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A kind of preparation method of carbon nanotube sodium superionic conductor coated ternary electrode material

A sodium superionic conductor and carbon nanotube technology, applied in positive electrodes, battery electrodes, active material electrodes, etc., can solve the problems of poor low-temperature performance of lithium batteries, slow diffusion of lithium ions, and inability to compensate for lithium batteries, etc. The effects of rate capability, excellent mechanical stability, and good flexibility

Active Publication Date: 2021-06-01
浙江晨阳新材料有限公司
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  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, even ternary materials cannot make up for the following shortcomings in the application of lithium batteries: (1) The tap density of the positive electrode of lithium batteries is small, the density is generally around 0.8 to 1.3, and the volume is large.
(2) The electrical conductivity is poor, the diffusion rate of lithium ions is slow, and the actual specific capacity is low when charging and discharging at a high rate
(3) The low temperature performance of lithium batteries is poor

Method used

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  • A kind of preparation method of carbon nanotube sodium superionic conductor coated ternary electrode material
  • A kind of preparation method of carbon nanotube sodium superionic conductor coated ternary electrode material
  • A kind of preparation method of carbon nanotube sodium superionic conductor coated ternary electrode material

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preparation example Construction

[0034] The preparation of carbon nanotube sodium superionic conductor comprises the following steps:

[0035] Step 1: Under high pressure, the flowing carbon nanotube liquid is collided with ultra-high pressure for 15-30 minutes to form a uniform and stable carbon nanotube dispersion;

[0036] Step 2: uniformly stir and mix the sodium superionic conductor, carbon nanotube dispersion and dispersant in the solvent N-methylpyrrolidone for 4-6 hours to obtain the first mixed solution; the reason for the formation of the superionic conductor is the non- The conductive ions form a rigid skeleton, and there are more occupyable positions than the number of conductive ions inside the crystal lattice. Free movement, the material has excellent comprehensive properties, high room temperature ionic conductivity, good thermal stability, and LiCoO 2 , LiMn 2 o 4 Positive electrodes such as metal lithium, lithium alloy and other negative electrodes have good compatibility, and carbon nanot...

Embodiment example 1

[0047] A method for preparing a carbon nanotube sodium superionic conductor-coated ternary electrode material: including the preparation of a carbon nanotube sodium superionic conductor and the preparation of a carbon nanotube sodium superionic conductor-coated ternary electrode material, the carbon nanotube sodium The preparation of superionic conductors includes the following steps:

[0048] Step 1: Under high pressure, the flowing carbon nanotube liquid is collided with ultra-high pressure for 15-30 minutes to form a uniform and stable carbon nanotube dispersion;

[0049] Step 2: Stir and mix 2 parts of sodium superionic conductor, 3 parts of carbon nanotube dispersion and 2 parts of dispersant in 1 part of solvent N-methylpyrrolidone for 4 hours to obtain the first mixed solution;

[0050] Step 3: 3 parts of carbon nanotube dispersion, 7 parts of thermoplastic polyurethane rubber, 5 parts of lithium titanium phosphate and 0.1 part of n-butanol were uniformly stirred and mi...

Embodiment example 2

[0056] A method for preparing a carbon nanotube sodium superionic conductor-coated ternary electrode material: including the preparation of a carbon nanotube sodium superionic conductor and the preparation of a carbon nanotube sodium superionic conductor-coated ternary electrode material, the carbon nanotube sodium The preparation of superionic conductors includes the following steps:

[0057] Step 1: Under high pressure, the flowing carbon nanotube liquid is collided with ultra-high pressure for 15-30 minutes to form a uniform and stable carbon nanotube dispersion;

[0058]Step 2: Stir and mix 3 parts of sodium superionic conductor, 3.5 parts of carbon nanotube dispersion and 1 part of dispersant in 2 parts of solvent N-methylpyrrolidone for 5 hours to obtain the first mixed solution;

[0059] Step 3: 3.4 parts of carbon nanotube dispersion, 7.2 parts of thermoplastic polyurethane rubber, 4.1 parts of lithium titanium phosphate and 0.15 parts of n-butanol were uniformly stirr...

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Abstract

The invention belongs to the technical field of preparation of electrode materials, and relates to a method for preparing a ternary electrode material coated with a carbon nanotube sodium superionic conductor, including the preparation of a carbon nanotube sodium superionic conductor and the coating of a carbon nanotube sodium superionic conductor. The preparation of the meta-electrode material, step 1: under high pressure, the flowing carbon nanotube liquid is collided with ultrahigh pressure to form a carbon nanotube dispersion; step 2: the sodium superionic conductor, carbon nanotube and dispersant are mixed in a solvent N- Stir and mix evenly in methylpyrrolidone for 4-6 hours; Step 3: prepare graphene carbon nanotube mixed solution; Step 4: use the mixed solution prepared in step 2 and the graphene carbon nanotube mixed solution prepared in step 3 to Stirring with a stirrer and ultrasonically dispersing to obtain a carbon nanotube sodium superionic conductor dispersion; Step 5: mixing the carbon nanotube sodium superionic conductor dispersion with the ternary electrode material. The ternary electrode material prepared by this method has high conductivity and can improve electrochemical performance.

Description

technical field [0001] The invention relates to a preparation method of a carbon nanotube sodium superionic conductor coating a ternary electrode material. It belongs to the technical field of electrode material preparation. Background technique [0002] Today, with the development of portable devices, lithium rechargeable batteries are currently being used as energy storage devices closest to us in our lives. With the development of industry, based on their higher theoretical energy density, low cost and environmental compatibility compared with traditional energy storage systems, various fields have higher requirements for the performance of lithium rechargeable batteries, and are also considered to be the most promising One of the promising energy storage systems. In order to ensure optimized energy density and improve safety, a lot of research has been done on the cathode, anode, and electrolyte materials constituting lithium secondary batteries. However, due to the l...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/36H01M4/505H01M4/525H01M4/62H01M10/0525
CPCH01M4/366H01M4/505H01M4/525H01M4/625H01M4/628H01M10/0525H01M2004/021H01M2004/028Y02E60/10
Inventor 陈忠伟
Owner 浙江晨阳新材料有限公司