433 results about "Large pore size" patented technology

The invention discloses a lithium battery diaphragm with a gradient pore structure and a preparation method thereof, the lithium battery diaphragm with the gradient pore structure is of a layered structure, the layered structure comprises a base membrane, a first coating and a second coating, the first coating and the second coating are located on the same side of the base membrane, the first coating is connected with one side of the base membrane, and the second coating is connected with the other side of the base membrane. The second coating is connected with the first coating, the porosity of the first coating is 40-50%, the porosity of the second coating is 30-40%, the first coating comprises large-aperture porous alumina, and the second coating comprises small-aperture porous alumina. A double-layer structural design is adopted, and the two coatings have different pore diameters, so that a gradient pore diameter structure is formed. The structure can realize gradual adaptation of ions in the charging and discharging process of the battery and reduce migration energy obstacles.

The invention discloses a large-aperture aluminum oxide loaded copper-based catalyst as well as preparation and application thereof. The large-aperture alumina-loaded copper-based catalyst comprises a large-aperture alumina carrier, and copper oxide and lanthanum oxide loaded on the surface of the large-aperture alumina carrier, the large-aperture alumina-loaded copper-based catalyst is granular, the specific surface area is 250-500 m < 2 > / g, the pore volume is 1.0-2.0 cm < 3 > / g, the average aperture is 16-30 nm, and the pore diameter of the large-aperture alumina-loaded copper-based catalyst is 20-30 nm. The large-aperture alumina supported copper-based catalyst comprises the following components in percentage by mass: 79%-98.9% of a large-aperture alumina carrier, 0.1%-6% of copper oxide and 1%-15% of lanthanum oxide. The large-aperture aluminum oxide loaded copper-based catalyst disclosed by the invention shows relatively high catalytic activity and higher alcohol selectivity in a reaction for preparing higher alcohol from ethanol, and particularly has relatively high C6-C10 fatty alcohol selectivity.

The invention provides an aggregation-induced emission molecule, a nano motor and a preparation method and application of the aggregation-induced emission molecule, the aggregation-induced emission molecule is used for near-infrared emission, has photo-thermal properties, and has the characteristics of near-infrared II region luminescence, heat production and good light stability; the nano motor is prepared by taking an asymmetric double-mesoporous nano material with different pore diameters as a support material and selectively loading aggregation-induced emission molecules on one side of the support material with a larger pore diameter; under the irradiation of near-infrared light, the aggregation-induced emission molecules with the photothermal effect can form a non-uniform thermal gradient to push the self-thermophoresis movement of the nano motor; tumor sites can be diagnosed and reported under the mediation of near-infrared II region imaging; through the photo-thermal effect, the motor can destroy tumor interstitial cells and degrade tumor matrix components; and in combination with autothermophoresis, blood vessels can be penetrated, so that penetration to the deep layer of the tumor can be realized.

The invention provides a large-aperture alumina carrier as well as a preparation method and application thereof. The large-aperture alumina carrier is prepared from dry materials and water, and the dry materials comprise inert fibers, aluminum hydroxide and ammonium aluminum carbonate. According to the invention, under the condition of low water-powder ratio, primary pores and secondary accumulation pores in aluminum hydroxide and ammonium aluminum carbonate are reserved to the greatest extent under high extrusion pressure in the carrier extrusion and molding process due to the enhancement effect of inert fibers; although the apertures of the primary pores, the secondary accumulation pores and the macropores generated by decomposition of the ammonium aluminum carbonate are reduced during roasting of the carrier, the volume ratio of the pores with the pore size of more than 500nm in the final carrier is still obviously increased due to the existence of the inert fibers, and the volume ratio of the pores with the pore size of more than 500nm is 15-25%. In addition, the by-product ammonium aluminum carbonate generated in the recovery process of the waste ethylene oxide catalyst is used as the raw material and the macroporous pore-enlarging agent, so that the production cost of the large-aperture alumina carrier is reduced. The prepared large-aperture alumina carrier can be used for preparing a residual oil hydrodemetallization catalyst.

The invention relates to a porous carbon material as well as a preparation method and application thereof. The specific surface area of the porous carbon material is 1500-3000m < 2 > / g, and pore channels are intensively distributed in a range of 0.6-2.0 nm. The preparation method of the porous carbon material comprises the following steps: (1) montmorillonite acid treatment; (2) uniformly mixing the acid-treated montmorillonite obtained in the step (1) with asphalt, and carrying out carbonization treatment to obtain a carbonized material; and (3) under the inert atmosphere condition, mixing the carbonized material with an activating agent for activation, and then washing and drying. The porous carbon material obtained by the invention has the advantages of large specific surface area, reasonable pore size distribution, high ion transmission speed and the like, and is a super-capacitor carbon material with excellent rate capability.

The degradable breast prosthesis shaping net bag with the heterogeneous hierarchical porous structure is composed of the large-aperture structure layer and the micro-aperture structure layer, the large-aperture structure layer and the micro-aperture structure layer are formed by combining degradable fibers in a staggered mode, the degradable breast prosthesis shaping net bag and the breast prosthesis are perfectly conformal, and the mechanical property and the tissue adhesion property needed by the net bag are provided; the two cooperate to realize the integration function of the prosthesis and the tissue, and an additional suture fixing device is not needed; the overall shape of the net bag is designed to be the hemispherical upper cover and the lower end cover edge, the process of adding the net bag and a prosthesis is simplified, the operation efficiency is improved, the net bag has excellent mechanical performance and shaping capacity, the micropore structure is beneficial to adhesion and immigration of cells, rejection reaction of a body is reduced, the incidence rate of capsular contracture is remarkably reduced, and the net bag is suitable for popularization and application. The invention has the characteristics of hierarchical porous structure design, mechanical shaping capability customization and capsule contracture prevention, and provides an innovative breast prosthesis shaping and biological performance improvement scheme for breast cancer patients.

The invention discloses a silicon-carbon composite material and a preparation method thereof. The composite material is composed of porous hard carbon, inorganic lithium salt doped with the porous hard carbon and a porous metal frame as a matrix, nano silicon deposited in pores of the matrix, and an amorphous carbon composite material coated on the surface. The preparation method comprises the following steps: uniformly mixing resin, inorganic lithium salt and a porous metal framework, and carrying out hydrothermal reaction, activation and secondary carbonization to obtain a porous carbon complex; and depositing nano silicon and coating the nano silicon with an organic lithium salt through a vapor deposition method to obtain the silicon-carbon composite material. According to the obtained material, expansion is reduced through large-aperture deposited nanometer silicon of the metal frame structure, the defects are reduced through the inorganic lithium salt of the inner core and the organic lithium salt of the outer shell, the ion diffusion rate is increased, and the first efficiency and the rate performance are improved.

The invention discloses a coated diaphragm and a preparation method thereof, and belongs to the technical field of lithium batteries. The coated diaphragm comprises a base film and a coating layer, the coating layer is attached to at least partial area of the base film, and the coating layer comprises a covalent triazine framework; a covalent triazine framework is used as a component of a coating layer, the covalent triazine framework is a porous organic polymer which is good in stability, ordered in structure, strong in polarity, large in specific surface area and controllable in pore diameter, and the thermal stability of the coated diaphragm can be improved due to the good stability of the covalent triazine framework; the relatively small mass density does not have obvious influence on the energy density of the battery; due to the high specific surface area and the strong polarity, the affinity of the diaphragm to an electrolyte can be improved, and the diaphragm has higher liquid absorption and liquid retention capabilities; the nano-scale pore structure can inhibit anion migration, reduce internal polarization of the battery, improve the capacity of the battery and prolong the cycle life of the battery, thereby achieving the effect of improving the comprehensive performance of the battery.

The invention discloses a waterproof long-lasting oil-control gel composition and a preparation method thereof, and belongs to the technical field of cosmetics. The composition comprises 4-6 parts of an oil absorption compound A, 9-13 parts of an oil absorption compound B and 70-95 parts of a gel matrix, wherein the oil absorption compound A is prepared from mesoporous silica and poloxamer 407, and the aperture of the oil absorption compound A is 5-10 nm; the oil absorption compound B is prepared from polymethyl methacrylate microspheres, isododecane and polyglycerol-3 diisostearate, and the pore diameter of the oil absorption compound B is 150 to 300 nm. According to the invention, through dual mechanisms of temperature response and volatilization driving, a dynamic gradient structure of bottom layer small aperture-surface layer large aperture is formed at skin temperature, and directional migration of grease is realized; meanwhile, the surface property transformation of the material after oil absorption is creatively utilized, a hydrophobic membrane is formed on the surface of the polymethyl methacrylate microsphere, a self-enhanced waterproof barrier is constructed, the unique effect that the more oil is absorbed, the more water is resisted is achieved, the problem of makeup removal caused by sebum and sweat can be effectively solved, and the makeup lasting time is remarkably prolonged.

The invention provides an automobile lining material with sterilization and peculiar smell removal functions and a preparation method of the automobile lining material. The material for the automobile lining comprises a surface layer, a functional layer and a bottom layer which are sequentially arranged, wherein the functional layer is obtained by performing surface treatment on a fabric through an MOF-lysozyme material. Silver-based ZIF is formed by silver ions and dimethylimidazole, the characteristics of large specific surface area, adjustable aperture and high crystallinity of a traditional MOF material are reserved, and the silver-based ZIF has a certain antibacterial effect due to the silver ions, so that the antibacterial characteristic of a functional layer is enhanced; as the silver-based ZIF has the characteristics of large specific surface area and large aperture, more lysozyme can be covalently grafted, and the silver-based ZIF still has excellent broad-spectrum antibacterial performance; the silver-based ZIF material and the lysozyme synergistically enhance the bactericidal ability of the functional layer, so that the effects of long-acting sterilization, good antibacterial effect and peculiar smell elimination are achieved, the air quality in a vehicle is further improved, and a healthier and fresher riding environment is provided for passengers.

The invention provides a preparation method for preparing porous carbon based on an aerogel method, the porous carbon and application of the porous carbon, and belongs to the technical field of porous carbon material preparation. The preparation method comprises the following steps: mixing polyhydroxy phenol, aromatic aldehyde, acrylamide, graphene oxide and lithium salt according to a mass ratio of 100: (50-200): (5-30): (1-5): (1-5), carrying out hydrothermal reaction at 100-200 DEG C for 1-6 hours, and freeze-drying at-40 DEG C to obtain a hydrogel precursor; and carbonizing the precursor in organic heteroatom gas at 500-800 DEG C, mixing the intermediate with alkali according to the ratio of 100: (100-500), activating at 900-1100 DEG C, pickling and drying to obtain the porous carbon. The conductivity of the product is improved by means of graphene, lithium salt and heteroatoms, and the aerogel method obtains large aperture, has the characteristics of low impedance, high first efficiency and small charge-discharge expansion, and can be efficiently applied to silicon-carbon materials.

The invention discloses a flexible three-dimensional MOF (Metal Organic Framework) array SERS (Surface Enhanced Raman Scattering) substrate and a preparation method thereof. The flexible three-dimensional MOF array SERS substrate comprises a flexible substrate, a three-dimensional MOF periodic array layer and a gold nanoparticle film which are sequentially arranged from bottom to top. The three-dimensional ordered MOF periodic array structure on the substrate can provide more attachment points for the gold nanoparticles, and high-density hot spots are formed; meanwhile, the MOF material has the advantages of high porosity, large specific surface area, adjustable aperture and the like, and can adsorb and capture a target analyte, so that to-be-detected molecules are concentrated and enriched in a hot spot region, and finally, the SERS activity is improved. The SERS substrate is a flexible substrate and can be directly attached to the surface of a complex to-be-detected object, and in-situ detection is achieved. The method has the characteristics of high sensitivity, good repeatability and wide applicability, and provides important support for rapid detection in food safety and environment monitoring.

The invention relates to the technical field of sodium ion batteries, in particular to an MOF-coated layered oxide positive electrode material, a preparation method thereof and a sodium ion battery. The preparation method comprises the following steps: ball-milling and mixing a metal source and a sodium source, and calcining to obtain a layered oxide positive electrode material; the preparation method comprises the following steps: adding Mn salt or Al salt and 2, 5-dihydroxy terephthalic acid into a mixed solvent composed of dimethyl amide, ethanol and deionized water, stirring, and reacting to obtain an MOF material; and mixing the layered oxide positive electrode material and the MOF material, and carrying out heat treatment to obtain the MOF-coated layered oxide positive electrode material. The MOF serving as a coating layer material has a large-aperture structure, a diffusion channel is provided for sodium ion transmission, and the migration rate of sodium ions is increased; mn-MOF or Al-MOF is used as a coating layer material, so that the surface oxygen defect concentration of the layered oxide positive electrode material can be adjusted, the reversibility of oxidation reduction of oxygen anions can be improved, and the coulombic efficiency and the cycling stability of the battery during charging and discharging under a high-voltage condition can be further improved.

The invention provides an aerogel film with a continuous gradient pore structure and a preparation method and application thereof.The preparation method comprises the steps that a pre-crosslinking solution containing a polymer nanofiber suspension, a sodium alginate solution, a polyethyleneimine aqueous solution and a crosslinking agent is sprayed to a temperature-conducting substrate with the initial temperature ranging from-20 DEG C to-15 DEG C at high pressure; and freeze-drying to obtain the aerogel film with the continuous gradient pore structure. The aperture of the aerogel film is gradually increased from bottom to top, and the range of the aperture is mainly 1-110 [mu] m. The aerogel film is placed in a filter membrane clamp, so that a solution to be filtered passes through the aerogel film according to the sequence of'macropore-mesopore-micropore ', the aerogel film is used for intercepting and recycling particles with different sizes, such as micro-plastics, and high water flux and high rejection rate are both considered. The pore size of the aerogel film can be changed by adjusting the temperature of the temperature-conducting substrate; the prepared aerogel film improves the trade-off effect in the existing filtration separation technology, and has a wide market prospect.

The invention discloses a simple preparation method of a high-performance film composite forward osmosis membrane, and belongs to the technical field of water treatment. The preparation method comprises the following steps: firstly, selecting a basement membrane with an ultra-large aperture as a supporting layer of the TFC to relieve a concentration polarization phenomenon and provide a larger interface specific surface area for the growth of polyamide; then, a surfactant is introduced into the water-phase solution to further promote the improvement of the effective water delivery area of the membrane. And finally, carrying out interfacial polymerization reaction on the surface of the substrate membrane to synthesize the TFC-FO membrane with higher performance. The TFC-FO membrane prepared through the method has excellent water flux and interception performance, the FO performance of the TFC-FO membrane is continuously improved along with increase of the pore diameter of the supporting layer, and the application potential of the TFC-FO membrane in the technical field of water treatment is greatly improved.

The invention discloses an asymmetric sulfone polymer nanoscale filter membrane as well as a preparation method and application thereof, and belongs to the technical field of membrane materials. The filter membrane comprises a filter membrane main body, the filter membrane main body comprises a pre-filtering layer and a separation layer for intercepting impurities, the average thickness of the separation layer is 0.5-12 microns, and the porosity is 40-80%; the ratio of the maximum aperture of the PMI to the minimum aperture of the PMI of the filter membrane is 1.2-3.5, the retention rate of the filter membrane to 2nm colloidal gold is greater than or equal to 90%, and the ratio of the standard deviation of the area value of the brightness displacement spectrum to the average value of the area value is 0.01-2 when the filter membrane with the retention rate of 2nm colloidal gold is subjected to section brightness measurement; the separation layer structure which is thin and uniform in thickness and the proper pore size and pore size distribution of the filter membrane are combined with high porosity, so that the filter membrane can be ensured to have high flux and high cleanliness while having high interception efficiency, and the filter membrane is suitable for nanoscale purification of a liquid treatment agent used in a semiconductor wet process.

The invention discloses a hydrogen-fluorine atom doped graphdiyne material and a preparation method thereof, and relates to the technical field of carbon materials. According to the method, halogenated aromatic hydrocarbon and an alkynyl compound are taken as raw materials, a palladium catalyst and a copper catalyst are taken as a catalytic system, and an acetylenic bond of the alkynyl compound and the halogenated aromatic hydrocarbon are subjected to a Sonogashira coupling reaction to obtain the hydrogen-fluorine-doped graphite alkynyl material. The graphdiyne material provided by the invention has a large pore diameter, multiple active sites and high thermal stability and chemical stability, so that the hydrofluorine-doped graphdiyne material has excellent electrochemical energy storage property, shows reversible capacity of 1155mAh g <-1 > under 0.05 Ag <-1 > when being used as a negative electrode of a lithium ion battery, and can be used as a negative electrode of the lithium ion battery. And the density is almost 3 times that of a commercial graphite negative electrode material (300-350mAh g <-1 >). The application of the graphdiyne material in the field of electrochemical energy storage is obviously promoted.

The utility model discloses a handle of a barrel-shaped article, which comprises a handle, the handle is connected with a ring body, the whole ring body is a strip-shaped hole, the ring body comprises a large-aperture hole domain section, one side of the large-aperture hole domain section is connected with a small-aperture hole domain section in an extending manner, and the other side of the large-aperture hole domain section is connected with a tooth-shaped hole domain section in an extending manner. The extension direction of tooth peaks or tooth valleys on the inner wall of the tooth-shaped hole domain section ring body is parallel to the through direction of the ring body; in the lifting process, the large-aperture hole domain section is aligned with the barrel cover and moves to the position below the convex ring, then the ring body is translated till the upper ring face of the small-aperture hole domain section abuts against the lower ring face of the convex ring, and the barrel body can be lifted when the handle is held. The tooth peaks or the tooth valleys on the tooth-shaped hole domain section are correspondingly meshed with the tooth parts on the barrel cover, so that the barrel cover can be opened by rotating the barrel cover in a labor-saving manner by rotating the handle; therefore, the barrel body is convenient to lift, and meanwhile, the problem of opening a bottle of a barreled article is solved.

The invention discloses a large-aperture Cu / SiO2 catalyst as well as preparation and application thereof. The large-aperture Cu / SiO2 catalyst comprises a carrier and copper oxides loaded on the inner surface and the outer surface of the carrier, the carrier is a large-aperture silicon dioxide carrier, in the large-aperture Cu / SiO2 catalyst, the mass percent of the carrier is 62.5%-99.5%, the mass percent of the copper oxides is 0.5%-37.5%, the large-aperture Cu / SiO2 catalyst is granular, the specific surface area is 150-300 m < 2 > / g, the pore volume is 0.8-1.2 ml / g, and the specific surface area of the large-aperture Cu / SiO2 catalyst is 20-30%. And the average pore size is 15-25nm. The invention provides the application of the large-aperture Cu / SiO2 catalyst in diethylene glycol dehydrogenation lactonization reaction, the selectivity of a target product is greatly improved finally, the production cost of the catalyst is low, the preparation method is simple and reliable, and the reaction conditions are mild.

The invention relates to a PVDF (Polyvinylidene Fluoride) polymer lateral chromatography membrane and a preparation method thereof, and according to the method, a large-aperture PVDF membrane is prepared by blending a hydrophilic additive with high molecular weight and PVDF powder. The method comprises the following steps: mixing PVDF powder with a hydrophilic pore-foaming agent (such as PVP, PEG and the like) by adopting a solution blending method, performing non-solvent induced phase separation (NIPS) to form a membrane, immersing the membrane into a coagulating bath for a period of time, transferring the membrane into deionized water for soaking, taking out the membrane after the solvent is completely removed, and drying the membrane at normal temperature to form the membrane. And immersing the membrane in a surfactant solution for a period of time, taking out the membrane, and naturally airing the membrane so as to obtain the PVDF flat membrane which has a macroporous structure, a good pore structure, hydrophilicity and protein adsorption performance.

The invention relates to a dual anti-pollution modified piezoelectric ceramic membrane and a preparation method thereof, and belongs to the field of membrane materials. The ceramic membrane takes piezoelectric ceramic as a support body, the surface of the ceramic membrane is coated with a membrane layer with a small aperture, and one side of the ceramic membrane is modified by zwitterions and is used for separation and pollution resistance. A main body is a porous piezoelectric medium, the pore diameter is large, and self-cleaning is achieved through in-situ ultrasonic cavitation. The preparation method comprises the following steps: sintering to prepare a piezoelectric support body, coating a film layer, sintering to obtain a composite film, and strengthening the binding force by using dopamine hydrochloride to generate sulfanilamide zwitterions. Experiments show that in-situ ultrasound and the zwitter-ion hydration layer have a synergistic effect, and the anti-pollution performance is remarkably improved.

The application discloses a biomass-based nitrogen-doped carbon-carbide molybdenum composite catalyst and a preparation method and application thereof, and is characterized in that: a widely-sourced biomass, especially agricultural biomass waste, is used as a carbon and nitrogen source, ammonium molybdate is used as a molybdenum source, and a nitrogen-doped carbon-carbide molybdenum composite catalyst is prepared through one-step pyrolysis under an ammonia atmosphere; the catalyst is mesoporous nitrogen-doped carbon loaded with pure beta-phase carbide molybdenum, has the characteristics of a large pore size, high dispersion of beta-phase carbide molybdenum and the like, and has good thermal stability; the catalyst can efficiently denitrogenate quinoline and directively convert the quinoline, and high-selectivity aromatic hydrocarbon products can be obtained; the conversion rate is not less than 99%, the denitrogenation rate is not less than 99%, the selectivity of aromatic compounds is not less than 86%, and the catalyst has the characteristics of low hydrogen consumption due to the avoidance of hydrogen saturation reaction.

Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.

The invention provides a preparation method of a PEM water electrolysis anode diffusion layer, which relates to the field of PEM water electrolysis. Titanium nanotubes with different pore sizes are selected, and the large-pore titanium nanotubes are used to transmit liquids, and the small-pore titanium nanotubes are used to transmit gases, so that the gas and liquid transmission in the PEM water electrolysis process is highly ordered, and good liquid and gas management functions are achieved; the surfaces of the titanium nanotubes and titanium powders are attached with noble metal ions, and then oxygen is introduced for calcination, so that the noble metal ions form an oxide grid structure and are attached and embedded in the surfaces of the titanium nanotubes and titanium powders, which has higher firmness, protects the titanium material from being oxidized in the water electrolysis process, and improves the conductivity and catalytic ability of the anode diffusion layer.

The application discloses a kind of linear cutting continuous processing methods of seat body large aperture parallel group hole, belong to mechanical manufacturing technical field.This method is first with seat body A face as reference, planing, planing seat body shape and concave surface to drawing size;Again, workpiece is once clamped and aligned, and linear cutting molybdenum wire is used along preset trajectory to continuously cut, and all large aperture through hole is simultaneously processed, and 45° chamfer bevel is reserved at cutting place;Finally, intermittent welding is used to cutting seam, and workpiece temperature is strictly controlled not to exceed 80 DEG C to prevent thermal deformation, and after welding, weld is ground flat to make surface flush with concave surface.The application is characterized by linear cutting without mechanical cutting force, solves the problem that tool is easily appeared in traditional boring machine processing, through hole taper is big, parallelism is poor, effectively guarantees the size and shape accuracy of through hole.Workpiece is only single clamping, and it is free from dependence on high-skilled operators, processing efficiency and product consistency are significantly improved, and it is suitable for batch processing of large-size seat body parallel deep hole of 45 steel.

The present invention provides a shrinkage-resistant macroporous ultralight soft elastic supercritical foaming sole material and a preparation method thereof; the foaming sole material improves the flexibility / resilience / compressibility / mechanical strength of the foaming sole by using poly (1,2-butadiene)-b-polyethylene oxide copolymer, improves the cell strength by the double cross-linking effect of ethylene-methacrylic polymer, and effectively disperses ultra-high molecular weight polyethylene micropowder in the matrix and enhances the strength of large-aperture cells with carboxyl polystyrene microspheres, and then selects medium molecular weight polyisobutylene and cross-linking agent micro-cross-linking to further enhance the viscosity and strength of the matrix and effectively lock the gas, not only meeting the physical property requirements of consumers for lightness, softness and elasticity, thereby effectively preventing the shrinkage of the sole under the appearance of large pores, and improving the yield of the product and the stability and safety of mass production. In terms of technology, the ultra-high pressure foaming method is adopted, and the foaming time can be shortened by more than 50% compared with the traditional supercritical autoclave pressure, greatly improving the production efficiency.

The invention discloses a catalytic slurry oil hydrogenation catalyst and a preparation method thereof. The catalyst comprises an alumina carrier containing an auxiliary agent, MoO3 and CoO, the carrier has bimodal pore size distribution, the smaller pore size is intensively distributed at 10-40nm, the pore volume of pore channels with the pore size of 10-40nm accounts for 20%-40% of the total pore volume, the larger pore size is intensively distributed at 150-400nm, and the pore volume of pore channels with the pore size of 150-400nm accounts for 30%-50% of the total pore volume. The catalyst disclosed by the invention is arranged between a hydrogenation protective agent and a hydrogenation desulfurizing agent in a catalytic cracking oil slurry hydrogenation reactor to play a role of connecting the previous part and the next part, so that primary removal of sulfur impurities in catalytic cracking oil slurry is realized, more deposits such as carbon deposits can be accommodated, and the running period of a device is prolonged.

A polyolefin separator for an electrochemical device, the separator having a plurality of pores having an average pore size of 20 nm to 40 nm and a maximum pore size of 50 nm or less and including a polyolefin resin having a polydispersity index (PDI) of in a range of 2.5 to 4.2. The polyolefin separator may have a strain rate of 25% or less as measured when a tensile stress is applied at 60° C. at 15 MPa for 60 seconds, and the polyolefin separator may have a recovery time of 200 seconds or less to reach a recovery rate of 70% as measured after removing a tensile stress applied at 70° C. at 2 MPa for 180 seconds.

The present application provides an ultra-high molecular weight polyolefin separator comprising ultra-high molecular weight polyethylene, the ultra-high molecular weight polyethylene having an average molecular weight of ≥ 1 million, wherein the ultra-high molecular weight polyolefin separator has a median pore size of 0.04 μm to 1 μm, a maximum pore size not exceeding 1.2 μm, and a puncture strength of ≥ 50 gf. The present application also provides a method for producing the ultra-high molecular weight polyolefin separator, which is safer than conventional nonwoven fabric separators and has higher ionic conductivity and a larger median pore size, thereby solving the problem that conventional nonwoven fabric separators in lithium batteries have high lithium ion permeability but are very dangerous and prone to short-circuiting the battery.

The invention discloses a pole piece. The pole piece has a large aperture size, uniform pores with relatively large sizes are formed in a slurry layer of the pole piece through a salt template method, and the defect that the pores formed by a gas pore-forming agent are too small is overcome; meanwhile, the performance of the pole piece is improved. A battery cell prepared from the pole piece disclosed by the invention can give consideration to both high volume energy density and good constant-current charging ratio.