A kind of preparation method of carbon nanotube sodium superionic conductor coated ternary electrode material
A sodium superionic conductor and carbon nanotube technology, applied in positive electrodes, battery electrodes, active material electrodes, etc., can solve the problems of poor low-temperature performance of lithium batteries, slow diffusion of lithium ions, and inability to compensate for lithium batteries, etc. The effects of rate capability, excellent mechanical stability, and good flexibility
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preparation example Construction
[0034] The preparation of carbon nanotube sodium superionic conductor comprises the following steps:
[0035] Step 1: Under high pressure, the flowing carbon nanotube liquid is collided with ultra-high pressure for 15-30 minutes to form a uniform and stable carbon nanotube dispersion;
[0036] Step 2: uniformly stir and mix the sodium superionic conductor, carbon nanotube dispersion and dispersant in the solvent N-methylpyrrolidone for 4-6 hours to obtain the first mixed solution; the reason for the formation of the superionic conductor is the non- The conductive ions form a rigid skeleton, and there are more occupyable positions than the number of conductive ions inside the crystal lattice. Free movement, the material has excellent comprehensive properties, high room temperature ionic conductivity, good thermal stability, and LiCoO 2 , LiMn 2 o 4 Positive electrodes such as metal lithium, lithium alloy and other negative electrodes have good compatibility, and carbon nanot...
Embodiment example 1
[0047] A method for preparing a carbon nanotube sodium superionic conductor-coated ternary electrode material: including the preparation of a carbon nanotube sodium superionic conductor and the preparation of a carbon nanotube sodium superionic conductor-coated ternary electrode material, the carbon nanotube sodium The preparation of superionic conductors includes the following steps:
[0048] Step 1: Under high pressure, the flowing carbon nanotube liquid is collided with ultra-high pressure for 15-30 minutes to form a uniform and stable carbon nanotube dispersion;
[0049] Step 2: Stir and mix 2 parts of sodium superionic conductor, 3 parts of carbon nanotube dispersion and 2 parts of dispersant in 1 part of solvent N-methylpyrrolidone for 4 hours to obtain the first mixed solution;
[0050] Step 3: 3 parts of carbon nanotube dispersion, 7 parts of thermoplastic polyurethane rubber, 5 parts of lithium titanium phosphate and 0.1 part of n-butanol were uniformly stirred and mi...
Embodiment example 2
[0056] A method for preparing a carbon nanotube sodium superionic conductor-coated ternary electrode material: including the preparation of a carbon nanotube sodium superionic conductor and the preparation of a carbon nanotube sodium superionic conductor-coated ternary electrode material, the carbon nanotube sodium The preparation of superionic conductors includes the following steps:
[0057] Step 1: Under high pressure, the flowing carbon nanotube liquid is collided with ultra-high pressure for 15-30 minutes to form a uniform and stable carbon nanotube dispersion;
[0058]Step 2: Stir and mix 3 parts of sodium superionic conductor, 3.5 parts of carbon nanotube dispersion and 1 part of dispersant in 2 parts of solvent N-methylpyrrolidone for 5 hours to obtain the first mixed solution;
[0059] Step 3: 3.4 parts of carbon nanotube dispersion, 7.2 parts of thermoplastic polyurethane rubber, 4.1 parts of lithium titanium phosphate and 0.15 parts of n-butanol were uniformly stirr...
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