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Preparation method of (SiC)

super-hydrophobic membrane layer with lotus leaf effect

A lotus leaf effect and super-hydrophobic technology, which is applied in coatings, metal material coating processes, liquid chemical plating, etc., can solve the problems of few reports on super-hydrophobic film preparation methods, small particle size of silicon carbide powder, and large specific surface area. problems, to achieve good superhydrophobicity, good hydrophobicity, and simple operation

Active Publication Date: 2021-06-11
HEILONGJIANG INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the above-mentioned preparation methods require the use of organic solvents, the preparation cost is relatively high, or they are not environmentally friendly, or the process is complicated, or they have high requirements for raw materials and equipment.
[0003] Silicon carbide particles [abbreviated as (SiC) P ] has the advantages of high hardness, wear resistance, high temperature resistance, etc., but it is hydrophilic, especially the particle size of silicon carbide powder is small, the specific surface area is large, and it has strong hydrophilicity. It is related to (SiC) P There are few reports on the preparation methods of superhydrophobic membranes

Method used

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  • Preparation method of (SiC)<p> super-hydrophobic membrane layer with lotus leaf effect
  • Preparation method of (SiC)<p> super-hydrophobic membrane layer with lotus leaf effect
  • Preparation method of (SiC)<p> super-hydrophobic membrane layer with lotus leaf effect

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Step 1. (SiC) P Surface pretreatment

[0037] Will (SiC) P Put it into a resistance furnace, heat it to 1200°C, and keep it warm for 2 hours for oxidation and etching. Take 5g of the sample after oxidation etching, add it to 200ml of HF, HCl, distilled water mixed solution with a volume ratio of 1:1:10, and carry out hydrophilic treatment at room temperature for 20 minutes; then the hydrophilic treated (SiC) P Add 1.0mol·L to 200ml -1 TiCl 3 , 1.5 g L -1 PdCl 2 , HCl mixed solution, activation treatment at room temperature for 30 minutes;

[0038] Step 2, preparation of deposition solution

[0039] Weigh nickel carbonate 60g L -1 , Sodium molybdate 15g·L -1 , sodium pyrophosphate 15g·L -1 , boric acid 8g·L -1 , rare earth 2.4mg·L -1 , sodium hypophosphite 24g·L -1 , stabilizer 0.3 mg·L -1 , dissolved in distilled water to prepare a 1L solution, and adjusted to pH 7.5 with ammonia water;

[0040] Step 3, preparation of superhydrophobic film layer

[0041...

Embodiment 2

[0049] Step 1. (SiC) P Surface pretreatment

[0050] Will (SiC) P Put it into a resistance furnace, heat it to 1000°C, and keep it warm for 3 hours to carry out oxidation and etching treatment. Take 7g of the sample after oxidation etching, add it to 300ml of HF, HCl, distilled water mixed solution with a volume ratio of 1:1:12, and carry out hydrophilic treatment at room temperature for 25 minutes; then the hydrophilic treated (SiC) P Add 300ml of 0.8 mol·L -1 TiCl 3 , 1.0 g L - 1 PdCl 2 , HCl mixed solution, activation treatment at room temperature for 35 minutes;

[0051] Step 2, preparation of deposition solution

[0052] Weigh 70g L of nickel carbonate -1 , Sodium molybdate 18g·L -1 , sodium pyrophosphate 16g·L -1 , boric acid 6g·L -1 , rare earth 2.6mg·L -1 , sodium hypophosphite 26g·L -1 , stabilizer 0.5 mg·L -1 , dissolved in distilled water to prepare a 1L solution, and adjust the pH value to 8.0 with ammonia water;

[0053] Step 3, preparation of supe...

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Abstract

The invention relates to a preparation method of a (SiC) super-hydrophobic membrane layer with a lotus leaf effect, and belongs to the technical field of material surface modification. A micro-nano structure is constructed and the preparation of the (SiC) super-hydrophobic membrane layer is realized by adopting a simple chemical deposition method under the conditions of normal pressure and normal temperature. The preparation process comprises the steps of (SiC) pretreatment, (SiC) surface chemical deposition modification and long-time standing of the modified (SiC). The static water contact angle of the prepared membrane layer is 150-160 degrees, the rolling angle is less than 10 degrees, and the prepared membrane layer shows good super-hydrophobicity at 10-80 DEG C. According to the preparation method of the (SiC) super-hydrophobic membrane layer with the lotus leaf effect, the used (SiC) is a waste material generated in an industrial production process, has low requirements on raw materials, is beneficial to resource reutilization, has the advantages of simplicity in operation, environmental friendliness, low equipment requirements, good hydrophobic effect and the like at the same time, and is convenient to popularize; and super-hydrophobic silicon carbide particles can be widely applied to the fields of self-cleaning, anti-icing, anti-fog, anti-fouling and the like by combining the excellent properties of wear resistance, corrosion resistance and the like of the super-hydrophobic silicon carbide particles.

Description

technical field [0001] The invention relates to the technical field of preparation and surface modification of inorganic powder materials, in particular to a method for preparing a silicon carbide superhydrophobic film layer with lotus leaf effect. Background technique [0002] Due to the limited contact area between the superhydrophobic surface and water, the chemical reaction and chemical bonding with water are inhibited, so it has the advantages of anti-pollution, self-cleaning, anti-ice and snow, anti-oxidation, and anti-corrosion. In nature, the leaves of many plants and certain parts of animals have superhydrophobic properties, such as lotus leaves, dragonfly wings, and mosquito compound eyes. The lotus leaf is the first plant to be found to be super-hydrophobic. Studies have found that the super-hydrophobic surface in nature has a micro-nano structure similar to the surface of the lotus leaf, which is called the "lotus leaf effect". The wettability of a solid surface...

Claims

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Application Information

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IPC IPC(8): C23C18/18C23C18/36
CPCC23C18/1639C23C18/1893C23C18/36C23C18/1689
Inventor 宿辉
Owner HEILONGJIANG INST OF TECH
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