Self-repairing anti-icing aluminum stranded wire with composite holes and preparation method of self-repairing anti-icing aluminum stranded wire

An aluminum stranded wire, self-repairing technology, applied in the direction of cable/conductor manufacturing, conductors, non-insulated conductors, etc., can solve problems such as anti-icing failure, structural damage, and limited application prospects, so as to improve poor self-repairability and improve self-repair The effect of ability and broad application prospects

Inactive Publication Date: 2021-09-28
CHONGQING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the energy consumption required for the current ice melting process is large, and the power needs to be cut off during the ice melting process. In addition, uneven ice removal during the ice melting process is prone to tower collapse
The micro-nano structure and low surface energy components of the traditional super-hydrophobic surface are very fragile, and are prone to structural damage under external physical effects, resulting in anti-icing failure; in addition, conventional super-hydrophobic surfaces cannot inhibit ice coating in low-temperature and high-humidity environments, such as : Frosting, rime, freezing rain and icing, etc., but because water vapor enters the micro-nano structure and condenses, it loses the anti-icing effect and even gradually develops into a hydrophilic surface, which aggravates icing, which restricts its practical application; at the same time, traditional coatings / paints Poor combination with the substrate leads to short service life and limits related application prospects

Method used

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  • Self-repairing anti-icing aluminum stranded wire with composite holes and preparation method of self-repairing anti-icing aluminum stranded wire
  • Self-repairing anti-icing aluminum stranded wire with composite holes and preparation method of self-repairing anti-icing aluminum stranded wire
  • Self-repairing anti-icing aluminum stranded wire with composite holes and preparation method of self-repairing anti-icing aluminum stranded wire

Examples

Experimental program
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Effect test

Embodiment 1

[0038] A self-repairing anti-icing aluminum stranded wire with composite holes, which is prepared by anodizing twice, specifically includes the following steps:

[0039] (1) The first anodic oxidation: wash the aluminum substrate (aluminum alloy core aluminum strand ) as the anode is placed in the phosphoric acid electrolyte (the concentration of phosphoric acid is 0.3mol / L, the solvent is water), the ring electrode made of 304 stainless steel plate is the cathode, and the applied current density is 0.15A / cm 2 DC current, and then perform the first anodic oxidation at 25°C for 15 minutes to form outer layer pores with a pore diameter of 250nm and a pore depth of 26um on the surface of the aluminum substrate;

[0040](2) Second anodic oxidation: place the product in step (1) as an anode in oxalic acid electrolyte (the concentration of oxalic acid is 0.15mol / L, and the solvent is water), lead plate, aluminum plate, graphite plate or 304 stainless steel The ring electrode made o...

Embodiment 2

[0043] A self-repairing anti-icing aluminum stranded wire with composite holes, which is prepared by anodizing twice, specifically includes the following steps:

[0044] (1) The first anodic oxidation: put the cleaned aluminum alloy strand as the anode in phosphoric acid In the electrolyte (the concentration of phosphoric acid is 0.3mol / L, the solvent is water), the ring electrode made of lead plate is the cathode, and the applied current density is 0.2A / cm 2 DC current, and then perform the first anodic oxidation at a temperature of 10°C for 10 minutes to form outer layer pores with a pore depth of 20um and a pore diameter of 220nm on the surface of the aluminum substrate;

[0045] (2) second anodic oxidation: the product in step (1) is placed as the anode in the oxalic acid electrolyte (the concentration of oxalic acid is 0.1mol / L, and the solvent is water), and the ring electrode made of the lead plate is the negative electrode, The applied current density is 0.1A / cm 2 Af...

Embodiment 3

[0048] A self-repairing anti-icing aluminum stranded wire with composite holes, which is prepared by anodizing twice, specifically includes the following steps:

[0049] (1) The first anodic oxidation: wash the aluminum substrate (steel-cored aluminum strand) (firstly wash the aluminum substrate in clean water, and then place it in a 1mol / L sodium hydroxide solution for 2 minutes) As the anode, it is placed in a phosphoric acid electrolyte (the concentration of phosphoric acid is 0.15mol / L, and the solvent is water), and the ring electrode made of aluminum plate is the cathode, and the applied current density is 0.1A / cm 2 DC current, and then carry out the first anodic oxidation at 50°C for 25 minutes to form outer layer pores with a pore diameter of 180nm and a pore depth of 35um on the surface of the aluminum substrate;

[0050] (2) The second anodic oxidation: the product in step (1) is placed as the anode in the oxalic acid electrolyte (the concentration of oxalic acid is ...

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Abstract

The invention relates to a self-repairing anti-icing aluminum stranded wire with composite holes and a preparation method of the self-repairing anti-icing aluminum stranded wire, and belongs to the technical field of anti-icing material preparation. According to the self-repairing anti-icing aluminum stranded wire with the composite holes provided by the invention, the uniform porous aluminum oxide film grows on the surface of the aluminum substrate to form small-aperture inner layer holes (for storing a repairing agent for a long time) and large-aperture outer layer holes (for improving the anti-icing performance by increasing the air cushion proportion), the anti-icing aluminum wire with lasting and excellent anti-icing self-repairing performance is prepared by optimizing the aperture and thickness of the large holes (outer holes) and the small holes (inner holes) and filling a low-surface-energy repairing agent in the holes under the action of air pressure, capillary force and surface energy. The anti-icing performance of the aluminum stranded wire in practical application and self-repairing of the anti-icing performance after the aluminum stranded wire is damaged are improved, so that the anti-icing service life of the aluminum stranded wire is prolonged, and the lasting anti-icing performance of the aluminum stranded wire is improved. According to the self-repairing anti-icing aluminum stranded wire with the composite holes, repeated self-repairing of the anti-icing performance is achieved, and meanwhile, the hardness and the abrasion resistance of the film layer are improved.

Description

technical field [0001] The invention belongs to the field of anti-icing material preparation, and relates to a self-repairing anti-icing aluminum stranded wire with composite holes and a preparation method thereof. Background technique [0002] In the current stage, the anti-icing technology is mainly electric current melting ice, which belongs to passive anti-icing. The material prevents or delays the icing on the surface of the wire, and the ice adhesion is low after icing, so that the ice can be easily removed, or the ice can be melted by heat. [0003] However, the energy consumption required for the current ice melting process is large, and the power needs to be cut off during the ice melting process. In addition, uneven ice removal during the ice melting process is prone to tower collapse. The micro-nano structure and low surface energy components of the traditional super-hydrophobic surface are very fragile, and are prone to structural damage under external physical ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B5/08H01B5/00H01B13/02
CPCH01B5/08H01B5/00H01B13/02C09K3/18C25D11/024C25D11/08C25D11/12C25D11/10C25D11/246C25D11/16C23F13/005C23F2213/30
Inventor 袁媛刘国勇廖瑞金向会英
Owner CHONGQING UNIV
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