Preparation method of (SiC)
super-hydrophobic membrane layer with lotus leaf effect
A lotus leaf effect and super-hydrophobic technology, which is applied in coatings, metal material coating processes, liquid chemical plating, etc., can solve the problems of few reports on super-hydrophobic film preparation methods, small particle size of silicon carbide powder, and large specific surface area. problems, to achieve good superhydrophobicity, good hydrophobicity, and simple operation
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Embodiment 1
[0036] Step 1. (SiC) P Surface pretreatment
[0037] Will (SiC) P Put it into a resistance furnace, heat it to 1200°C, and keep it warm for 2 hours for oxidation and etching. Take 5g of the sample after oxidation etching, add it to 200ml of HF, HCl, distilled water mixed solution with a volume ratio of 1:1:10, and carry out hydrophilic treatment at room temperature for 20 minutes; then the hydrophilic treated (SiC) P Add 1.0mol·L to 200ml -1 TiCl 3 , 1.5 g L -1 PdCl 2 , HCl mixed solution, activation treatment at room temperature for 30 minutes;
[0038] Step 2, preparation of deposition solution
[0039] Weigh nickel carbonate 60g L -1 , Sodium molybdate 15g·L -1 , sodium pyrophosphate 15g·L -1 , boric acid 8g·L -1 , rare earth 2.4mg·L -1 , sodium hypophosphite 24g·L -1 , stabilizer 0.3 mg·L -1 , dissolved in distilled water to prepare a 1L solution, and adjusted to pH 7.5 with ammonia water;
[0040] Step 3, preparation of superhydrophobic film layer
[0041...
Embodiment 2
[0049] Step 1. (SiC) P Surface pretreatment
[0050] Will (SiC) P Put it into a resistance furnace, heat it to 1000°C, and keep it warm for 3 hours to carry out oxidation and etching treatment. Take 7g of the sample after oxidation etching, add it to 300ml of HF, HCl, distilled water mixed solution with a volume ratio of 1:1:12, and carry out hydrophilic treatment at room temperature for 25 minutes; then the hydrophilic treated (SiC) P Add 300ml of 0.8 mol·L -1 TiCl 3 , 1.0 g L - 1 PdCl 2 , HCl mixed solution, activation treatment at room temperature for 35 minutes;
[0051] Step 2, preparation of deposition solution
[0052] Weigh 70g L of nickel carbonate -1 , Sodium molybdate 18g·L -1 , sodium pyrophosphate 16g·L -1 , boric acid 6g·L -1 , rare earth 2.6mg·L -1 , sodium hypophosphite 26g·L -1 , stabilizer 0.5 mg·L -1 , dissolved in distilled water to prepare a 1L solution, and adjust the pH value to 8.0 with ammonia water;
[0053] Step 3, preparation of supe...
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