be copied at room temperature and the use time at room temperature is short, and achieve the effect of meeting the process requirements of room temperature copy process and increasing the use time at room temperature

Pending Publication Date: 2020-10-27
SHANGHAI COMPOSITES SCI & TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the digital normal temperature use time is short, about 30 minutes, which cannot meet the normal temperature replication requirements of the antenna reflector (vacuum defoaming 5h, operation 1h, supply and demand 6h)

Method used

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  • Normal-temperature curable resin system for replicating antenna reflecting surface and preparation method thereof
  • Normal-temperature curable resin system for replicating antenna reflecting surface and preparation method thereof
  • Normal-temperature curable resin system for replicating antenna reflecting surface and preparation method thereof

Examples

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Effect test

Embodiment 1

[0034] This embodiment provides a room temperature curing resin system, and its components and parts by weight are shown in Table 1. Its preparation method comprises the following steps:

[0035] 1) Take 100 parts of novolac epoxy resin F-44, 35 parts of 3,4 epoxycyclohexylcarboxylate-3',4'-epoxycyclohexylmethyl ester (viscosity at 25°C is 400mPa.s) and mix Carry out mechanical stirring (rotating speed 2000 revs / min) after 15min for subsequent use;

[0036] 2) Take 4 parts of triethylenetetramine and 35 parts of menthanediamine (MDA, viscosity at 25°C is 19mPa.s) curing agent, mix them mechanically (speed 4000 rpm) for 10 minutes, and then let stand for 24 hours;

[0037] 3) Put the two mixed liquids above into the refrigerator for storage for later use, which can be used in the high-precision replication process of the antenna reflector later.

Embodiment 2

[0039] This embodiment provides an epoxy resin system cured at room temperature for use at medium and high temperatures, and its components and parts by weight are shown in Table 1. Its preparation method comprises the following steps:

[0040] 1) Take 100 parts of novolac epoxy resin F-51 and 35 parts of 3,4 epoxycyclohexylcarboxylate-3',4'-epoxycyclohexylmethyl ester (viscosity at 25°C is 400mPa.s) and mix Carry out mechanical stirring (rotating speed 2000 revs / min) after 15min for subsequent use;

[0041] 2) Mix 5 parts of triethylenetetramine and 40 parts of menthanediamine (MDA, viscosity at 25°C is 19mPa.s) curing agent, stir mechanically (rotating speed: 4000 rpm) for 10 minutes and let stand for 24 hours;

[0042] 3) Put the two mixed liquids above into the refrigerator for storage for later use, which can be used in the process of high-precision reflective surface and high reproduction ratio in the future.

Embodiment 3

[0044] This embodiment provides a room temperature curing resin system, and its components and parts by weight are shown in Table 1. Its preparation method comprises the following steps:

[0045] 1) Take 110 parts of novolac epoxy resin F-44, 30 parts of 3,4 epoxycyclohexylcarboxylate-3',4'-epoxycyclohexylmethyl ester (viscosity at 25°C is 400mPa.s) and mix Carry out mechanical stirring (rotating speed 3000 revs / min) after 20min for subsequent use;

[0046] 2) Mix 4 parts of triethylenetetramine and 32 parts of menthane diamine (MDA, viscosity at 25°C is 19mPa.s) curing agent, mix them mechanically (speed 2000 rpm) for 15 minutes, and then let stand for 24 hours;

[0047] 3) Put the two mixed liquids above into the refrigerator for storage for later use, which can be used in the high-precision replication process of the antenna reflector later.

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Abstract

The invention discloses a normal-temperature curable resin system for replicating an antenna reflecting surface and a preparation method thereof. The normal-temperature curable resin system comprisesthe following components by weight: A: 90-110 parts of phenolic epoxy resin and 30-40 parts of alicyclic epoxy resin; and B: 4-6 parts of triethylene tetramine and 30-40 parts of an alicyclic amine curing agent. The epoxy resin system obtained by the invention can be used for an antenna reflecting surface normal-temperature replication molding process to obtain a high-precision antenna reflectingpanel.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a normal temperature curing resin system, in particular to a normal temperature curing resin system for duplicating antenna reflection surfaces and a preparation method thereof. Background technique [0002] Due to its low density, high specific stiffness, high specific strength, and small thermal expansion coefficient (close to zero by design), resin-based composite materials have become the most ideal materials for preparing high-precision and high-stability antenna reflectors. However, due to the composite material molding process During the curing process, the difference in thermal expansion coefficient between the resin matrix and the carbon fiber and the curing shrinkage of the resin matrix will cause residual stress inside the antenna panel after curing, and warp and deformation of the antenna reflector panel after demoulding. Therefore, a new The pro...

Claims

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Application Information

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IPC IPC(8): C08L63/04C08L63/00C08G59/50H01Q15/14
CPCC08L63/04C08G59/5006C08G59/5026C08G59/5073H01Q15/14C08L2203/20C08L2205/02C08L63/00
Inventor 徐宏涛郝旭峰鞠博文张尉博王晓蕾戴晶滨李钱福吴泽州梁燕民田杰
Owner SHANGHAI COMPOSITES SCI & TECH CO LTD
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