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Waterborne polyurethane compound paint and production method thereof

A technology of water-based polyurethane and composite coatings, which is applied in the direction of polyurea/polyurethane coatings, epoxy resin coatings, coatings, etc., and can solve the problems of poor water penetration resistance and low mechanical strength

Inactive Publication Date: 2020-11-24
杭州丽彩文化用品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Waterborne polyurethane has the characteristics of high hardness, good toughness and excell

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A kind of water-based polyurethane composite paint, comprises following raw materials in parts by weight:

[0032] 20 parts of polytetrahydrofuran diol, 1 part of 1,4-butanediol, 2 parts of 2,2-dimethylol propionic acid, 12 parts of isophorone diisocyanate, 4 parts of N,N-dimethylacetamide , 0.1 part of dibutyltin dilaurate, 16 parts of acetone, 200 parts of deionized water, 0.1 part of diethylenetriamine, 40 parts of modified epoxy resin, 0.1 part of defoamer, 0.1 part of wetting agent, and 0.1 part of leveling agent part and 0.1 part of thickener;

[0033] This waterborne polyurethane composite coating is prepared by the following steps:

[0034] The first step, put polytetrahydrofuran diol and 1,4-butanediol into a three-necked flask, put the three-necked flask into a vacuum drying oven at 70°C, and dry it in vacuum for 2 hours. After the drying, take out the flask and cool the three-necked flask to 20°C, add 2,2-dimethylolpropionic acid, isophorone diisocyanate, N...

Embodiment 2

[0047] A kind of water-based polyurethane composite paint, comprises following raw materials in parts by weight:

[0048] 25 parts of polytetrahydrofuran diol, 2 parts of 1,4-butanediol, 3 parts of 2,2-dimethylol propionic acid, 13 parts of isophorone diisocyanate, 5 parts of N,N-dimethylacetamide , 0.2 parts of dibutyltin dilaurate, 18 parts of acetone, 250 parts of deionized water, 0.2 parts of diethylenetriamine, 45 parts of modified epoxy resin, 0.2 parts of defoamer, 0.2 parts of wetting agent, and 0.2 parts of leveling agent part and 0.2 part of thickener;

[0049] This waterborne polyurethane composite coating is prepared by the following steps:

[0050] The first step, put polytetrahydrofuran diol and 1,4-butanediol into a three-necked flask, put the three-necked flask into a vacuum drying oven at 75°C, and dry it in vacuum for 2.5 hours. After drying, take out the flask and cool the three-necked flask To 25°C, add 2,2-dimethylolpropionic acid, isophorone diisocyanat...

Embodiment 3

[0063] A kind of water-based polyurethane composite paint, comprises following raw materials in parts by weight:

[0064]30 parts of polytetrahydrofuran diol, 3 parts of 1,4-butanediol, 4 parts of 2,2-dimethylol propionic acid, 14 parts of isophorone diisocyanate, 6 parts of N,N-dimethylacetamide , 0.3 parts of dibutyltin dilaurate, 20 parts of acetone, 300 parts of deionized water, 0.3 parts of diethylenetriamine, 50 parts of modified epoxy resin, 0.3 parts of defoamer, 0.3 parts of wetting agent, and 0.3 parts of leveling agent part and 0.3 part of thickener;

[0065] This waterborne polyurethane composite coating is prepared by the following steps:

[0066] The first step, put polytetrahydrofuran diol and 1,4-butanediol into a three-necked flask, put the three-necked flask in a vacuum drying oven at 80°C, and dry it in vacuum for 3 hours. After the drying, take out the flask and cool the three-necked flask to 30°C, add 2,2-dimethylolpropionic acid, isophorone diisocyanate...

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Abstract

The invention discloses waterborne polyurethane compound paint. The waterborne polyurethane compound paint comprises the following raw materials in parts by weight: 20-30 parts of poly(tetrahydrofuran), 1-3 parts of 1,4-butanediol, 2-4 parts of 2,2-bis(hydroxymethyl)propionic acid, 12-14 parts of isophorone diisocyanate, 4-6 parts of N,N-dimethylacetamide, 0.1-0.3 part of dibutyltin dilaurate, 16-20 parts of acetone, 200-300 parts of deionized water, 0.1-0.3 part of diethylenetriamine, 40-50 parts of modified epoxy resin, 0.1-0.3 part of a defoaming agent, 0.1-0.3 part of a wetting agent, 0.1-0.3 part of a flatting agent and 0.1-0.3 part of a thickener. Aerogel and epoxy resin can form hydrogen bonds, Van Der Walls action force between molecules is enhanced, thus the modified epoxy resin is more beneficial for improving the mechanical performance of a coating, and along with increase of a molecular weight and the cross-linking density, inward diffusion of water is hindered, so that thewater resistance of the paint is improved.

Description

technical field [0001] The invention belongs to the technical field of water-based paint preparation, and in particular relates to a water-based polyurethane composite paint and a preparation method thereof. Background technique [0002] Polyurethane coating is a common type of coating at present. It has the characteristics of low film-forming temperature, strong adhesion, good wear resistance, high hardness, chemical resistance and weather resistance. Waterborne polyurethane has the characteristics of high hardness, good toughness and excellent corrosion resistance, but has low mechanical strength and poor water penetration resistance. [0003] Invention patent CN103102718A discloses a water-based polyurethane composite coating, which is characterized in that the coating is made of the following raw materials in parts by weight: 40-60 parts of water-based polyurethane emulsion, 12-25 parts of polyacrylic acid, 20-30 parts of polyisocyanate, 30-40 parts of joint agent, 10-1...

Claims

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Application Information

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IPC IPC(8): C09D175/08C08L63/00C09D7/62C09D175/04
CPCC09D163/00C09D175/04C09D175/08C09D7/62C09D7/70C08L63/00C08K9/08C08K9/06C08K7/26C08L75/08
Inventor 刘国聪胡庭维
Owner 杭州丽彩文化用品有限公司