The invention discloses a nano-composite superhydrophobic icing-proof coating material. The nano-composite superhydrophobic icing-proof coating material comprises the following components in percentage by mass: 5-50% of fluorine-containing acrylate copolymer-modified inorganic nanoparticles and 50-95% of an organic solvent. A preparation method for the nano-composite superhydrophobic icing-proof coating material comprises the following steps: uniformly mixing nano-SiO2, methylbenzene and 3-aminopropyl triethoxysilane, and performing refluxing reaction in an oil bath to obtain amino-modified SiO2-NH2 inorganic nanoparticles; uniformly mixing the SiO2-NH2, dichloromethane, triethylamine and 2-bromoisobutyryl bromide, and reacting in an ice-water bath to obtain 2-bromoisobutyryl bromide-grafted nanoparticle SiO2-NH-Br; uniformly mixing the SiO2-NH-Br, an acrylate monomer, fluorine-containing acrylate, CuX, methylbenzene and a ligand, deoxidizing, precipitating, performing centrifugal separation, and dissolving a product into the organic solvent to obtain the nano-composite superhydrophobic icing-proof coating material. The nano-composite superhydrophobic icing-proof coating material has excellent performance, lasting low surface energy and superhydrophobicity, and good icing-proof performance and has the effect of prolonging the icing time, and can be widely used for prevention and control of icing on the surfaces of communication lines, fan blades, airport facilities, airplane wings and the like.