Reconfigurable driver based on self-healing elastomer and preparation method of reconfigurable driver
An actuating, self-healing technology, applied in chemical instruments and methods, manufacturing tools, program-controlled manipulators, etc., can solve the problems of limiting the variety of deformation and the practical application of reconfigurable actuators
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[0038] Materials: dimethylglyoxime (DMG, 98%), acetone (99.7%) were purchased from Sinopharm Chemical Reagent (China). Polytetrahydrofuran diol (PTMG, Mn=1000 g mol-1) was purchased from Aladdin (China). Diethylenetriamine (DETA, 99.0%) was purchased from Alfa Aesar (China). Diphenylmethane diisocyanate (MDI, 2,4'-MDI / 4,4'-MDI=50 / 50, 99.6%) was purchased from Wanhua Chemical (China). Chloroform (99.8%) was purchased from Yonghua Chemical (China). Reagents were used without further purification unless otherwise stated.
[0039] Synthesis of PDOUs
[0040] Add polytetrahydrofuran glycol (PTMG) into the reaction flask, raise the temperature to 110°C, and vacuumize for 2 hours to remove the adsorbed water in the polytetrahydrofuran glycol. The vacuum was then removed, and a nitrogen balloon was inserted to maintain N 2 Atmosphere, after slowly adding diphenylmethane diisocyanate (MDI) at 110°C, N 2 Reaction under atmosphere for 2h. Then keep N 2 The whole system was lowere...
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