An efficient method for grain refinement of aluminum and aluminum alloys

A grain refining, aluminum alloy technology, applied in the field of metal materials, can solve the problems of low particle utilization rate, limited refining effect, surface scratches on aluminum and aluminum alloy sheet structural parts, etc., and achieve stable grain refining effect. , Improve the effect of grain refinement and the effect of high grain refinement efficiency

Active Publication Date: 2022-02-18
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at present, the fluorine salt reaction method is often used in the industry to prepare Al-Ti-B alloys. When using this method to prepare the refiner, the reaction time between the fluoride salt and the aluminum melt is relatively long, and the heterogeneous core particles TiB 2 Continuous nucleation and growth, TiB in the alloy 2 The particle size distribution is broad, which leads to TiB 2 The particle utilization rate is low, and the refinement effect is limited
In addition, Al-Ti-B alloys usually have some TiB with a size of several microns or more 2 Particles and larger TiB 2 Particle clusters, using such a refining agent to refine aluminum and aluminum alloy melts according to the traditional refining process, may bring serious harm to the subsequent processing of alloy ingots, such as causing aluminum and aluminum alloy thin plate structural parts Surface scratches, streak defects, etc.

Method used

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  • An efficient method for grain refinement of aluminum and aluminum alloys
  • An efficient method for grain refinement of aluminum and aluminum alloys
  • An efficient method for grain refinement of aluminum and aluminum alloys

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] In this embodiment, an efficient method for grain refinement of aluminum and aluminum alloys, the steps are as follows:

[0027] (1) Add 1kg of Al-Zn-Mg-Cu aluminum alloy ingots into two crucibles respectively, heat and melt and raise the temperature to 750°C to form two aluminum melts;

[0028] (2) adding 0.2% Ti and 0.04% B accounting for the weight of the aluminum melt to the above two aluminum melts in the form of an Al-Ti alloy (or pure Ti) and an Al-B alloy, Stir and keep warm for 20min;

[0029] (3) Pour the alloy melt containing B into the alloy melt containing Ti, so that the two melts are fully mixed;

[0030] (4) Adjust the temperature of the mixed melt to 700°C ± 20°C, and keep it warm for 5 minutes; keep it warm at a specific temperature of 720°C ± 20°C, its function is to adjust the size distribution of the core particles in the melt.

[0031] (5) Pour the mixed melt into a mold to cool and solidify to form an Al-Zn-Mg-Cu aluminum alloy ingot.

[0032] ...

Embodiment 2

[0034] In this embodiment, a highly efficient method for grain refinement of aluminum and aluminum alloys, the steps are as follows:

[0035] (1) Add 1kg of Al-Zn-Mg-Cu aluminum alloy ingots into two crucibles respectively, heat and melt and raise the temperature to 680°C to form two aluminum melts;

[0036] (2) adding 0.04% Ti and 0.008% B accounting for the weight of the aluminum melt to the two aluminum melts in the form of an Al-Ti alloy (or pure Ti) and an Al-B alloy, Stir and keep warm for 20min;

[0037] (3) Pour the alloy melt containing B into the alloy melt containing Ti, so that the two melts are fully mixed;

[0038] (4) Adjust the temperature of the mixed melt to 700°C±20°C and keep it warm for 5 minutes;

[0039] (5) Pour the mixed melt into a mold to cool and solidify to form an Al-Zn-Mg-Cu aluminum alloy ingot.

[0040] The structure and morphology of the Al-Zn-Mg-Cu aluminum alloy prepared in this example has an average grain size of about 45.2 μm, which is...

Embodiment 3

[0042] In this embodiment, a highly efficient method for grain refinement of aluminum and aluminum alloys, the steps are as follows:

[0043] (1) Add 1kg of Al-Zn-Mg-Cu aluminum alloy ingots into two crucibles respectively, heat and melt and raise the temperature to 720°C to form two aluminum melts;

[0044] (2) adding 0.04% Ti and 0.008% B accounting for the weight of the aluminum melt to the two aluminum melts in the form of an Al-Ti alloy (or pure Ti) and an Al-B alloy, Stir and keep warm for 10 minutes;

[0045] (3) Pour the alloy melt containing B into the alloy melt containing Ti, so that the two melts are fully mixed;

[0046](4) Keep the mixed melt at 700°C±20°C for 5 minutes;

[0047] (5) Pour the mixed melt into a mold to cool and solidify to form an Al-Zn-Mg-Cu aluminum alloy ingot.

[0048] The structure and morphology of the Al-Zn-Mg-Cu aluminum alloy prepared in this example has an average grain size of about 42.5 μm, which is much smaller than the average gra...

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Abstract

The invention relates to the field of metal materials, in particular to an efficient method for refining grains of aluminum and aluminum alloys, by which the grains of aluminum and aluminum alloys can be efficiently refined. The method includes the following steps: 1) adding aluminum or aluminum alloy ingots into two crucibles respectively, heating and melting, and heating up to 680-850 ° C; 0.008% to 0.06% of B by body weight is added to the above two melts in the form of Al-Ti alloy (or pure Ti) and Al-B alloy respectively, stirred and kept for 10 to 30 minutes; The melt is poured into another crucible, and the two melts are fully mixed; 4) The temperature of the mixed melt is adjusted to 700°C ± 20°C, and the temperature is kept for 5-60 minutes; 5) The mixed melt is poured into the mold for cooling Solidifies to form an aluminum or aluminum alloy ingot with fine grain size. The grain refining method for aluminum and aluminum alloys of the present invention has the advantages of low cost, simple process, high grain refining efficiency, stable grain refining effect, and the like.

Description

technical field [0001] The invention relates to the field of metal materials, in particular to an efficient aluminum and aluminum alloy grain refining method, which can efficiently refine the aluminum and aluminum alloy grains. Background technique [0002] Aluminum and aluminum alloys have the advantages of light weight, corrosion resistance, high specific strength, and excellent electrical conductivity, and have great application prospects in aerospace, transportation, and electric power transportation. Previous studies have shown that the grain refinement of the solidification structure is very important whether it is cast aluminum alloy or deformed aluminum alloy. From the perspective of alloy properties, aluminum alloy castings composed of fine and uniform equiaxed grains have high strength, high plasticity and excellent subsequent deformation processing performance; from the perspective of casting defects, grain refinement can greatly reduce element segregation , Redu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/03C22C1/06C22C21/00
CPCC22C1/026C22C1/03C22C1/06C22C21/00
Inventor 江鸿翔赵九洲张丽丽何杰
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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