Preparation method of high-coercivity diffusion samarium-cobalt composite permanent magnet

A high coercivity, permanent magnet technology, used in magnetic objects, inductor/transformer/magnet manufacturing, magnetic materials, etc., can solve problems such as uneven distribution of soft and hard magnetic phases, and achieve improved coercivity and maximum magnetic energy product. , The experimental method is simple, and the effect of maintaining the magnetic properties

A high coercivity, permanent magnet technology, used in magnetic objects, inductor/transformer/magnet manufacturing, magnetic materials, etc., can solve problems such as uneven distribution of soft and hard magnetic phases, and achieve improved coercivity and maximum magnetic energy product. , The experimental method is simple, and the effect of maintaining the magnetic properties

CN112382497AActive Publication Date: 2021-02-19CHINA JILIANG UNIV

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  • Preparation method of high-coercivity diffusion samarium-cobalt composite permanent magnet

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Embodiment 1

[0021] Embodiment 1: a kind of preparation method of high coercive force diffused samarium cobalt permanent magnet, comprises the following steps:

[0022] Step (1) Preparation of diffusion source:

[0023] Mixing soft magnetic phase nanoscale Fe powder with organic solvent acetone to form a mixed solution of diffusion source;

[0024] Step (2) Preparation of samarium cobalt hard magnetic phase permanent magnet:

[0025] Preparation of samarium cobalt hard magnetic phase permanent magnet: according to (Sm, Tb) 1 (Co,Fe,Ni,Cu) 5 After the alloy components are mixed, the samarium cobalt permanent magnet is obtained through melting, hot pressing and heat treatment, in which the atomic ratio of Sm:Tb is 1:0.04, (Co,Fe,Ni,Cu) 5 The atomic proportion of Co in the medium is 70%;

[0026] Step (3) Laser perforation of samarium cobalt permanent magnet:

[0027] Using femtosecond to nanometer laser pulses, the laser wavelength is 820nm, the pulse duration is 300fs, the pulse intens...

Embodiment 2

[0035] Step (1) Preparation of diffusion source:

[0036] Mixing soft magnetic phase nanoscale Fe powder with organic solvent acetone to form a mixed solution of diffusion source;

[0037] Step (2) Preparation of samarium cobalt hard magnetic phase permanent magnet:

[0038] Preparation of samarium cobalt hard magnetic phase permanent magnet: according to (Sm, Gd) 1 (Co,Fe,Ni,Cu) 5 After the alloy components are mixed, the samarium-cobalt permanent magnet is obtained through smelting, hot pressing and heat treatment, in which the atomic ratio of Sm:Tb is 1:0.08, (Co,Fe,Ni,Cu) 5 The atomic proportion of Co in the medium is 90%;

[0039] Step (3) Laser perforation of samarium cobalt permanent magnet:

[0040] Using femtosecond to nanometer laser pulses, the laser wavelength is 820nm, the pulse duration is 300fs, the pulse intensity is 200uJ, the spot size is 7μm, and the surface of a samarium cobalt magnet with a size of 20mm×20mm×20mm is perforated. The shape of the hole is...

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Abstract

The invention discloses a preparation method of a high-coercivity diffusion samarium-cobalt composite permanent magnet. The preparation method comprises the following steps: mixing soft magnetic phasenanoscale Fe or Co powder with an organic solvent to form a diffusion source mixed solution; mixing (Sm, Re) 1 (Co, Fe, Ni, Cu) 5 alloy components, carrying out smelting, hot pressing and heat treatment, and preparing samarium-cobalt master alloy; perforating the surface of the samarium-cobalt permanent magnet by using femtosecond to nano laser pulses to form a coal ball-shaped magnet; immersingthe coal ball-shaped magnet into the diffusion source mixed solution, taking out the magnet, and presintering at low temperature under the protection of nitrogen to obtain a magnet with a diffusion source coating inside and on the surface of the magnet; and carrying out heat treatment on the obtained magnet under argon protection and a strong magnetic field to obtain the samarium-cobalt compositepermanent magnet. Through the laser perforation grain boundary diffusion technology, the soft magnetic phase and the doping elements can effectively enter the grain boundary of the samarium-cobalt magnet, the coupling effect and pinning effect of the soft magnetic phase and the hard magnetic phase are improved, the coercive force and the maximum magnetic energy product are improved, in addition, the method does not need nanometer compounding of the soft magnetic phase and the hard magnetic phase , the adopted experimental method is simple. Few impure phases are introduced, and the magnetic performance of the hard magnetic phase can be kept to the maximum extent.

Description

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Claims

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Application Information

Patent Timeline
19 Feb 2021
Publication
CN112382497A